Synthesis of Diaryl Diazaphosphonates via 1,6-Hydrophosphonylation of p-Quinone Methides with N-Heterocyclic Phosphine–Thioureas
Publication type: Journal Article
Publication date: 2017-02-08
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
28177635
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
A mild, efficient method for the synthesis of diaryl diazaphosphonates via 1,6-hydrophosphonylation/aromatization of p-quinone methides (p-QMs) with N-heterocyclic phosphine-thioureas has been developed. This transformation proceeds without any additive or catalyst under mild reaction conditions and tolerates a wide range of p-QMs. This methodology provides a straightforward access to diaryl phosphonate derivatives in good to excellent yields (up to 99%).
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56
Total citations:
56
Citations from 2025:
3
(5.36%)
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GOST
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Molleti N., Huang H. Synthesis of Diaryl Diazaphosphonates via 1,6-Hydrophosphonylation of p-Quinone Methides with N-Heterocyclic Phosphine–Thioureas // Organic Letters. 2017. Vol. 19. No. 4. pp. 958-961.
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Molleti N., Huang H. Synthesis of Diaryl Diazaphosphonates via 1,6-Hydrophosphonylation of p-Quinone Methides with N-Heterocyclic Phosphine–Thioureas // Organic Letters. 2017. Vol. 19. No. 4. pp. 958-961.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.orglett.7b00261
UR - https://doi.org/10.1021/acs.orglett.7b00261
TI - Synthesis of Diaryl Diazaphosphonates via 1,6-Hydrophosphonylation of p-Quinone Methides with N-Heterocyclic Phosphine–Thioureas
T2 - Organic Letters
AU - Molleti, Nagaraju
AU - Huang, Hai
PY - 2017
DA - 2017/02/08
PB - American Chemical Society (ACS)
SP - 958-961
IS - 4
VL - 19
PMID - 28177635
SN - 1523-7060
SN - 1523-7052
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2017_Molleti,
author = {Nagaraju Molleti and Hai Huang},
title = {Synthesis of Diaryl Diazaphosphonates via 1,6-Hydrophosphonylation of p-Quinone Methides with N-Heterocyclic Phosphine–Thioureas},
journal = {Organic Letters},
year = {2017},
volume = {19},
publisher = {American Chemical Society (ACS)},
month = {feb},
url = {https://doi.org/10.1021/acs.orglett.7b00261},
number = {4},
pages = {958--961},
doi = {10.1021/acs.orglett.7b00261}
}
Cite this
MLA
Copy
Molleti, Nagaraju, and Hai Huang. “Synthesis of Diaryl Diazaphosphonates via 1,6-Hydrophosphonylation of p-Quinone Methides with N-Heterocyclic Phosphine–Thioureas.” Organic Letters, vol. 19, no. 4, Feb. 2017, pp. 958-961. https://doi.org/10.1021/acs.orglett.7b00261.