volume 19 issue 23 pages 6344-6347

Bromide-Mediated C–H Bond Functionalization: Intermolecular Annulation of Phenylethanone Derivatives with Alkynes for the Synthesis of 1-Naphthols

Publication typeJournal Article
Publication date2017-11-17
scimago Q1
wos Q1
SJR1.235
CiteScore8.7
Impact factor5.0
ISSN15237060, 15237052
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
Bromide-mediated intermolecular annulation of phenylethanone derivatives with alkynes has been developed, which allows for the regioselective formation of polysubstituted 1-naphthols. The usage of readily available bromine catalyst, broad substrate scope, and mild conditions make this protocol very practical. Mechanistic investigations reveal that the bromination of phenylethanone derivatives occurs to yield bromo-substituted intermediates, which react in situ with alkynes to furnish the desired 1-naphthols.
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GOST |
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GOST Copy
Lu T. et al. Bromide-Mediated C–H Bond Functionalization: Intermolecular Annulation of Phenylethanone Derivatives with Alkynes for the Synthesis of 1-Naphthols // Organic Letters. 2017. Vol. 19. No. 23. pp. 6344-6347.
GOST all authors (up to 50) Copy
Lu T., Jiang Ya. T., Ma F. P., Tang Z. J., Liu K., Wang Y., Wang B. Bromide-Mediated C–H Bond Functionalization: Intermolecular Annulation of Phenylethanone Derivatives with Alkynes for the Synthesis of 1-Naphthols // Organic Letters. 2017. Vol. 19. No. 23. pp. 6344-6347.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1021/acs.orglett.7b03186
UR - https://doi.org/10.1021/acs.orglett.7b03186
TI - Bromide-Mediated C–H Bond Functionalization: Intermolecular Annulation of Phenylethanone Derivatives with Alkynes for the Synthesis of 1-Naphthols
T2 - Organic Letters
AU - Lu, Tao
AU - Jiang, Ya Ting
AU - Ma, Feng Ping
AU - Tang, Zi Jing
AU - Liu, Kuang
AU - Wang, Yu-Xuan
AU - Wang, Bin
PY - 2017
DA - 2017/11/17
PB - American Chemical Society (ACS)
SP - 6344-6347
IS - 23
VL - 19
PMID - 29148795
SN - 1523-7060
SN - 1523-7052
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2017_Lu,
author = {Tao Lu and Ya Ting Jiang and Feng Ping Ma and Zi Jing Tang and Kuang Liu and Yu-Xuan Wang and Bin Wang},
title = {Bromide-Mediated C–H Bond Functionalization: Intermolecular Annulation of Phenylethanone Derivatives with Alkynes for the Synthesis of 1-Naphthols},
journal = {Organic Letters},
year = {2017},
volume = {19},
publisher = {American Chemical Society (ACS)},
month = {nov},
url = {https://doi.org/10.1021/acs.orglett.7b03186},
number = {23},
pages = {6344--6347},
doi = {10.1021/acs.orglett.7b03186}
}
MLA
Cite this
MLA Copy
Lu, Tao, et al. “Bromide-Mediated C–H Bond Functionalization: Intermolecular Annulation of Phenylethanone Derivatives with Alkynes for the Synthesis of 1-Naphthols.” Organic Letters, vol. 19, no. 23, Nov. 2017, pp. 6344-6347. https://doi.org/10.1021/acs.orglett.7b03186.