Highly Regio- and Stereoselective Heterogeneous Hydrosilylation of Terminal Alkynes over Cobalt-Metalated Porous Organic Polymer
Publication type: Journal Article
Publication date: 2018-07-31
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
30063365
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
A cobalt/POL-PPh3 catalyzed ( E)-selective hydrosilylation of alkynes with PhSiH3 has been developed for the synthesis of ( E)-β-vinylsilanes with high regio- and stereoselectivity and wide functional group tolerance. It is the first report of using porous organic polymer as a recyclable regio- and stereoselective and efficient ligand in hydrosilylation reactions in which the polymer could be recycled numerous times in a continuous flow system without loss of activity and selectivity. The earth-abundant base-metal catalyst, coordinated by heterogeneous recyclable ligand, shows promise for industrial application.
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46
Total citations:
46
Citations from 2024:
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(17.39%)
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MLA
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GOST
Copy
Li R. H. et al. Highly Regio- and Stereoselective Heterogeneous Hydrosilylation of Terminal Alkynes over Cobalt-Metalated Porous Organic Polymer // Organic Letters. 2018. Vol. 20. No. 16. pp. 5023-5026.
GOST all authors (up to 50)
Copy
Li R. H., An X. M., Yang Y., Li D. C., Hu Z. L., Zhan Z. Highly Regio- and Stereoselective Heterogeneous Hydrosilylation of Terminal Alkynes over Cobalt-Metalated Porous Organic Polymer // Organic Letters. 2018. Vol. 20. No. 16. pp. 5023-5026.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.orglett.8b02176
UR - https://doi.org/10.1021/acs.orglett.8b02176
TI - Highly Regio- and Stereoselective Heterogeneous Hydrosilylation of Terminal Alkynes over Cobalt-Metalated Porous Organic Polymer
T2 - Organic Letters
AU - Li, Ren Hao
AU - An, Xiao Ming
AU - Yang, Ying
AU - Li, Ding Chang
AU - Hu, Zi Lin
AU - Zhan, Zhuang-ping
PY - 2018
DA - 2018/07/31
PB - American Chemical Society (ACS)
SP - 5023-5026
IS - 16
VL - 20
PMID - 30063365
SN - 1523-7060
SN - 1523-7052
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2018_Li,
author = {Ren Hao Li and Xiao Ming An and Ying Yang and Ding Chang Li and Zi Lin Hu and Zhuang-ping Zhan},
title = {Highly Regio- and Stereoselective Heterogeneous Hydrosilylation of Terminal Alkynes over Cobalt-Metalated Porous Organic Polymer},
journal = {Organic Letters},
year = {2018},
volume = {20},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://doi.org/10.1021/acs.orglett.8b02176},
number = {16},
pages = {5023--5026},
doi = {10.1021/acs.orglett.8b02176}
}
Cite this
MLA
Copy
Li, Ren Hao, et al. “Highly Regio- and Stereoselective Heterogeneous Hydrosilylation of Terminal Alkynes over Cobalt-Metalated Porous Organic Polymer.” Organic Letters, vol. 20, no. 16, Jul. 2018, pp. 5023-5026. https://doi.org/10.1021/acs.orglett.8b02176.