volume 1 issue 4 pages 1549-1558

Role of the Carbon Support on the Oxygen Reduction and Evolution Activities in LaNiO3 Composite Electrodes in Alkaline Solution

Publication typeJournal Article
Publication date2018-03-28
scimago Q1
wos Q2
SJR1.378
CiteScore10.2
Impact factor5.5
ISSN25740962
Materials Chemistry
Electrochemistry
Electrical and Electronic Engineering
Energy Engineering and Power Technology
Chemical Engineering (miscellaneous)
Abstract
Metal–air batteries and fuel cells show a great deal of promise in advancing low-cost, high-energy-density charge storage solutions for sustainable energy applications. To improve the activities and stabilities of electrocatalysts for the critical oxygen reduction and evolution reactions (ORR and OER, respectively), a greater understanding is needed of the catalyst/carbon interactions and carbon stability. Herein, we report how LaNiO3 (LNO) supported on nitrogen-doped carbon nanotubes (N-CNT) made from a high-yield synthesis lowers the overpotential for both the OER and ORR markedly to enable a low bifunctional window of 0.81 V at only a 51 μg cm–2 mass loading. Furthermore, the addition of LNO to the N-CNTs improves the galvanostatic stability for the OER by almost 2 orders of magnitude. The nanoscale geometries of the perovskites and the CNTs enhance the number of metal–support and charge transfer interactions and thus the activity. We use rotating ring disk electrodes (RRDEs) combined with Tafel slope ...
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GOST Copy
Alexander C. et al. Role of the Carbon Support on the Oxygen Reduction and Evolution Activities in LaNiO3 Composite Electrodes in Alkaline Solution // ACS Applied Energy Materials. 2018. Vol. 1. No. 4. pp. 1549-1558.
GOST all authors (up to 50) Copy
Alexander C., Abakumov A. M., Forslund R., Johnston K. P., Stevenson K. J. Role of the Carbon Support on the Oxygen Reduction and Evolution Activities in LaNiO3 Composite Electrodes in Alkaline Solution // ACS Applied Energy Materials. 2018. Vol. 1. No. 4. pp. 1549-1558.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1021/acsaem.7b00339
UR - https://doi.org/10.1021/acsaem.7b00339
TI - Role of the Carbon Support on the Oxygen Reduction and Evolution Activities in LaNiO3 Composite Electrodes in Alkaline Solution
T2 - ACS Applied Energy Materials
AU - Alexander, Caleb
AU - Abakumov, Artem M.
AU - Forslund, Robin
AU - Johnston, Keith P.
AU - Stevenson, Keith J
PY - 2018
DA - 2018/03/28
PB - American Chemical Society (ACS)
SP - 1549-1558
IS - 4
VL - 1
SN - 2574-0962
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2018_Alexander,
author = {Caleb Alexander and Artem M. Abakumov and Robin Forslund and Keith P. Johnston and Keith J Stevenson},
title = {Role of the Carbon Support on the Oxygen Reduction and Evolution Activities in LaNiO3 Composite Electrodes in Alkaline Solution},
journal = {ACS Applied Energy Materials},
year = {2018},
volume = {1},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021/acsaem.7b00339},
number = {4},
pages = {1549--1558},
doi = {10.1021/acsaem.7b00339}
}
MLA
Cite this
MLA Copy
Alexander, Caleb, et al. “Role of the Carbon Support on the Oxygen Reduction and Evolution Activities in LaNiO3 Composite Electrodes in Alkaline Solution.” ACS Applied Energy Materials, vol. 1, no. 4, Mar. 2018, pp. 1549-1558. https://doi.org/10.1021/acsaem.7b00339.