volume 12 issue 18 pages 20563-20569

Material and Interfacial Modification toward a Stable Room-Temperature Solid-State Na–S Battery

Publication typeJournal Article
Publication date2020-04-14
scimago Q1
wos Q1
SJR1.921
CiteScore14.5
Impact factor8.2
ISSN19448244, 19448252
General Materials Science
Abstract
Room-temperature solid-state sodium batteries have the remarkable potential to simultaneously achieve high safety, high energy density and low cost. Yet their current performance is far below expectations. Through material and interfacial modification based on Na3PS4 solid electrolytes, progress is made toward stable room-temperature solid-state sodium-sulfur (Na-S) batteries. First, ionic liquid N-butyl-N-methylpyrrolidinium bis(fluorosulfonyl)imide (Pyr14FSI) is employed to modify anode/electrolyte interface. An overpotential of 0.55 V after 900 h of a symmetrical battery indicates enhanced interfacial stability. A stable in-situ solid electrolyte interphase layer is formed between the interface of NaSn and Na3PS4, proved by X-ray photoelectron spectroscopy measurements. Furthermore, selenium-doped sulfurized polyacrylonitrile (Se0.05S0.95@pPAN) is used to boost the ionic and electronic conductivity of the sulfur cathode. As a result, the Na-S battery using a Se0.05S0.95@pPAN cathode and the interfacial modification delivers stable cycle performance and enhanced rate capability.
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GOST |
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GOST Copy
An T. et al. Material and Interfacial Modification toward a Stable Room-Temperature Solid-State Na–S Battery // ACS applied materials & interfaces. 2020. Vol. 12. No. 18. pp. 20563-20569.
GOST all authors (up to 50) Copy
An T., Jia H., Peng L., Xie J. Material and Interfacial Modification toward a Stable Room-Temperature Solid-State Na–S Battery // ACS applied materials & interfaces. 2020. Vol. 12. No. 18. pp. 20563-20569.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1021/acsami.0c03899
UR - https://doi.org/10.1021/acsami.0c03899
TI - Material and Interfacial Modification toward a Stable Room-Temperature Solid-State Na–S Battery
T2 - ACS applied materials & interfaces
AU - An, Tao
AU - Jia, Huanhuan
AU - Peng, Linfeng
AU - Xie, Jia
PY - 2020
DA - 2020/04/14
PB - American Chemical Society (ACS)
SP - 20563-20569
IS - 18
VL - 12
PMID - 32286042
SN - 1944-8244
SN - 1944-8252
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2020_An,
author = {Tao An and Huanhuan Jia and Linfeng Peng and Jia Xie},
title = {Material and Interfacial Modification toward a Stable Room-Temperature Solid-State Na–S Battery},
journal = {ACS applied materials & interfaces},
year = {2020},
volume = {12},
publisher = {American Chemical Society (ACS)},
month = {apr},
url = {https://doi.org/10.1021/acsami.0c03899},
number = {18},
pages = {20563--20569},
doi = {10.1021/acsami.0c03899}
}
MLA
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MLA Copy
An, Tao, et al. “Material and Interfacial Modification toward a Stable Room-Temperature Solid-State Na–S Battery.” ACS applied materials & interfaces, vol. 12, no. 18, Apr. 2020, pp. 20563-20569. https://doi.org/10.1021/acsami.0c03899.
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