ACS Applied Energy Materials

, том 2 , издание 3 , страницы 1923-1931

Investigation of NaTiOPO4 as Anode for Sodium-Ion Batteries: A Solid Electrolyte Interphase Free Material?

Тип публикации: Journal Article

Дата публикации: 2019-02-05

American Chemical Society (ACS)

ACS Applied Energy Materials

SCImago Q1

WOS Q2

БС1

SJR: 1.122

CiteScore: 9.2

Impact factor: 5.5

ISSN: 25740962

DOI: 10.1021/acsaem.8b02040

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Materials Chemistry

Electrochemistry

Electrical and Electronic Engineering

Energy Engineering and Power Technology

Chemical Engineering (miscellaneous)

Краткое описание

Tavorite NaTiOPO4 (NaTP) is here explored as a possible solid electrolyte interphase (SEI) free anode material for Na-ion batteries (NIBs). The operation voltage is found around 1.4 V vs Na+/Na with a very low polarization (around 0.02 V) and an efficiency of ∼95% after 100 cycles in half-cells. Operando X-ray diffraction measurements have unveiled that insertion and deinsertion of Na ions occurs via a symmetric mechanism involving biphasic and solid solution reactions. The evolution of the SEI formation at different voltage values upon electrochemical cycling has been analyzed by means of X-ray photoelectron spectroscopy (XPS), and the results show that although not inexistent, a very thin and stable SEI layer is formed that positively contributes to the excellent cycling stability of the material.

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Journal of Power Sources	Journal of Power Sources, 3, 15% Journal of Power Sources 3 публикации, 15%
Journal of Physical Chemistry C	Journal of Physical Chemistry C, 1, 5% Journal of Physical Chemistry C 1 публикация, 5%
Energies	Energies, 1, 5% Energies 1 публикация, 5%
Electrochimica Acta	Electrochimica Acta, 1, 5% Electrochimica Acta 1 публикация, 5%
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ACS applied materials & interfaces	ACS applied materials & interfaces, 1, 5% ACS applied materials & interfaces 1 публикация, 5%
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Journal of Electrochemical Energy Conversion and Storage	Journal of Electrochemical Energy Conversion and Storage, 1, 5% Journal of Electrochemical Energy Conversion and Storage 1 публикация, 5%
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Advanced Energy Materials	Advanced Energy Materials, 1, 5% Advanced Energy Materials 1 публикация, 5%
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Galcerán M. et al. Investigation of NaTiOPO4 as Anode for Sodium-Ion Batteries: A Solid Electrolyte Interphase Free Material? // ACS Applied Energy Materials. 2019. Vol. 2. No. 3. pp. 1923-1931.

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Galcerán M., Rikarte J., Zarrabeitia M., Pujol M. C., Aguiló M., Casas-Cabanas M. Investigation of NaTiOPO4 as Anode for Sodium-Ion Batteries: A Solid Electrolyte Interphase Free Material? // ACS Applied Energy Materials. 2019. Vol. 2. No. 3. pp. 1923-1931.

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