Insight into Copper Catalysis: In Situ Formed Nano Cu2O in Suzuki–Miyaura Cross-Coupling of Aryl/Indolyl Boronates
Тип публикации: Journal Article
Дата публикации: 2017-07-19
SCImago Q1
Tоп 10% SCImago
WOS Q1
БС1
SJR: 1.007
CiteScore: 8.7
Impact factor: 5
ISSN: 15237060, 15237052
PubMed ID:
28723102
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Краткое описание
A ligand-free copper catalyzed Suzuki-Miyaura coupling of 3,5-diiodopyridine with aryl and indole boronates has been explored in good to excellent yields. In situ generation of nano-Cu2O from CuCl2 under the reaction conditions has been discovered for the first time. The generality of the reaction was further demonstrated by the arylation of 5-iodopyrimidine, iodopyridines, iodobenzenes, and diiodobenzenes and resulted in good to moderate yields. Moreover, bisindole alkaloid Scalaridine A has been successfully synthesized in 60% overall yield.
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ГОСТ
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Ranjani G., Nagarajan R. Insight into Copper Catalysis: In Situ Formed Nano Cu2O in Suzuki–Miyaura Cross-Coupling of Aryl/Indolyl Boronates // Organic Letters. 2017. Vol. 19. No. 15. pp. 3974-3977.
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Ranjani G., Nagarajan R. Insight into Copper Catalysis: In Situ Formed Nano Cu2O in Suzuki–Miyaura Cross-Coupling of Aryl/Indolyl Boronates // Organic Letters. 2017. Vol. 19. No. 15. pp. 3974-3977.
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RIS
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TY - JOUR
DO - 10.1021/acs.orglett.7b01669
UR - https://doi.org/10.1021/acs.orglett.7b01669
TI - Insight into Copper Catalysis: In Situ Formed Nano Cu2O in Suzuki–Miyaura Cross-Coupling of Aryl/Indolyl Boronates
T2 - Organic Letters
AU - Ranjani, Ganapathy
AU - Nagarajan, Rajagopal
PY - 2017
DA - 2017/07/19
PB - American Chemical Society (ACS)
SP - 3974-3977
IS - 15
VL - 19
PMID - 28723102
SN - 1523-7060
SN - 1523-7052
ER -
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BibTex (до 50 авторов)
Скопировать
@article{2017_Ranjani,
author = {Ganapathy Ranjani and Rajagopal Nagarajan},
title = {Insight into Copper Catalysis: In Situ Formed Nano Cu2O in Suzuki–Miyaura Cross-Coupling of Aryl/Indolyl Boronates},
journal = {Organic Letters},
year = {2017},
volume = {19},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://doi.org/10.1021/acs.orglett.7b01669},
number = {15},
pages = {3974--3977},
doi = {10.1021/acs.orglett.7b01669}
}
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MLA
Скопировать
Ranjani, Ganapathy, and Rajagopal Nagarajan. “Insight into Copper Catalysis: In Situ Formed Nano Cu2O in Suzuki–Miyaura Cross-Coupling of Aryl/Indolyl Boronates.” Organic Letters, vol. 19, no. 15, Jul. 2017, pp. 3974-3977. https://doi.org/10.1021/acs.orglett.7b01669.
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