ACS Applied Energy Materials, volume 2, issue 4, pages 2486-2493

Stable and Reproducible 2D/3D Formamidinium–Lead–Iodide Perovskite Solar Cells

Thote Abhishek 1
Jeon Il 1
Lee Jinwook 2
Seo Seungju 1
Yang Yang 2
Maruyama Shigeo 1, 3
1
 
Department of Mechanical Engineering, School of Engineering, The University of Tokyo, Tokyo 113-8656, Japan
2
 
Department of Materials Science and Engineering and California Nano Systems Institute, University of California, Los Angeles, California 90095, United States
3
 
Energy Nano Engineering Laboratory, National Institute of Advanced Industrial Science and Technology (AIST), Ibaraki 305-8564, Japan
Publication typeJournal Article
Publication date2019-03-08
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor6.4
ISSN25740962
Materials Chemistry
Electrochemistry
Electrical and Electronic Engineering
Energy Engineering and Power Technology
Chemical Engineering (miscellaneous)
Abstract
2D perovskite-stabilized FACsPbI3 (FA = formamidinium) perovskite solar cells were fabricated in both normal-type and inverted-type architectures. While the normal-type devices exhibited a high power conversion efficiency of 20.2%, their reproducibility was limited. On the other hand, the inverted-type devices exhibited an efficiency of 18.2% with a greater stability and higher reproducibility than those of the normal-type devices. The reduced reproducibility of the normal-type devices was associated with the crack formation on the perovskite films during a spin-coating process. The hardness of both the perovskite and the sublayer was directly linked to the crack formation. Inverted-type 2D/3D FACsPbI3 with ozone-treated poly(triarylamine) as sublayer exhibited the highest phase stability owing to the hydrophobic nature of poly(triarylamine) and improved energy level alignment upon an ozone treatment. In addition, strong interaction between phenethylamine cations of the 2D perovskite and of the 3D FACsPbI...

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Thote A. et al. Stable and Reproducible 2D/3D Formamidinium–Lead–Iodide Perovskite Solar Cells // ACS Applied Energy Materials. 2019. Vol. 2. No. 4. pp. 2486-2493.
GOST all authors (up to 50) Copy
Thote A., Jeon I., Lee J., Seo S., Lin H., Yang Y., Daiguji H., Maruyama S., MATSUO Y. Stable and Reproducible 2D/3D Formamidinium–Lead–Iodide Perovskite Solar Cells // ACS Applied Energy Materials. 2019. Vol. 2. No. 4. pp. 2486-2493.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1021/acsaem.8b01964
UR - https://doi.org/10.1021%2Facsaem.8b01964
TI - Stable and Reproducible 2D/3D Formamidinium–Lead–Iodide Perovskite Solar Cells
T2 - ACS Applied Energy Materials
AU - Thote, Abhishek
AU - Jeon, Il
AU - Lin, Hao-Sheng
AU - Yang, Yang
AU - Daiguji, Hirofumi
AU - Maruyama, Shigeo
AU - MATSUO, Yutaka
AU - Lee, Jinwook
AU - Seo, Seungju
PY - 2019
DA - 2019/03/08 00:00:00
PB - American Chemical Society (ACS)
SP - 2486-2493
IS - 4
VL - 2
SN - 2574-0962
ER -
BibTex |
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BibTex Copy
@article{2019_Thote,
author = {Abhishek Thote and Il Jeon and Hao-Sheng Lin and Yang Yang and Hirofumi Daiguji and Shigeo Maruyama and Yutaka MATSUO and Jinwook Lee and Seungju Seo},
title = {Stable and Reproducible 2D/3D Formamidinium–Lead–Iodide Perovskite Solar Cells},
journal = {ACS Applied Energy Materials},
year = {2019},
volume = {2},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021%2Facsaem.8b01964},
number = {4},
pages = {2486--2493},
doi = {10.1021/acsaem.8b01964}
}
MLA
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MLA Copy
Thote, Abhishek, et al. “Stable and Reproducible 2D/3D Formamidinium–Lead–Iodide Perovskite Solar Cells.” ACS Applied Energy Materials, vol. 2, no. 4, Mar. 2019, pp. 2486-2493. https://doi.org/10.1021%2Facsaem.8b01964.
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