volume 21 issue 23 pages 9795-9799

Chameleon-Like Activating Nature of the Spirooxindole Group in Donor–Acceptor Cyclopropanes

Publication typeJournal Article
Publication date2019-11-25
scimago Q1
wos Q1
SJR1.235
CiteScore8.7
Impact factor5.0
ISSN15237060, 15237052
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
The concept of a chameleon activating group is considered in the context of donor-acceptor cyclopropane chemistry. When spiro-conjugated with cyclopropane, oxindole can act as an acceptor or a donor depending on the electronic nature of vicinal substituents. This dichotomy is reflected in the alteration of chemoselectivity of spiro[oxindole-1,3'-cyclopropane] ring opening with nucleophiles.
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GOST Copy
Akaev A. A., Melnikov M. Y., Budynina E. M. Chameleon-Like Activating Nature of the Spirooxindole Group in Donor–Acceptor Cyclopropanes // Organic Letters. 2019. Vol. 21. No. 23. pp. 9795-9799.
GOST all authors (up to 50) Copy
Akaev A. A., Melnikov M. Y., Budynina E. M. Chameleon-Like Activating Nature of the Spirooxindole Group in Donor–Acceptor Cyclopropanes // Organic Letters. 2019. Vol. 21. No. 23. pp. 9795-9799.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1021/acs.orglett.9b04153
UR - https://doi.org/10.1021/acs.orglett.9b04153
TI - Chameleon-Like Activating Nature of the Spirooxindole Group in Donor–Acceptor Cyclopropanes
T2 - Organic Letters
AU - Akaev, Andrey A
AU - Melnikov, Mikhail Y.
AU - Budynina, Ekaterina M
PY - 2019
DA - 2019/11/25
PB - American Chemical Society (ACS)
SP - 9795-9799
IS - 23
VL - 21
PMID - 31763847
SN - 1523-7060
SN - 1523-7052
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2019_Akaev,
author = {Andrey A Akaev and Mikhail Y. Melnikov and Ekaterina M Budynina},
title = {Chameleon-Like Activating Nature of the Spirooxindole Group in Donor–Acceptor Cyclopropanes},
journal = {Organic Letters},
year = {2019},
volume = {21},
publisher = {American Chemical Society (ACS)},
month = {nov},
url = {https://doi.org/10.1021/acs.orglett.9b04153},
number = {23},
pages = {9795--9799},
doi = {10.1021/acs.orglett.9b04153}
}
MLA
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MLA Copy
Akaev, Andrey A., et al. “Chameleon-Like Activating Nature of the Spirooxindole Group in Donor–Acceptor Cyclopropanes.” Organic Letters, vol. 21, no. 23, Nov. 2019, pp. 9795-9799. https://doi.org/10.1021/acs.orglett.9b04153.