ACS applied materials & interfaces, volume 13, issue 41, pages 48525-48535

Improving Fast and Safe Transfer of Lithium Ions in Solid-State Lithium Batteries by Porosity and Channel Structure of Polymer Electrolyte

Libo Li ¹

YuHang SHAN ¹

Furi Wang ¹

Xiaochuan Chen ¹

Yangmingyue Zhao ¹

Da Zhou ¹

Heng Wang ¹

Wenjun Cui ¹

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School of Materials Science and Chemical Engineering, Harbin University of Science and Technology, Harbin 150040, China |

Publication type: Journal Article

Publication date: 2021-10-08

American Chemical Society (ACS)

Journal: ACS applied materials & interfaces

Quartile SCImago

Quartile WOS

Impact factor: 9.5

ISSN: 19448244, 19448252

DOI: 10.1021/acsami.1c11489

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General Materials Science

Abstract

Solid-state lithium batteries using solid polymer electrolytes can improve the safety and energy density of batteries. Smoother lithium-ion channels are necessary for solid polymer electrolytes with high ionic conductivity. The porosity and channel structure of the polymer film affect the transfer of lithium ions. However, their controllable synthesis remains a big challenge. Here, we developed a simple synthesis approach toward wrinkled microporous polymer electrolytes by combining the amphoteric (water solubility and organic solubility) polymer in three polymer blends. The homogeneous blend solution spontaneously wrinkled to vertical fold channels as the solvent evaporated. Two minor polymers, poly(vinyl pyrrolidone) (PVP) and polyetherimide (PEI), formed close stacks, and Janus PVP was dispersed in the poly(vinylidene fluoride) (PVDF) matrix. The interfacial tensions between the three polymers were different, so stress was produced when they solidified. The solvent was evaporated to the top layer of the polymers when the temperature increased. The bottom layer wrinkled owing to the stress during solidification. The evaporation of the solvent generated micropores to form the lithium-ion channel. They helped Li+ transference and created a wrinkled microporous PVDF-based polymer electrolyte, which achieved an ionic conductivity of 5.1 × 10-4 S cm-1 and a lithium-ion transference number of 0.51 at room temperature. Meanwhile, the good flame retardancy and tensile strength of the polymer electrolyte film can improve the safety of the battery. At 0.5C and room temperature, the batteries with a LiFePO4 cathode and the wrinkled microporous LiTFSI/PEI/PVP/PVDF electrolyte reached a high discharge specific capacity of 122.1 mAh g-1 at the 100th cycle with a Coulombic efficiency of above 99%. The results of tensile and self-extinguishing tests show that the polymer electrolyte film has good safety application prospects.

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Citations by journals

	1 2 3
Journal of Nanostructure in Chemistry	Journal of Nanostructure in Chemistry, 3, 4.76% Journal of Nanostructure in Chemistry 3 publications, 4.76%
International Journal of Hydrogen Energy	International Journal of Hydrogen Energy, 3, 4.76% International Journal of Hydrogen Energy 3 publications, 4.76%
Main Group Chemistry	Main Group Chemistry, 2, 3.17% Main Group Chemistry 2 publications, 3.17%
Surfaces and Interfaces	Surfaces and Interfaces, 2, 3.17% Surfaces and Interfaces 2 publications, 3.17%
Advanced Functional Materials	Advanced Functional Materials, 2, 3.17% Advanced Functional Materials 2 publications, 3.17%
Small Structures	Small Structures, 2, 3.17% Small Structures 2 publications, 3.17%
Applied Surface Science	Applied Surface Science, 2, 3.17% Applied Surface Science 2 publications, 3.17%
Small	Small, 2, 3.17% Small 2 publications, 3.17%
InfoMat	InfoMat, 1, 1.59% InfoMat 1 publication, 1.59%
Journal of Molecular Modeling	Journal of Molecular Modeling, 1, 1.59% Journal of Molecular Modeling 1 publication, 1.59%
Brazilian Journal of Physics	Brazilian Journal of Physics, 1, 1.59% Brazilian Journal of Physics 1 publication, 1.59%
Silicon	Silicon, 1, 1.59% Silicon 1 publication, 1.59%
Optical and Quantum Electronics	Optical and Quantum Electronics, 1, 1.59% Optical and Quantum Electronics 1 publication, 1.59%
Journal of Thermal Analysis and Calorimetry	Journal of Thermal Analysis and Calorimetry, 1, 1.59% Journal of Thermal Analysis and Calorimetry 1 publication, 1.59%
Journal of Environmental Chemical Engineering	Journal of Environmental Chemical Engineering, 1, 1.59% Journal of Environmental Chemical Engineering 1 publication, 1.59%
Inorganic Chemistry Communication	Inorganic Chemistry Communication, 1, 1.59% Inorganic Chemistry Communication 1 publication, 1.59%
Ceramics International	Ceramics International, 1, 1.59% Ceramics International 1 publication, 1.59%
Sustainable Energy Technologies and Assessments	Sustainable Energy Technologies and Assessments, 1, 1.59% Sustainable Energy Technologies and Assessments 1 publication, 1.59%
Journal of Electroanalytical Chemistry	Journal of Electroanalytical Chemistry, 1, 1.59% Journal of Electroanalytical Chemistry 1 publication, 1.59%
Vacuum	Vacuum, 1, 1.59% Vacuum 1 publication, 1.59%
Desalination	Desalination, 1, 1.59% Desalination 1 publication, 1.59%
Journal of Energy Chemistry	Journal of Energy Chemistry, 1, 1.59% Journal of Energy Chemistry 1 publication, 1.59%
Journal of Materials Research and Technology	Journal of Materials Research and Technology, 1, 1.59% Journal of Materials Research and Technology 1 publication, 1.59%
Materials Today	Materials Today, 1, 1.59% Materials Today 1 publication, 1.59%
New Carbon Materials	New Carbon Materials, 1, 1.59% New Carbon Materials 1 publication, 1.59%
Energy & Fuels	Energy & Fuels, 1, 1.59% Energy & Fuels 1 publication, 1.59%
Batteries & Supercaps	Batteries & Supercaps, 1, 1.59% Batteries & Supercaps 1 publication, 1.59%
Electrochemical Energy Reviews	Electrochemical Energy Reviews, 1, 1.59% Electrochemical Energy Reviews 1 publication, 1.59%
ACS Energy Letters	ACS Energy Letters, 1, 1.59% ACS Energy Letters 1 publication, 1.59%
	1 2 3

Citations by publishers

	5 10 15 20 25
Elsevier	Elsevier, 23, 36.51% Elsevier 23 publications, 36.51%
Wiley	Wiley, 12, 19.05% Wiley 12 publications, 19.05%
Springer Nature	Springer Nature, 9, 14.29% Springer Nature 9 publications, 14.29%
American Chemical Society (ACS)	American Chemical Society (ACS), 7, 11.11% American Chemical Society (ACS) 7 publications, 11.11%
IOS Press	IOS Press, 2, 3.17% IOS Press 2 publications, 3.17%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 2, 3.17% Royal Society of Chemistry (RSC) 2 publications, 3.17%
Taylor & Francis	Taylor & Francis, 2, 3.17% Taylor & Francis 2 publications, 3.17%
Hindawi Limited	Hindawi Limited, 2, 3.17% Hindawi Limited 2 publications, 3.17%
Electrochemical Science Group, University of Belgrade	Electrochemical Science Group, University of Belgrade, 1, 1.59% Electrochemical Science Group, University of Belgrade 1 publication, 1.59%
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii	Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii, 1, 1.59% Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii 1 publication, 1.59%
	5 10 15 20 25

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Li L. et al. Improving Fast and Safe Transfer of Lithium Ions in Solid-State Lithium Batteries by Porosity and Channel Structure of Polymer Electrolyte // ACS applied materials & interfaces. 2021. Vol. 13. No. 41. pp. 48525-48535.

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Li L., SHAN Y., Wang F., Chen X., Zhao Y., Zhou D., Wang H., Cui W. Improving Fast and Safe Transfer of Lithium Ions in Solid-State Lithium Batteries by Porosity and Channel Structure of Polymer Electrolyte // ACS applied materials & interfaces. 2021. Vol. 13. No. 41. pp. 48525-48535.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1021/acsami.1c11489

UR - https://doi.org/10.1021/acsami.1c11489

TI - Improving Fast and Safe Transfer of Lithium Ions in Solid-State Lithium Batteries by Porosity and Channel Structure of Polymer Electrolyte

T2 - ACS applied materials & interfaces

AU - SHAN, YuHang

AU - Wang, Furi

AU - Chen, Xiaochuan

AU - Zhao, Yangmingyue

AU - Zhou, Da

AU - Cui, Wenjun

AU - Li, Libo

AU - Wang, Heng

PY - 2021

DA - 2021/10/08 00:00:00

PB - American Chemical Society (ACS)

SP - 48525-48535

IS - 41

VL - 13

SN - 1944-8244

SN - 1944-8252

ER -

BibTex |

Cite this

BibTex Copy

@article{2021_Li,

author = {YuHang SHAN and Furi Wang and Xiaochuan Chen and Yangmingyue Zhao and Da Zhou and Wenjun Cui and Libo Li and Heng Wang},

title = {Improving Fast and Safe Transfer of Lithium Ions in Solid-State Lithium Batteries by Porosity and Channel Structure of Polymer Electrolyte},

journal = {ACS applied materials & interfaces},

year = {2021},

volume = {13},

publisher = {American Chemical Society (ACS)},

month = {oct},

url = {https://doi.org/10.1021/acsami.1c11489},

number = {41},

pages = {48525--48535},

doi = {10.1021/acsami.1c11489}

}

MLA

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Li, Libo, et al. “Improving Fast and Safe Transfer of Lithium Ions in Solid-State Lithium Batteries by Porosity and Channel Structure of Polymer Electrolyte.” ACS applied materials & interfaces, vol. 13, no. 41, Oct. 2021, pp. 48525-48535. https://doi.org/10.1021/acsami.1c11489.

Found error?

Publisher

American Chemical Society (ACS)

Journal

ACS applied materials & interfaces

Quartile SCImago

Quartile WOS

Impact factor

9.5

ISSN

19448244 (Print)
19448252 (Electronic)