volume 19 issue 13 pages 3656-3659

Transfer Hydrogenation of Carbonyl Derivatives Catalyzed by an Inexpensive Phosphine-Free Manganese Precatalyst.

Publication typeJournal Article
Publication date2017-06-20
scimago Q1
wos Q1
SJR1.235
CiteScore8.7
Impact factor5.0
ISSN15237060, 15237052
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
A very simple and inexpensive catalytic system based on abundant manganese as transition metal and on an inexpensive phosphine-free bidendate ligand, 2-(aminomethyl)pyridine, has been developed for the reduction of a large variety of carbonyl derivatives with 2-propanol as hydrogen donor. Remarkably, the reaction proceeds at room temperature with low catalyst loading (down to 0.1 mol %) and exhibits a good tolerance toward functional groups. High TON (2000) and TOF (3600 h-1) were obtained.
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GOST Copy
Bruneau Voisine A. et al. Transfer Hydrogenation of Carbonyl Derivatives Catalyzed by an Inexpensive Phosphine-Free Manganese Precatalyst. // Organic Letters. 2017. Vol. 19. No. 13. pp. 3656-3659.
GOST all authors (up to 50) Copy
Bruneau Voisine A., Wang D., Dorcet V., Roisnel T., Darcel C., Sortais J. Transfer Hydrogenation of Carbonyl Derivatives Catalyzed by an Inexpensive Phosphine-Free Manganese Precatalyst. // Organic Letters. 2017. Vol. 19. No. 13. pp. 3656-3659.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1021/acs.orglett.7b01657
UR - https://doi.org/10.1021/acs.orglett.7b01657
TI - Transfer Hydrogenation of Carbonyl Derivatives Catalyzed by an Inexpensive Phosphine-Free Manganese Precatalyst.
T2 - Organic Letters
AU - Bruneau Voisine, Antoine
AU - Wang, Ding
AU - Dorcet, Vincent
AU - Roisnel, Thierry
AU - Darcel, Christophe
AU - Sortais, Jean-Baptiste
PY - 2017
DA - 2017/06/20
PB - American Chemical Society (ACS)
SP - 3656-3659
IS - 13
VL - 19
PMID - 28632391
SN - 1523-7060
SN - 1523-7052
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2017_Bruneau Voisine,
author = {Antoine Bruneau Voisine and Ding Wang and Vincent Dorcet and Thierry Roisnel and Christophe Darcel and Jean-Baptiste Sortais},
title = {Transfer Hydrogenation of Carbonyl Derivatives Catalyzed by an Inexpensive Phosphine-Free Manganese Precatalyst.},
journal = {Organic Letters},
year = {2017},
volume = {19},
publisher = {American Chemical Society (ACS)},
month = {jun},
url = {https://doi.org/10.1021/acs.orglett.7b01657},
number = {13},
pages = {3656--3659},
doi = {10.1021/acs.orglett.7b01657}
}
MLA
Cite this
MLA Copy
Bruneau Voisine, Antoine, et al. “Transfer Hydrogenation of Carbonyl Derivatives Catalyzed by an Inexpensive Phosphine-Free Manganese Precatalyst..” Organic Letters, vol. 19, no. 13, Jun. 2017, pp. 3656-3659. https://doi.org/10.1021/acs.orglett.7b01657.