ACS Applied Energy Materials, volume 2, issue 3, pages 1600-1607
UV-Cross-Linked Composite Polymer Electrolyte for High-Rate, Ambient Temperature Lithium Batteries
Marisa Falco
1
,
Laurent Castro
2
,
Jijeesh Ravi Nair
1
,
Federico Bella
1
,
Fanny Bardé
2
,
Giuseppina Meligrana
1
,
Claudio Gerbaldi
1
2
Research & Development 2, Advanced Material Research, Battery & Fuel Cell, Toyota Motor Europe, Hoge Wei 33 B, B-1930 Zaventem, Belgium
|
Publication type: Journal Article
Publication date: 2019-02-19
Journal:
ACS Applied Energy Materials
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 6.4
ISSN: 25740962, 25740962
Materials Chemistry
Electrochemistry
Electrical and Electronic Engineering
Energy Engineering and Power Technology
Chemical Engineering (miscellaneous)
Abstract
We report an innovative cross-linked composite polymer electrolyte (CPE) based on the garnet-type ceramic super Li+ ion conductor, Li7La3Zr2O12 (LLZO), that is encompassed in a supersoft poly(ethylene oxide)/tetraglyme matrix. UV-induced, facile and solvent-free cross-linking process ensures flexible and self-standing CPEs, which are nonflammable and perfectly shape-retaining under thermal/mechanical stress. The CPEs exhibit high ionic conductivity, exceeding 0.1 mS cm–1 at 20 °C, suitable for ambient and subambient temperature operation. Lab-scale lithium metal polymer cells assembled with LiFePO4-based composite cathode and the optimized CPE deliver full capacity at low current rates and outstanding specific discharge capacity of 115 mAh g–1 at 1C rate and ambient temperature. Remarkably, the lithium metal cell can run for hundreds of galvanostatic cycles (>400) with low overpotential, limited fading, and excellent Coulombic efficiency (>99%), which postulates the practical application of the newly deve...
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Citations by publishers
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35
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Elsevier
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The Electrochemical Society
3 publications, 3.09%
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1 publication, 1.03%
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IEEE
1 publication, 1.03%
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American Institute of Physics (AIP)
1 publication, 1.03%
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Taylor & Francis
1 publication, 1.03%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 1.03%
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Falco M. et al. UV-Cross-Linked Composite Polymer Electrolyte for High-Rate, Ambient Temperature Lithium Batteries // ACS Applied Energy Materials. 2019. Vol. 2. No. 3. pp. 1600-1607.
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Falco M., Castro L., Nair J. R., Bella F., Bardé F., Meligrana G., Gerbaldi C. UV-Cross-Linked Composite Polymer Electrolyte for High-Rate, Ambient Temperature Lithium Batteries // ACS Applied Energy Materials. 2019. Vol. 2. No. 3. pp. 1600-1607.
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TY - JOUR
DO - 10.1021/acsaem.8b02185
UR - https://doi.org/10.1021/acsaem.8b02185
TI - UV-Cross-Linked Composite Polymer Electrolyte for High-Rate, Ambient Temperature Lithium Batteries
T2 - ACS Applied Energy Materials
AU - Falco, Marisa
AU - Castro, Laurent
AU - Nair, Jijeesh Ravi
AU - Bardé, Fanny
AU - Meligrana, Giuseppina
AU - Bella, Federico
AU - Gerbaldi, Claudio
PY - 2019
DA - 2019/02/19 00:00:00
PB - American Chemical Society (ACS)
SP - 1600-1607
IS - 3
VL - 2
SN - 2574-0962
SN - 2574-0962
ER -
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@article{2019_Falco,
author = {Marisa Falco and Laurent Castro and Jijeesh Ravi Nair and Fanny Bardé and Giuseppina Meligrana and Federico Bella and Claudio Gerbaldi},
title = {UV-Cross-Linked Composite Polymer Electrolyte for High-Rate, Ambient Temperature Lithium Batteries},
journal = {ACS Applied Energy Materials},
year = {2019},
volume = {2},
publisher = {American Chemical Society (ACS)},
month = {feb},
url = {https://doi.org/10.1021/acsaem.8b02185},
number = {3},
pages = {1600--1607},
doi = {10.1021/acsaem.8b02185}
}
Cite this
MLA
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Falco, Marisa, et al. “UV-Cross-Linked Composite Polymer Electrolyte for High-Rate, Ambient Temperature Lithium Batteries.” ACS Applied Energy Materials, vol. 2, no. 3, Feb. 2019, pp. 1600-1607. https://doi.org/10.1021/acsaem.8b02185.