Reactions of gem-Difluorinated Phosphonium Salts Induced by Light
Publication type: Journal Article
Publication date: 2016-02-10
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
26862998
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
gem-Difluorinated phosphonium salts, which are readily obtained from aldehydes and difluoromethylene phosphobetaine, can serve as a source of radicals under reductive conditions. An iridium complex or Hantzsch ester was used as a one-electron reducing agent when irradiated with visible light. The fluorinated radicals were trapped with various alkenes, leading to products either via a photoredox cycle (for the iridium catalyst) or via a hydrogen atom transfer (for the Hantzsch ester).
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95
Total citations:
95
Citations from 2025:
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(10.52%)
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GOST
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Panferova L. I. et al. Reactions of gem-Difluorinated Phosphonium Salts Induced by Light // Organic Letters. 2016. Vol. 18. No. 5. pp. 996-999.
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Panferova L. I., Tsymbal A. V., Levin V. V., Struchkova M. I., Dilman A. D. Reactions of gem-Difluorinated Phosphonium Salts Induced by Light // Organic Letters. 2016. Vol. 18. No. 5. pp. 996-999.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.orglett.6b00117
UR - https://doi.org/10.1021/acs.orglett.6b00117
TI - Reactions of gem-Difluorinated Phosphonium Salts Induced by Light
T2 - Organic Letters
AU - Panferova, Liubov I
AU - Tsymbal, Artem V
AU - Levin, Vitalij V
AU - Struchkova, Marina I.
AU - Dilman, Alexander D
PY - 2016
DA - 2016/02/10
PB - American Chemical Society (ACS)
SP - 996-999
IS - 5
VL - 18
PMID - 26862998
SN - 1523-7060
SN - 1523-7052
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2016_Panferova,
author = {Liubov I Panferova and Artem V Tsymbal and Vitalij V Levin and Marina I. Struchkova and Alexander D Dilman},
title = {Reactions of gem-Difluorinated Phosphonium Salts Induced by Light},
journal = {Organic Letters},
year = {2016},
volume = {18},
publisher = {American Chemical Society (ACS)},
month = {feb},
url = {https://doi.org/10.1021/acs.orglett.6b00117},
number = {5},
pages = {996--999},
doi = {10.1021/acs.orglett.6b00117}
}
Cite this
MLA
Copy
Panferova, Liubov I., et al. “Reactions of gem-Difluorinated Phosphonium Salts Induced by Light.” Organic Letters, vol. 18, no. 5, Feb. 2016, pp. 996-999. https://doi.org/10.1021/acs.orglett.6b00117.
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