In Situ Formation of RSCl/ArSeCl and Their Application to the Synthesis of 4-Chalcogenylisocumarins/Pyrones from o-(1-Alkynyl)benzoates and (Z)-2-Alken-4-ynoates
Publication type: Journal Article
Publication date: 2019-05-03
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
31050294
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
The reaction of diorganyl disulfides or diselenides with PhICl2 in acetonitrile was found for the first time to lead to the in situ formation of organosulfenyl chloride or selenenyl chloride, which enables the regioselective intramolecular chalcogenylacyloxylation of alkynes resulting in the formation of 4-chalcogenylisocumarins/pyrones in good to excellent yields under metal-free conditions.
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68
Total citations:
68
Citations from 2024:
17
(25%)
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GOST
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Xing L. et al. In Situ Formation of RSCl/ArSeCl and Their Application to the Synthesis of 4-Chalcogenylisocumarins/Pyrones from o-(1-Alkynyl)benzoates and (Z)-2-Alken-4-ynoates // Organic Letters. 2019. Vol. 21. No. 10. pp. 3620-3624.
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Xing L., Zhang Y., Li B., Du Y. In Situ Formation of RSCl/ArSeCl and Their Application to the Synthesis of 4-Chalcogenylisocumarins/Pyrones from o-(1-Alkynyl)benzoates and (Z)-2-Alken-4-ynoates // Organic Letters. 2019. Vol. 21. No. 10. pp. 3620-3624.
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TY - JOUR
DO - 10.1021/acs.orglett.9b01046
UR - https://doi.org/10.1021/acs.orglett.9b01046
TI - In Situ Formation of RSCl/ArSeCl and Their Application to the Synthesis of 4-Chalcogenylisocumarins/Pyrones from o-(1-Alkynyl)benzoates and (Z)-2-Alken-4-ynoates
T2 - Organic Letters
AU - Xing, Linlin
AU - Zhang, Yong
AU - Li, Bing
AU - Du, Yunfei
PY - 2019
DA - 2019/05/03
PB - American Chemical Society (ACS)
SP - 3620-3624
IS - 10
VL - 21
PMID - 31050294
SN - 1523-7060
SN - 1523-7052
ER -
Cite this
BibTex (up to 50 authors)
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@article{2019_Xing,
author = {Linlin Xing and Yong Zhang and Bing Li and Yunfei Du},
title = {In Situ Formation of RSCl/ArSeCl and Their Application to the Synthesis of 4-Chalcogenylisocumarins/Pyrones from o-(1-Alkynyl)benzoates and (Z)-2-Alken-4-ynoates},
journal = {Organic Letters},
year = {2019},
volume = {21},
publisher = {American Chemical Society (ACS)},
month = {may},
url = {https://doi.org/10.1021/acs.orglett.9b01046},
number = {10},
pages = {3620--3624},
doi = {10.1021/acs.orglett.9b01046}
}
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MLA
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Xing, Linlin, et al. “In Situ Formation of RSCl/ArSeCl and Their Application to the Synthesis of 4-Chalcogenylisocumarins/Pyrones from o-(1-Alkynyl)benzoates and (Z)-2-Alken-4-ynoates.” Organic Letters, vol. 21, no. 10, May. 2019, pp. 3620-3624. https://doi.org/10.1021/acs.orglett.9b01046.