Organic Letters, volume 21, issue 20, pages 8404-8408
Iron-Catalyzed β-Alkylation of Alcohols
1
Normandie Univ., LCMT, ENSICAEN, UNICAEN, CNRS, 6 Boulevard du Maréchal Juin, 14000 Caen, France
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Publication type: Journal Article
Publication date: 2019-10-07
Journal:
Organic Letters
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 5.2
ISSN: 15237060, 15237052
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
β-Branched alkylated alcohols have been prepared in good yields using a double-hydrogen autotransfer strategy in the presence of our diaminocyclopentadienone iron tricarbonyl complex Fe1. The alkylation of some 2-arylethanol derivatives was successfully addressed with benzylic alcohols and methanol as alkylating reagents under mild conditions. Deuterium labeling experiments suggested that both alcohols (2-arylethanol and either methanol or benzyl alcohol) served as hydrogen donors in this cascade process.
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Citations by publishers
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American Chemical Society (ACS)
16 publications, 32%
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Wiley
12 publications, 24%
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9 publications, 18%
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Elsevier
8 publications, 16%
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2 publications, 4%
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Springer Nature
2 publications, 4%
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1 publication, 2%
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Bettoni L., Gaillard S., Renaud J. F. Iron-Catalyzed β-Alkylation of Alcohols // Organic Letters. 2019. Vol. 21. No. 20. pp. 8404-8408.
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Bettoni L., Gaillard S., Renaud J. F. Iron-Catalyzed β-Alkylation of Alcohols // Organic Letters. 2019. Vol. 21. No. 20. pp. 8404-8408.
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TY - JOUR
DO - 10.1021/acs.orglett.9b03171
UR - https://doi.org/10.1021/acs.orglett.9b03171
TI - Iron-Catalyzed β-Alkylation of Alcohols
T2 - Organic Letters
AU - Gaillard, Sylvain
AU - Renaud, J. F.
AU - Bettoni, Léo
PY - 2019
DA - 2019/10/07 00:00:00
PB - American Chemical Society (ACS)
SP - 8404-8408
IS - 20
VL - 21
SN - 1523-7060
SN - 1523-7052
ER -
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@article{2019_Bettoni,
author = {Sylvain Gaillard and J. F. Renaud and Léo Bettoni},
title = {Iron-Catalyzed β-Alkylation of Alcohols},
journal = {Organic Letters},
year = {2019},
volume = {21},
publisher = {American Chemical Society (ACS)},
month = {oct},
url = {https://doi.org/10.1021/acs.orglett.9b03171},
number = {20},
pages = {8404--8408},
doi = {10.1021/acs.orglett.9b03171}
}
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MLA
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Bettoni, Léo, et al. “Iron-Catalyzed β-Alkylation of Alcohols.” Organic Letters, vol. 21, no. 20, Oct. 2019, pp. 8404-8408. https://doi.org/10.1021/acs.orglett.9b03171.