Metal-Free Direct α-Selective Arylation of Boron Dipyrromethenes via Base-Mediated C–H Functionalization
Xin Zhou
1
,
Qinghua Wu
1
,
Yang Yu
1
,
Changjiang Yu
1
,
Erhong Hao
1
,
Yun Wei
1
,
Xiaolong Mu
1
,
Publication type: Journal Article
Publication date: 2016-02-09
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
26859791
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
A metal-free direct α-selective arylation of BODIPYs has been developed based on base-mediated C-H functionalization with easily accessible diaryliodonium salts, which provides a straightforward facile access to a variety of α-arylBODIPY dyes. The α-regioselectivity was confirmed by X-ray analysis, and was studied by DFT calculation. The resultant dyes show strong absorption and emission over a broad range of spectra tunable via the simple variation of the diaryliodonium salts.
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54
Total citations:
54
Citations from 2024:
8
(14.81%)
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MLA
Cite this
GOST
Copy
Zhou X. et al. Metal-Free Direct α-Selective Arylation of Boron Dipyrromethenes via Base-Mediated C–H Functionalization // Organic Letters. 2016. Vol. 18. No. 4. pp. 736-739.
GOST all authors (up to 50)
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Zhou X., Wu Q., Yu Y., Yu C., Hao E., Wei Y., Mu X., Jiao L. Metal-Free Direct α-Selective Arylation of Boron Dipyrromethenes via Base-Mediated C–H Functionalization // Organic Letters. 2016. Vol. 18. No. 4. pp. 736-739.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.orglett.5b03706
UR - https://doi.org/10.1021/acs.orglett.5b03706
TI - Metal-Free Direct α-Selective Arylation of Boron Dipyrromethenes via Base-Mediated C–H Functionalization
T2 - Organic Letters
AU - Zhou, Xin
AU - Wu, Qinghua
AU - Yu, Yang
AU - Yu, Changjiang
AU - Hao, Erhong
AU - Wei, Yun
AU - Mu, Xiaolong
AU - Jiao, Lijuan
PY - 2016
DA - 2016/02/09
PB - American Chemical Society (ACS)
SP - 736-739
IS - 4
VL - 18
PMID - 26859791
SN - 1523-7060
SN - 1523-7052
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2016_Zhou,
author = {Xin Zhou and Qinghua Wu and Yang Yu and Changjiang Yu and Erhong Hao and Yun Wei and Xiaolong Mu and Lijuan Jiao},
title = {Metal-Free Direct α-Selective Arylation of Boron Dipyrromethenes via Base-Mediated C–H Functionalization},
journal = {Organic Letters},
year = {2016},
volume = {18},
publisher = {American Chemical Society (ACS)},
month = {feb},
url = {https://doi.org/10.1021/acs.orglett.5b03706},
number = {4},
pages = {736--739},
doi = {10.1021/acs.orglett.5b03706}
}
Cite this
MLA
Copy
Zhou, Xin, et al. “Metal-Free Direct α-Selective Arylation of Boron Dipyrromethenes via Base-Mediated C–H Functionalization.” Organic Letters, vol. 18, no. 4, Feb. 2016, pp. 736-739. https://doi.org/10.1021/acs.orglett.5b03706.