volume 20 issue 8 pages 2395-2398

Photoredox-Induced Intramolecular 1,5-H Transfer Reaction of Aryl Iodides for the Synthesis of Spirocyclic γ-Lactams

Publication typeJournal Article
Publication date2018-04-03
scimago Q1
wos Q1
SJR1.235
CiteScore8.7
Impact factor5.0
ISSN15237060, 15237052
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
This work develops a photocatalysis method for the synthesis of γ-spirolactams through a tandem intramolecular 1,5-HAT reaction-cyclization process. A variety of novel γ-spirolactams are prepared in good to excellent yields with this method. This transformation features mild reaction conditions and exceptional functional group tolerance. Additionally, γ-terpinene is applied to this transformation as a hydrogen atom donor for the first time.
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GOST |
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GOST Copy
Chen J. Q. et al. Photoredox-Induced Intramolecular 1,5-H Transfer Reaction of Aryl Iodides for the Synthesis of Spirocyclic γ-Lactams // Organic Letters. 2018. Vol. 20. No. 8. pp. 2395-2398.
GOST all authors (up to 50) Copy
Chen J. Q., Chang R., Lin J. B., Luo Y. C., Xu P. F. Photoredox-Induced Intramolecular 1,5-H Transfer Reaction of Aryl Iodides for the Synthesis of Spirocyclic γ-Lactams // Organic Letters. 2018. Vol. 20. No. 8. pp. 2395-2398.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1021/acs.orglett.8b00731
UR - https://doi.org/10.1021/acs.orglett.8b00731
TI - Photoredox-Induced Intramolecular 1,5-H Transfer Reaction of Aryl Iodides for the Synthesis of Spirocyclic γ-Lactams
T2 - Organic Letters
AU - Chen, Jian Qiang
AU - Chang, Rui
AU - Lin, Jun Bing
AU - Luo, Yong Chun
AU - Xu, Peng Fei
PY - 2018
DA - 2018/04/03
PB - American Chemical Society (ACS)
SP - 2395-2398
IS - 8
VL - 20
PMID - 29613807
SN - 1523-7060
SN - 1523-7052
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2018_Chen,
author = {Jian Qiang Chen and Rui Chang and Jun Bing Lin and Yong Chun Luo and Peng Fei Xu},
title = {Photoredox-Induced Intramolecular 1,5-H Transfer Reaction of Aryl Iodides for the Synthesis of Spirocyclic γ-Lactams},
journal = {Organic Letters},
year = {2018},
volume = {20},
publisher = {American Chemical Society (ACS)},
month = {apr},
url = {https://doi.org/10.1021/acs.orglett.8b00731},
number = {8},
pages = {2395--2398},
doi = {10.1021/acs.orglett.8b00731}
}
MLA
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MLA Copy
Chen, Jian Qiang, et al. “Photoredox-Induced Intramolecular 1,5-H Transfer Reaction of Aryl Iodides for the Synthesis of Spirocyclic γ-Lactams.” Organic Letters, vol. 20, no. 8, Apr. 2018, pp. 2395-2398. https://doi.org/10.1021/acs.orglett.8b00731.