Enhancing Na+ Extraction Limit through High Voltage Activation of the NASICON-Type Na4MnV(PO4)3 Cathode
Maxim V. Zakharkin
1, 2
,
Oleg A. Drozhzhin
1, 2
,
Ivan V. Tereshchenko
1, 2
,
D. O. Chernyshov
3, 4
,
Dmitry Chernyshov
3, 4
,
Evgeny V. Antipov
1, 2
,
Publication type: Journal Article
Publication date: 2018-11-02
scimago Q1
wos Q2
SJR: 1.378
CiteScore: 10.2
Impact factor: 5.5
ISSN: 25740962
Materials Chemistry
Electrochemistry
Electrical and Electronic Engineering
Energy Engineering and Power Technology
Chemical Engineering (miscellaneous)
Abstract
Sodium (de)intercalation in the Na4MnV(PO4)3 NASICON-type cathode has been studied with operando synchrotron X-ray powder diffraction and galvanostatic cycling up to 3.8 and 4.0 V cutoff voltages. Symmetry reduction from rhombohedral to monoclinic was observed immediately after the start of the electrochemical desodiation, with restoring of the rhombohedral phase at 3.8 V. Cycling within the 2.5–3.8 V potential range proceeds through both solid-solution and two-phase processes. An additional voltage plateau at ∼3.9 V is observed, associated with “unlocking” of the Na1 site in the rhombohedral phase. Reverse insertion of Na+ cations proceeds via the entire solid-solution region. The experimentally observed discharge capacity increases by ≈14% after raising cutoff voltage.
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113
Total citations:
113
Citations from 2024:
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(27%)
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Zakharkin M. V. et al. Enhancing Na+ Extraction Limit through High Voltage Activation of the NASICON-Type Na4MnV(PO4)3 Cathode // ACS Applied Energy Materials. 2018. Vol. 1. No. 11. pp. 5842-5846.
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Zakharkin M. V., Drozhzhin O. A., Tereshchenko I. V., Chernyshov D. O., Chernyshov D., Abakumov A. M., Antipov E. V., Stevenson K. J. Enhancing Na+ Extraction Limit through High Voltage Activation of the NASICON-Type Na4MnV(PO4)3 Cathode // ACS Applied Energy Materials. 2018. Vol. 1. No. 11. pp. 5842-5846.
Cite this
RIS
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TY - JOUR
DO - 10.1021/acsaem.8b01269
UR - https://pubs.acs.org/doi/10.1021/acsaem.8b01269
TI - Enhancing Na+ Extraction Limit through High Voltage Activation of the NASICON-Type Na4MnV(PO4)3 Cathode
T2 - ACS Applied Energy Materials
AU - Zakharkin, Maxim V.
AU - Drozhzhin, Oleg A.
AU - Tereshchenko, Ivan V.
AU - Chernyshov, D. O.
AU - Chernyshov, Dmitry
AU - Abakumov, Artem M.
AU - Antipov, Evgeny V.
AU - Stevenson, Keith J
PY - 2018
DA - 2018/11/02
PB - American Chemical Society (ACS)
SP - 5842-5846
IS - 11
VL - 1
SN - 2574-0962
ER -
Cite this
BibTex (up to 50 authors)
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@article{2018_Zakharkin,
author = {Maxim V. Zakharkin and Oleg A. Drozhzhin and Ivan V. Tereshchenko and D. O. Chernyshov and Dmitry Chernyshov and Artem M. Abakumov and Evgeny V. Antipov and Keith J Stevenson},
title = {Enhancing Na+ Extraction Limit through High Voltage Activation of the NASICON-Type Na4MnV(PO4)3 Cathode},
journal = {ACS Applied Energy Materials},
year = {2018},
volume = {1},
publisher = {American Chemical Society (ACS)},
month = {nov},
url = {https://pubs.acs.org/doi/10.1021/acsaem.8b01269},
number = {11},
pages = {5842--5846},
doi = {10.1021/acsaem.8b01269}
}
Cite this
MLA
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Zakharkin, Maxim V., et al. “Enhancing Na+ Extraction Limit through High Voltage Activation of the NASICON-Type Na4MnV(PO4)3 Cathode.” ACS Applied Energy Materials, vol. 1, no. 11, Nov. 2018, pp. 5842-5846. https://pubs.acs.org/doi/10.1021/acsaem.8b01269.