Organic Letters, volume 20, issue 10, pages 3017-3020
Pd(II)-Catalyzed Cyclization–Oxidation of Urea-Tethered Alkylidenecyclopropanes
Publication type: Journal Article
Publication date: 2018-05-03
Journal:
Organic Letters
Q1
Q1
SJR: 1.245
CiteScore: 9.3
Impact factor: 4.9
ISSN: 15237060, 15237052
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
A Pd(OAc)2-catalyzed intramolecular oxidative cyclization of urea-tethered alkylidenecyclopropanes with urea as a nitrogen source through a Pd(II)/Pd(IV) catalytic cycle has been presented, giving the corresponding cyclobuta[ b]indoline derivatives in moderate to good yields with a broad substrate scope. The reaction proceeds through a ring expansion of alkylidenecyclopropane along with the nucleophilic attack of nitrogen atom onto the in situ generated palladium carbenoid species as well as an oxidation process.
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GOST
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Tao L., Shi M. Pd(II)-Catalyzed Cyclization–Oxidation of Urea-Tethered Alkylidenecyclopropanes // Organic Letters. 2018. Vol. 20. No. 10. pp. 3017-3020.
GOST all authors (up to 50)
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Tao L., Shi M. Pd(II)-Catalyzed Cyclization–Oxidation of Urea-Tethered Alkylidenecyclopropanes // Organic Letters. 2018. Vol. 20. No. 10. pp. 3017-3020.
Cite this
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TY - JOUR
DO - 10.1021/acs.orglett.8b01047
UR - https://doi.org/10.1021/acs.orglett.8b01047
TI - Pd(II)-Catalyzed Cyclization–Oxidation of Urea-Tethered Alkylidenecyclopropanes
T2 - Organic Letters
AU - Tao, Leyi
AU - Shi, Min
PY - 2018
DA - 2018/05/03
PB - American Chemical Society (ACS)
SP - 3017-3020
IS - 10
VL - 20
SN - 1523-7060
SN - 1523-7052
ER -
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BibTex (up to 50 authors)
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@article{2018_Tao,
author = {Leyi Tao and Min Shi},
title = {Pd(II)-Catalyzed Cyclization–Oxidation of Urea-Tethered Alkylidenecyclopropanes},
journal = {Organic Letters},
year = {2018},
volume = {20},
publisher = {American Chemical Society (ACS)},
month = {may},
url = {https://doi.org/10.1021/acs.orglett.8b01047},
number = {10},
pages = {3017--3020},
doi = {10.1021/acs.orglett.8b01047}
}
Cite this
MLA
Copy
Tao, Leyi, and Min Shi. “Pd(II)-Catalyzed Cyclization–Oxidation of Urea-Tethered Alkylidenecyclopropanes.” Organic Letters, vol. 20, no. 10, May. 2018, pp. 3017-3020. https://doi.org/10.1021/acs.orglett.8b01047.