Investigation of NaTiOPO4 as Anode for Sodium-Ion Batteries: A Solid Electrolyte Interphase Free Material?
Тип публикации: Journal Article
Дата публикации: 2019-02-05
scimago Q1
wos Q2
БС1
SJR: 1.378
CiteScore: 10.2
Impact factor: 5.5
ISSN: 25740962
Materials Chemistry
Electrochemistry
Electrical and Electronic Engineering
Energy Engineering and Power Technology
Chemical Engineering (miscellaneous)
Краткое описание
Tavorite NaTiOPO4 (NaTP) is here explored as a possible solid electrolyte interphase (SEI) free anode material for Na-ion batteries (NIBs). The operation voltage is found around 1.4 V vs Na+/Na with a very low polarization (around 0.02 V) and an efficiency of ∼95% after 100 cycles in half-cells. Operando X-ray diffraction measurements have unveiled that insertion and deinsertion of Na ions occurs via a symmetric mechanism involving biphasic and solid solution reactions. The evolution of the SEI formation at different voltage values upon electrochemical cycling has been analyzed by means of X-ray photoelectron spectroscopy (XPS), and the results show that although not inexistent, a very thin and stable SEI layer is formed that positively contributes to the excellent cycling stability of the material.
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Galcerán M. et al. Investigation of NaTiOPO4 as Anode for Sodium-Ion Batteries: A Solid Electrolyte Interphase Free Material? // ACS Applied Energy Materials. 2019. Vol. 2. No. 3. pp. 1923-1931.
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Galcerán M., Rikarte J., Zarrabeitia M., Pujol M. C., Aguiló M., Casas-Cabanas M. Investigation of NaTiOPO4 as Anode for Sodium-Ion Batteries: A Solid Electrolyte Interphase Free Material? // ACS Applied Energy Materials. 2019. Vol. 2. No. 3. pp. 1923-1931.
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TY - JOUR
DO - 10.1021/acsaem.8b02040
UR - https://doi.org/10.1021/acsaem.8b02040
TI - Investigation of NaTiOPO4 as Anode for Sodium-Ion Batteries: A Solid Electrolyte Interphase Free Material?
T2 - ACS Applied Energy Materials
AU - Galcerán, Montserrat
AU - Rikarte, Jokin
AU - Zarrabeitia, Maider
AU - Pujol, M C.
AU - Aguiló, M
AU - Casas-Cabanas, Montse
PY - 2019
DA - 2019/02/05
PB - American Chemical Society (ACS)
SP - 1923-1931
IS - 3
VL - 2
SN - 2574-0962
ER -
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@article{2019_Galcerán,
author = {Montserrat Galcerán and Jokin Rikarte and Maider Zarrabeitia and M C. Pujol and M Aguiló and Montse Casas-Cabanas},
title = {Investigation of NaTiOPO4 as Anode for Sodium-Ion Batteries: A Solid Electrolyte Interphase Free Material?},
journal = {ACS Applied Energy Materials},
year = {2019},
volume = {2},
publisher = {American Chemical Society (ACS)},
month = {feb},
url = {https://doi.org/10.1021/acsaem.8b02040},
number = {3},
pages = {1923--1931},
doi = {10.1021/acsaem.8b02040}
}
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MLA
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Galcerán, Montserrat, et al. “Investigation of NaTiOPO4 as Anode for Sodium-Ion Batteries: A Solid Electrolyte Interphase Free Material?.” ACS Applied Energy Materials, vol. 2, no. 3, Feb. 2019, pp. 1923-1931. https://doi.org/10.1021/acsaem.8b02040.