volume 2 issue 3 pages 2072-2079

Inductive Effect in Mn-Doped NiO Nanosheet Arrays for Enhanced Capacitive and Highly Stable Hybrid Supercapacitor

Han Xu 1
Bingqing Wang 1
Can Yang 1
Meng Ge 1
Ruifeng Zhao 1
Qiannan Hu 1
Okky Triana 1
Yaping Li 1
Aijuan Han 1
Publication typeJournal Article
Publication date2019-02-22
scimago Q1
wos Q2
SJR1.378
CiteScore10.2
Impact factor5.5
ISSN25740962
Materials Chemistry
Electrochemistry
Electrical and Electronic Engineering
Energy Engineering and Power Technology
Chemical Engineering (miscellaneous)
Abstract
The inductive effect related to foreign metal substitution has great effect on the redox behavior of transition metal oxides, which plays an important role in their electrochemical activities. In this work, we demonstrate the inductive effect in nickel oxide nanosheet arrays (NSAs) via doping with the lower electronegative element Mn, which has greatly improved their electrochemical capacitance and stability. Density functional theory (DFT) calculations show that the inductive effect in Mn–NiO increases the electron transport efficiency, enhances the adsorption energy of OH–, and also makes the compound more covalent. Therefore, Mn–NiO NSAs demonstrated a dramatically improved specific capacitance twofold better than that of pure NiO NSAs at a current density of 5 mA cm–2 and higher stability without any decay of capacitance after 10 000 cycles at 30 mA cm–2. Moreover, the hybrid supercapacitor device of Mn–NiO NSAs//graphene–CNT exhibited an excellent recycling stability after 50 000 cycles of charging/d...
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Xu H. et al. Inductive Effect in Mn-Doped NiO Nanosheet Arrays for Enhanced Capacitive and Highly Stable Hybrid Supercapacitor // ACS Applied Energy Materials. 2019. Vol. 2. No. 3. pp. 2072-2079.
GOST all authors (up to 50) Copy
Xu H., Wang B., Yang C., Ge M., Zhao R., Hu Q., Triana O., Iqbal M., Li Y., Han A., Liu J. Inductive Effect in Mn-Doped NiO Nanosheet Arrays for Enhanced Capacitive and Highly Stable Hybrid Supercapacitor // ACS Applied Energy Materials. 2019. Vol. 2. No. 3. pp. 2072-2079.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1021/acsaem.8b02129
UR - https://doi.org/10.1021/acsaem.8b02129
TI - Inductive Effect in Mn-Doped NiO Nanosheet Arrays for Enhanced Capacitive and Highly Stable Hybrid Supercapacitor
T2 - ACS Applied Energy Materials
AU - Xu, Han
AU - Wang, Bingqing
AU - Yang, Can
AU - Ge, Meng
AU - Zhao, Ruifeng
AU - Hu, Qiannan
AU - Triana, Okky
AU - Iqbal, Muzaffar
AU - Li, Yaping
AU - Han, Aijuan
AU - Liu, Junfeng
PY - 2019
DA - 2019/02/22
PB - American Chemical Society (ACS)
SP - 2072-2079
IS - 3
VL - 2
SN - 2574-0962
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2019_Xu,
author = {Han Xu and Bingqing Wang and Can Yang and Meng Ge and Ruifeng Zhao and Qiannan Hu and Okky Triana and Muzaffar Iqbal and Yaping Li and Aijuan Han and Junfeng Liu},
title = {Inductive Effect in Mn-Doped NiO Nanosheet Arrays for Enhanced Capacitive and Highly Stable Hybrid Supercapacitor},
journal = {ACS Applied Energy Materials},
year = {2019},
volume = {2},
publisher = {American Chemical Society (ACS)},
month = {feb},
url = {https://doi.org/10.1021/acsaem.8b02129},
number = {3},
pages = {2072--2079},
doi = {10.1021/acsaem.8b02129}
}
MLA
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MLA Copy
Xu, Han, et al. “Inductive Effect in Mn-Doped NiO Nanosheet Arrays for Enhanced Capacitive and Highly Stable Hybrid Supercapacitor.” ACS Applied Energy Materials, vol. 2, no. 3, Feb. 2019, pp. 2072-2079. https://doi.org/10.1021/acsaem.8b02129.
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