Organic Letters

, volume 18 , issue 18 , pages 4470-4473

Free-Radical Triggered Ordered Domino Reaction: An Approach to C–C Bond Formation via Selective Functionalization of α-Hydroxyl-(sp³)C–H in Fluorinated Alcohols

Zhengbao Xu ¹

Zhaojia Hang ¹

Zhongquan Liu ¹

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State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, P. R. China |

Publication type: Journal Article

Publication date: 2016-08-25

American Chemical Society (ACS)

Organic Letters

scimago Q1

wos Q1

SJR: 1.235

CiteScore: 8.7

Impact factor: 5.0

ISSN: 15237060, 15237052

DOI: 10.1021/acs.orglett.6b01946

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PubMed ID: 27560642

Organic Chemistry

Biochemistry

Physical and Theoretical Chemistry

Abstract

A free-radical mediated highly ordered radical addition/cyclization/(sp(3))C-C(sp(3)) formation domino reaction is developed. Three new C-C bonds are formed one by one in a mixed system. Furthermore, it represents the first example of cascade C-C bond formation via selective functionalization of α-hydroxyl-C(sp(3))-H in fluorinated alcohols.

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Xu Z., Hang Z., Liu Z. Free-Radical Triggered Ordered Domino Reaction: An Approach to C–C Bond Formation via Selective Functionalization of α-Hydroxyl-(sp3)C–H in Fluorinated Alcohols // Organic Letters. 2016. Vol. 18. No. 18. pp. 4470-4473.

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RIS |

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RIS Copy

TY - JOUR

DO - 10.1021/acs.orglett.6b01946

UR - https://doi.org/10.1021/acs.orglett.6b01946

TI - Free-Radical Triggered Ordered Domino Reaction: An Approach to C–C Bond Formation via Selective Functionalization of α-Hydroxyl-(sp3)C–H in Fluorinated Alcohols

T2 - Organic Letters

AU - Xu, Zhengbao

AU - Hang, Zhaojia

AU - Liu, Zhongquan

PY - 2016

DA - 2016/08/25

PB - American Chemical Society (ACS)

SP - 4470-4473

IS - 18

VL - 18

PMID - 27560642

SN - 1523-7060

SN - 1523-7052

ER -

BibTex |

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BibTex (up to 50 authors) Copy

@article{2016_Xu,

author = {Zhengbao Xu and Zhaojia Hang and Zhongquan Liu},

title = {Free-Radical Triggered Ordered Domino Reaction: An Approach to C–C Bond Formation via Selective Functionalization of α-Hydroxyl-(sp3)C–H in Fluorinated Alcohols},

journal = {Organic Letters},

year = {2016},

volume = {18},

publisher = {American Chemical Society (ACS)},

month = {aug},

url = {https://doi.org/10.1021/acs.orglett.6b01946},

number = {18},

pages = {4470--4473},

doi = {10.1021/acs.orglett.6b01946}

}

MLA

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MLA Copy

Xu, Zhengbao, et al. “Free-Radical Triggered Ordered Domino Reaction: An Approach to C–C Bond Formation via Selective Functionalization of α-Hydroxyl-(sp3)C–H in Fluorinated Alcohols.” Organic Letters, vol. 18, no. 18, Aug. 2016, pp. 4470-4473. https://doi.org/10.1021/acs.orglett.6b01946.

Publisher

American Chemical Society (ACS)

Journal

Organic Letters

scimago Q1

wos Q1

SJR

1.235

CiteScore

8.7

Impact factor

5.0

ISSN

15237060 (Print)

15237052 (Electronic)