ACS applied materials & interfaces, volume 12, issue 38, pages 42653-42659

Stable and Flexible Sulfide Composite Electrolyte for High-Performance Solid-State Lithium Batteries

Ka Ming Ng ¹

William Arnold ²

Arjun Thapa ¹

Jacek B. Jasinski ¹

Gamini Sumanasekera ^{1, 3}

Mahendra Sunkara ^{1, 4}

Thad Druffel ¹

Hui Wang ^{1, 2}

Hide authors affiliations Show authors affiliations: 4 affiliations

Conn Center for Renewable Energy Research, University of Louisville, Louisville, Kentucky 40292, United States |

Department of Mechanical Engineering, University of Louisville, Louisville, Kentucky 40292, United States |

Department of Physics & Astronomy, University of Louisville, Louisville, Kentucky 40208, United States |

⁴

Department of Chemical Engineering, University of Louisville, Louisville, Kentucky 40292, United States |

Publication type: Journal Article

Publication date: 2020-08-26

American Chemical Society (ACS)

Journal: ACS applied materials & interfaces

Quartile SCImago

Quartile WOS

Impact factor: 9.5

ISSN: 19448244, 19448252

DOI: 10.1021/acsami.0c08261

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General Materials Science

Abstract

Sulfide-based lithium (Li)-ion conductors represent one of the most popular solid electrolytes (SEs) for solid-state Li metal batteries (SSLMBs) with high safety. However, the commercial application of sulfide SEs is significantly limited by their chemical instability in air and electrochemical instability with electrode materials (metallic Li anode and oxide cathodes). To address these difficulties, here, we design and successfully demonstrate a novel sulfide-incorporated composite electrolyte (SCE) through the combination of inorganic sulfide Li argyrodite (Li7PS6) with poly(vinylidenefluoride-co-hexafluoropropylene) (PVDF-HFP) polymer. In this composite structure, Li7PS6 is embedded in PVDF-HFP polymer matrix, making the SCE flexible and air-stable and achieve great chemical and electrochemical stability. Meanwhile, the presence of sulfide facilitates Li-ion transport in SCE, leading to a superior room-temperature ionic conductivity of 1.1 × 10-4 S cm-1. Using the SCE with enhanced stability while maintaining high conductivity, Li||Li symmetric cells achieved stable cycling up to 1000 h at 0.2 mA cm-2. In addition, LiFePO4 (LFP)||SCE||Li cells can deliver an impressive specific capacity of 160 mAh g-1 over 150 cycles. These features indicate that Li7PS6/PVDF-HFP SCE is a promising candidate to contribute to the practical development of SSLMBs.

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Citations by journals

	1 2 3 4 5 6
ACS applied materials & interfaces	ACS applied materials & interfaces, 6, 10.34% ACS applied materials & interfaces 6 publications, 10.34%
Science China Materials	Science China Materials, 2, 3.45% Science China Materials 2 publications, 3.45%
Journal of Power Sources	Journal of Power Sources, 2, 3.45% Journal of Power Sources 2 publications, 3.45%
Energy Storage Materials	Energy Storage Materials, 2, 3.45% Energy Storage Materials 2 publications, 3.45%
Chemical Engineering Journal	Chemical Engineering Journal, 2, 3.45% Chemical Engineering Journal 2 publications, 3.45%
InfoMat	InfoMat, 2, 3.45% InfoMat 2 publications, 3.45%
ACS Applied Energy Materials	ACS Applied Energy Materials, 2, 3.45% ACS Applied Energy Materials 2 publications, 3.45%
Zeitschrift fur Physikalische Chemie	Zeitschrift fur Physikalische Chemie, 2, 3.45% Zeitschrift fur Physikalische Chemie 2 publications, 3.45%
Nano-Micro Letters	Nano-Micro Letters, 1, 1.72% Nano-Micro Letters 1 publication, 1.72%
Science China Chemistry	Science China Chemistry, 1, 1.72% Science China Chemistry 1 publication, 1.72%
International Journal of Minerals, Metallurgy and Materials	International Journal of Minerals, Metallurgy and Materials, 1, 1.72% International Journal of Minerals, Metallurgy and Materials 1 publication, 1.72%
Frontiers in Energy	Frontiers in Energy, 1, 1.72% Frontiers in Energy 1 publication, 1.72%
Electrochemical Energy Reviews	Electrochemical Energy Reviews, 1, 1.72% Electrochemical Energy Reviews 1 publication, 1.72%
Journal of Energy Chemistry	Journal of Energy Chemistry, 1, 1.72% Journal of Energy Chemistry 1 publication, 1.72%
Applied Surface Science	Applied Surface Science, 1, 1.72% Applied Surface Science 1 publication, 1.72%
Journal of the Taiwan Institute of Chemical Engineers	Journal of the Taiwan Institute of Chemical Engineers, 1, 1.72% Journal of the Taiwan Institute of Chemical Engineers 1 publication, 1.72%
Advanced Functional Materials	Advanced Functional Materials, 1, 1.72% Advanced Functional Materials 1 publication, 1.72%
ChemElectroChem	ChemElectroChem, 1, 1.72% ChemElectroChem 1 publication, 1.72%
ChemistrySelect	ChemistrySelect, 1, 1.72% ChemistrySelect 1 publication, 1.72%
Advanced Materials	Advanced Materials, 1, 1.72% Advanced Materials 1 publication, 1.72%
Membranes	Membranes, 1, 1.72% Membranes 1 publication, 1.72%
Industrial & Engineering Chemistry Research	Industrial & Engineering Chemistry Research, 1, 1.72% Industrial & Engineering Chemistry Research 1 publication, 1.72%
ACS Omega	ACS Omega, 1, 1.72% ACS Omega 1 publication, 1.72%
Journal of Materials Chemistry A	Journal of Materials Chemistry A, 1, 1.72% Journal of Materials Chemistry A 1 publication, 1.72%
Materials Chemistry Frontiers	Materials Chemistry Frontiers, 1, 1.72% Materials Chemistry Frontiers 1 publication, 1.72%
Energy and Environmental Science	Energy and Environmental Science, 1, 1.72% Energy and Environmental Science 1 publication, 1.72%
Chemical Communications	Chemical Communications, 1, 1.72% Chemical Communications 1 publication, 1.72%
Sustainable Energy and Fuels	Sustainable Energy and Fuels, 1, 1.72% Sustainable Energy and Fuels 1 publication, 1.72%
eTransportation	eTransportation, 1, 1.72% eTransportation 1 publication, 1.72%
	1 2 3 4 5 6

Citations by publishers

	2 4 6 8 10 12 14
Elsevier	Elsevier, 14, 24.14% Elsevier 14 publications, 24.14%
Wiley	Wiley, 11, 18.97% Wiley 11 publications, 18.97%
American Chemical Society (ACS)	American Chemical Society (ACS), 11, 18.97% American Chemical Society (ACS) 11 publications, 18.97%
Springer Nature	Springer Nature, 8, 13.79% Springer Nature 8 publications, 13.79%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 5, 8.62% Royal Society of Chemistry (RSC) 5 publications, 8.62%
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 2, 3.45% Multidisciplinary Digital Publishing Institute (MDPI) 2 publications, 3.45%
Walter de Gruyter	Walter de Gruyter, 2, 3.45% Walter de Gruyter 2 publications, 3.45%
University of Science and Technology Beijing	University of Science and Technology Beijing, 1, 1.72% University of Science and Technology Beijing 1 publication, 1.72%
Taiwan Institute of Chemical Engineers	Taiwan Institute of Chemical Engineers, 1, 1.72% Taiwan Institute of Chemical Engineers 1 publication, 1.72%
Ceramic Society of Japan	Ceramic Society of Japan, 1, 1.72% Ceramic Society of Japan 1 publication, 1.72%
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii	Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii, 1, 1.72% Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii 1 publication, 1.72%
	2 4 6 8 10 12 14

We do not take into account publications without a DOI.
Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
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Ming Ng K. et al. Stable and Flexible Sulfide Composite Electrolyte for High-Performance Solid-State Lithium Batteries // ACS applied materials & interfaces. 2020. Vol. 12. No. 38. pp. 42653-42659.

GOST all authors (up to 50) Copy

Ming Ng K., Arnold W., Thapa A., Jasinski J. B., Sumanasekera G., Sunkara M., Druffel T., Wang H. Stable and Flexible Sulfide Composite Electrolyte for High-Performance Solid-State Lithium Batteries // ACS applied materials & interfaces. 2020. Vol. 12. No. 38. pp. 42653-42659.

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.1021/acsami.0c08261

UR - https://doi.org/10.1021/acsami.0c08261

TI - Stable and Flexible Sulfide Composite Electrolyte for High-Performance Solid-State Lithium Batteries

T2 - ACS applied materials & interfaces

AU - Thapa, Arjun

AU - Ming Ng, Ka

AU - Jasinski, Jacek B.

AU - Sunkara, Mahendra

AU - Druffel, Thad

AU - Wang, Hui

AU - Arnold, William

AU - Sumanasekera, Gamini

PY - 2020

DA - 2020/08/26 00:00:00

PB - American Chemical Society (ACS)

SP - 42653-42659

IS - 38

VL - 12

SN - 1944-8244

SN - 1944-8252

ER -

BibTex |

Cite this

BibTex Copy

@article{2020_Ming Ng,

author = {Arjun Thapa and Ka Ming Ng and Jacek B. Jasinski and Mahendra Sunkara and Thad Druffel and Hui Wang and William Arnold and Gamini Sumanasekera},

title = {Stable and Flexible Sulfide Composite Electrolyte for High-Performance Solid-State Lithium Batteries},

journal = {ACS applied materials & interfaces},

year = {2020},

volume = {12},

publisher = {American Chemical Society (ACS)},

month = {aug},

url = {https://doi.org/10.1021/acsami.0c08261},

number = {38},

pages = {42653--42659},

doi = {10.1021/acsami.0c08261}

}

MLA

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MLA Copy

Ming Ng, Ka, et al. “Stable and Flexible Sulfide Composite Electrolyte for High-Performance Solid-State Lithium Batteries.” ACS applied materials & interfaces, vol. 12, no. 38, Aug. 2020, pp. 42653-42659. https://doi.org/10.1021/acsami.0c08261.

Found error?

Publisher

American Chemical Society (ACS)

Journal

ACS applied materials & interfaces

Quartile SCImago

Quartile WOS

Impact factor

9.5

ISSN

19448244 (Print)
19448252 (Electronic)