Tandem Copper-Catalyzed Conjugate Addition-Diastereoselective Protonation of (E)-α-Trialkylsilyl-β-Alkyl(Aryl)-α,β-Unsaturated Esters
Publication type: Journal Article
Publication date: 2018-09-14
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
30215526
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
A tandem Cu(I)-catalyzed conjugate addition of Kharasch reagents/diastereoselective protonation of ( E)-α-trialkylsilyl-β-alkyl(aryl)-α,β-unsaturated esters afforded the saturated products with d.r. values of >20:1 favoring the anti-diastereomer in modest to excellent isolated yields.
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Total citations:
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Citations from 2024:
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(16.67%)
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Johnson D. A., Jennings M. P. Tandem Copper-Catalyzed Conjugate Addition-Diastereoselective Protonation of (E)-α-Trialkylsilyl-β-Alkyl(Aryl)-α,β-Unsaturated Esters // Organic Letters. 2018. Vol. 20. No. 19. pp. 6099-6103.
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Johnson D. A., Jennings M. P. Tandem Copper-Catalyzed Conjugate Addition-Diastereoselective Protonation of (E)-α-Trialkylsilyl-β-Alkyl(Aryl)-α,β-Unsaturated Esters // Organic Letters. 2018. Vol. 20. No. 19. pp. 6099-6103.
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TY - JOUR
DO - 10.1021/acs.orglett.8b02527
UR - https://doi.org/10.1021/acs.orglett.8b02527
TI - Tandem Copper-Catalyzed Conjugate Addition-Diastereoselective Protonation of (E)-α-Trialkylsilyl-β-Alkyl(Aryl)-α,β-Unsaturated Esters
T2 - Organic Letters
AU - Johnson, David A.
AU - Jennings, Michael P
PY - 2018
DA - 2018/09/14
PB - American Chemical Society (ACS)
SP - 6099-6103
IS - 19
VL - 20
PMID - 30215526
SN - 1523-7060
SN - 1523-7052
ER -
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BibTex (up to 50 authors)
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@article{2018_Johnson,
author = {David A. Johnson and Michael P Jennings},
title = {Tandem Copper-Catalyzed Conjugate Addition-Diastereoselective Protonation of (E)-α-Trialkylsilyl-β-Alkyl(Aryl)-α,β-Unsaturated Esters},
journal = {Organic Letters},
year = {2018},
volume = {20},
publisher = {American Chemical Society (ACS)},
month = {sep},
url = {https://doi.org/10.1021/acs.orglett.8b02527},
number = {19},
pages = {6099--6103},
doi = {10.1021/acs.orglett.8b02527}
}
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MLA
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Johnson, David A., and Michael P Jennings. “Tandem Copper-Catalyzed Conjugate Addition-Diastereoselective Protonation of (E)-α-Trialkylsilyl-β-Alkyl(Aryl)-α,β-Unsaturated Esters.” Organic Letters, vol. 20, no. 19, Sep. 2018, pp. 6099-6103. https://doi.org/10.1021/acs.orglett.8b02527.