ACS applied materials & interfaces, volume 13, issue 41, pages 48569-48581
Application of a Modified Porphyrin in a Polymer Electrolyte with Superior Properties for All-Solid-State Lithium Batteries
Qinghui Zeng
1
,
Pingping Chen
1
,
Zhenfeng Li
1
,
Xin Wen
1
,
Wen Wen
1
,
Yu Liu
1
,
Hai-Lei Zhao
2
,
Shuping Zhang
2
,
Henghui Zhou
3, 4
,
Liaoyun Zhang
1
4
Pulead Technology Industry Company Limited, Beijing 102200, China
|
Publication type: Journal Article
Publication date: 2021-10-12
Journal:
ACS applied materials & interfaces
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 9.5
ISSN: 19448244, 19448252
General Materials Science
Abstract
Porphyrins and their derivatives are a unique class of multifunctional and modifiable π-conjugated heterocyclic organic molecules, which have been widely applied in the fields of optoelectronic devices and catalysis. However, the application of porphyrins in polymer electrolytes for all-solid-state lithium-ion batteries (ASSLIBs) has rarely been reported. Herein, porphyrin molecules modified by polyether chains are used for composite solid-state polymer electrolytes (CSPEs) for the first time. The introduction of a modified porphyrin in an electrolyte can not only promote the electrochemical properties by constructing ordered ion channels via the intermolecular interaction between π-conjugated heterocyclic porphyrins, but also significantly improve the mechanical strength and interface contact between the electrolyte membrane and the lithium metal anode. Consequently, the all-solid-state batteries assembled by the modified porphyrin composite polymer electrolyte, LiFePO4 cathodes, and Li anodes deliver a higher discharge capacity of 158.2 mA h g-1 at 60 °C, 0.2 C, which remains at 153.6 mA h g-1 after 120 cycles with an average coulombic efficiency of ∼99.60%. Furthermore, the flexible porphyrin-based composite polymer electrolyte can also enable a Li || LiCoO2 battery to exhibit a maximum discharge capacity of 108.6 mA h g-1 at 60 °C, 0.1 C with an active material loading of 2-3 mg cm-2, which is unable to realize for the corresponding batteries with a pure PEO-based polymer electrolyte. This work not only broadens the application scope of porphyrins, but also proposes a novel method to fabricate CSPEs with improved electrochemical and mechanical properties, which may shed new light on the development of CSPEs for next-generation high-energy-density lithium-ion batteries.
Top-30
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2 publications, 20%
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1 publication, 10%
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1 publication, 10%
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1 publication, 10%
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1 publication, 10%
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1 publication, 10%
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RSC Advances
1 publication, 10%
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1 publication, 10%
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Russian Chemical Reviews
1 publication, 10%
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Citations by publishers
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3
4
5
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Elsevier
5 publications, 50%
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Multidisciplinary Digital Publishing Institute (MDPI)
1 publication, 10%
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American Chemical Society (ACS)
1 publication, 10%
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Wiley
1 publication, 10%
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Royal Society of Chemistry (RSC)
1 publication, 10%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 10%
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Zeng Q. et al. Application of a Modified Porphyrin in a Polymer Electrolyte with Superior Properties for All-Solid-State Lithium Batteries // ACS applied materials & interfaces. 2021. Vol. 13. No. 41. pp. 48569-48581.
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Zeng Q., Chen P., Li Z., Wen X., Wen W., Liu Yu., Zhao H., Zhang S., Zhou H., Zhang L. Application of a Modified Porphyrin in a Polymer Electrolyte with Superior Properties for All-Solid-State Lithium Batteries // ACS applied materials & interfaces. 2021. Vol. 13. No. 41. pp. 48569-48581.
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TY - JOUR
DO - 10.1021/acsami.1c12086
UR - https://doi.org/10.1021/acsami.1c12086
TI - Application of a Modified Porphyrin in a Polymer Electrolyte with Superior Properties for All-Solid-State Lithium Batteries
T2 - ACS applied materials & interfaces
AU - Li, Zhenfeng
AU - Zhang, Shuping
AU - Zhao, Hai-Lei
AU - Zhou, Henghui
AU - Zhang, Liaoyun
AU - Zeng, Qinghui
AU - Chen, Pingping
AU - Wen, Xin
AU - Wen, Wen
AU - Liu, Yu
PY - 2021
DA - 2021/10/12 00:00:00
PB - American Chemical Society (ACS)
SP - 48569-48581
IS - 41
VL - 13
SN - 1944-8244
SN - 1944-8252
ER -
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@article{2021_Zeng,
author = {Zhenfeng Li and Shuping Zhang and Hai-Lei Zhao and Henghui Zhou and Liaoyun Zhang and Qinghui Zeng and Pingping Chen and Xin Wen and Wen Wen and Yu Liu},
title = {Application of a Modified Porphyrin in a Polymer Electrolyte with Superior Properties for All-Solid-State Lithium Batteries},
journal = {ACS applied materials & interfaces},
year = {2021},
volume = {13},
publisher = {American Chemical Society (ACS)},
month = {oct},
url = {https://doi.org/10.1021/acsami.1c12086},
number = {41},
pages = {48569--48581},
doi = {10.1021/acsami.1c12086}
}
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Zeng, Qinghui, et al. “Application of a Modified Porphyrin in a Polymer Electrolyte with Superior Properties for All-Solid-State Lithium Batteries.” ACS applied materials & interfaces, vol. 13, no. 41, Oct. 2021, pp. 48569-48581. https://doi.org/10.1021/acsami.1c12086.