Gold(I)-Catalyzed Oxidation of Acyl Acetylenes to Vicinal Tricarbonyls.
Publication type: Journal Article
Publication date: 2019-05-15
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
31090426
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
Efficient gold(I)-catalyzed oxidation of COR2-functionalized internal alkynes to vicinal tricarbonyl compounds by 2,6-dichloropyridine N-oxide proceeds under mild conditions (DCM, rt). This catalytic reaction provides a good to excellent yielding route to diverse tricarbonyls such as α,β-diketoesters, 1,2,3-triketones, and α,β-diketoamides. The utility of these compounds was also demonstrated by facile one-pot synthesis of important azaheterocyclic systems.
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32
Total citations:
32
Citations from 2024:
8
(25%)
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MLA
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GOST
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Dubovtsev A. Yu., Dar’in D., Kukushkin V. Y. Gold(I)-Catalyzed Oxidation of Acyl Acetylenes to Vicinal Tricarbonyls. // Organic Letters. 2019. Vol. 21. No. 11. pp. 4116-4119.
GOST all authors (up to 50)
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Dubovtsev A. Yu., Dar’in D., Kukushkin V. Y. Gold(I)-Catalyzed Oxidation of Acyl Acetylenes to Vicinal Tricarbonyls. // Organic Letters. 2019. Vol. 21. No. 11. pp. 4116-4119.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.orglett.9b01297
UR - https://doi.org/10.1021/acs.orglett.9b01297
TI - Gold(I)-Catalyzed Oxidation of Acyl Acetylenes to Vicinal Tricarbonyls.
T2 - Organic Letters
AU - Dubovtsev, Alexey Yu
AU - Dar’in, Dmitry
AU - Kukushkin, Vadim Yu.
PY - 2019
DA - 2019/05/15
PB - American Chemical Society (ACS)
SP - 4116-4119
IS - 11
VL - 21
PMID - 31090426
SN - 1523-7060
SN - 1523-7052
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2019_Dubovtsev,
author = {Alexey Yu Dubovtsev and Dmitry Dar’in and Vadim Yu. Kukushkin},
title = {Gold(I)-Catalyzed Oxidation of Acyl Acetylenes to Vicinal Tricarbonyls.},
journal = {Organic Letters},
year = {2019},
volume = {21},
publisher = {American Chemical Society (ACS)},
month = {may},
url = {https://doi.org/10.1021/acs.orglett.9b01297},
number = {11},
pages = {4116--4119},
doi = {10.1021/acs.orglett.9b01297}
}
Cite this
MLA
Copy
Dubovtsev, Alexey Yu., et al. “Gold(I)-Catalyzed Oxidation of Acyl Acetylenes to Vicinal Tricarbonyls..” Organic Letters, vol. 21, no. 11, May. 2019, pp. 4116-4119. https://doi.org/10.1021/acs.orglett.9b01297.