ACS applied materials & interfaces, publication number acsami.0c03363
Molecular Design of a Highly Stable Single-Ion Conducting Polymer Gel Electrolyte
Kewei Liu
1
,
Sisi Jiang
1
,
Trevor L Dzwiniel
2
,
Hong-Keun Kim
1
,
Zhou Yu
3
,
Nancy L Dietz Rago
1
,
Jae Jin Kim
1
,
Timothy Fister
1
,
Jianzhong Yang
1
,
Qian Liu
1
,
James Gilbert
1
,
Lei Cheng
3
,
Venkat Srinivasan
4, 5
,
Zhengcheng Zhang
1
,
Chen Liao
1, 4
4
Joint Center for Energy Storage Research, Lemont, Illinois 60439, United States
|
5
Argonne Collaborative Center for Energy Storage Science, Lemont, Illinois 60439, United States
|
Publication type: Journal Article
Publication date: 2020-05-29
Journal:
ACS applied materials & interfaces
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 9.5
ISSN: 19448244, 19448252
General Materials Science
Abstract
Single-ion conducting polymer electrolyte with its high Li transference number (tLi+) has showed the capability in enabling high battery performance and safety by avoiding liquid electrolyte leakeage and suppressing the Li dendrite formation. However, the insufficient ionic conductivity, low electrochemical stability, and poor polymer/electrode interfacial issues greatly hindered its commecial use. Here, a Li-containing boron centered fluorinated single ion conducting (SIC) polymer gel electrolyte (LiBFSIE) was rationally designed in targeting a high tLi+ and high electrochemical stability. Owing to the low dissociation energy of the boron-center anion and Li+, the as-prepared LiBFSIE exhibited an ionic conductivity of 2 × 10-4 S/cm at 35 ºC, which is exclusively contributed by Li ions due to the high tLi+of 0.93. Both simulation and experimental approaches were applied to investigate the ion diffusion and concentration gradient in the LiBFSIE and non-cross-linked dual ion systems. Typical rectangular Li stripping/plating voltage profiles demonstrated the uniform Li deposition assisted by LiBFSIE. The interfacial contact and electrolyte infiltration were further optimized with an in-situ UV-Vis initiated polymerization method together with the electrode materials. Benefited from the high electrochemical stability of LiBFSIE, a promising average coulombic efficiency of 99.95% over 200 cycles was achieved, which is higher than that of the liquid electrolyte based cells. No obvious capacity fading was observed, indicating the long term-stability of LiBFSIE for lithium metal batteries.
Top-30
Citations by journals
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ACS applied materials & interfaces
4 publications, 25%
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ACS Energy Letters
2 publications, 12.5%
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Nano Energy
2 publications, 12.5%
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Journal of the Electrochemical Society
1 publication, 6.25%
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ACS Applied Polymer Materials
1 publication, 6.25%
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ACS Applied Energy Materials
1 publication, 6.25%
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Journal of Physical Chemistry C
1 publication, 6.25%
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ECS Advances
1 publication, 6.25%
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Journal of Colloid and Interface Science
1 publication, 6.25%
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Russian Chemical Reviews
1 publication, 6.25%
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Electrochemical Energy Reviews
1 publication, 6.25%
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Citations by publishers
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American Chemical Society (ACS)
9 publications, 56.25%
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Elsevier
3 publications, 18.75%
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The Electrochemical Society
2 publications, 12.5%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 6.25%
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Springer Nature
1 publication, 6.25%
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Liu K. et al. Molecular Design of a Highly Stable Single-Ion Conducting Polymer Gel Electrolyte // ACS applied materials & interfaces. 2020. acsami.0c03363
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Liu K., Jiang S., Dzwiniel T. L., Kim H., Yu Z., Dietz Rago N. L., Kim J. J., Fister T., Yang J., Liu Q., Gilbert J., Cheng L., Srinivasan V., Zhang Z., Liao C. Molecular Design of a Highly Stable Single-Ion Conducting Polymer Gel Electrolyte // ACS applied materials & interfaces. 2020. acsami.0c03363
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TY - JOUR
DO - 10.1021/acsami.0c03363
UR - https://doi.org/10.1021/acsami.0c03363
TI - Molecular Design of a Highly Stable Single-Ion Conducting Polymer Gel Electrolyte
T2 - ACS applied materials & interfaces
AU - Dzwiniel, Trevor L
AU - Dietz Rago, Nancy L
AU - Gilbert, James
AU - Yu, Zhou
AU - Kim, Jae Jin
AU - Fister, Timothy
AU - Cheng, Lei
AU - Zhang, Zhengcheng
AU - Liao, Chen
AU - Liu, Kewei
AU - Jiang, Sisi
AU - Kim, Hong-Keun
AU - Yang, Jianzhong
AU - Liu, Qian
AU - Srinivasan, Venkat
PY - 2020
DA - 2020/05/29 00:00:00
PB - American Chemical Society (ACS)
SN - 1944-8244
SN - 1944-8252
ER -
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@article{2020_Liu,
author = {Trevor L Dzwiniel and Nancy L Dietz Rago and James Gilbert and Zhou Yu and Jae Jin Kim and Timothy Fister and Lei Cheng and Zhengcheng Zhang and Chen Liao and Kewei Liu and Sisi Jiang and Hong-Keun Kim and Jianzhong Yang and Qian Liu and Venkat Srinivasan},
title = {Molecular Design of a Highly Stable Single-Ion Conducting Polymer Gel Electrolyte},
journal = {ACS applied materials & interfaces},
year = {2020},
publisher = {American Chemical Society (ACS)},
month = {may},
url = {https://doi.org/10.1021/acsami.0c03363},
doi = {10.1021/acsami.0c03363}
}