ACS applied materials & interfaces, volume 14, issue 14, pages 16147-16156
Influence of Porosity of Sulfide-Based Artificial Solid Electrolyte Interphases on Their Performance with Liquid and Solid Electrolytes in Li and Na Metal Batteries
Kyungmi Lim
1
,
Bernhard Fenk
1
,
Kathrin Küster
1
,
Tolga Acartürk
1
,
Jürgen Weiss
1
,
Ulrich Starke
1
,
Hai-Wen Liu
1
,
Joachim Maier
1
Publication type: Journal Article
Publication date: 2022-03-31
Journal:
ACS applied materials & interfaces
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 9.5
ISSN: 19448244, 19448252
General Materials Science
Abstract
Realization of all-solid-state batteries combined with metallic Li/Na is still hindered due to the unstable interface between the alkali metal and solid electrolytes, especially for highly promising thiophosphate materials. Artificial and uniform solid-electrolyte interphases (SEIs), serving as thin ion-conducting films, have been considered as a strategy to overcome the issues of such reactive interfaces. Here, we synthesized sulfide-based artificial SEIs (LixSy and NaxSy) on Li and Na by solid/gas reaction between the alkali metal and S vapor. The synthesized films are carefully characterized with various chemical/electrochemical techniques. We show that these artificial SEIs are not beneficial from an application point of view since they either contribute to additional resistances (Li) or do not prevent reactions at the alkali metal/electrolyte interface (Na). We show that NaxSy is more porous than LixSy, supported by (i) its rough morphology observed by focused ion beam-scanning electron microscopy, (ii) the rapid decrease of Rinterface (interfacial resistance) in NaxSy-covered-Na symmetric cells with liquid electrolyte upon aging under open-circuit potential, and (iii) the increase of Rinterface in NaxSy-covered-Na solid-state symmetric cells with Na3PS4 electrolyte. The porous SEI allows the penetration of liquid electrolyte or alkali metal creep through its pores, resulting in a continuous chemical reaction. Hence, porosity of SEIs in general should be carefully taken into account in the application of batteries containing both liquid electrolyte and solid electrolyte.
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Lim K. et al. Influence of Porosity of Sulfide-Based Artificial Solid Electrolyte Interphases on Their Performance with Liquid and Solid Electrolytes in Li and Na Metal Batteries // ACS applied materials & interfaces. 2022. Vol. 14. No. 14. pp. 16147-16156.
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Lim K., Fenk B., Küster K., Acartürk T., Weiss J., Starke U., Liu H., Maier J. Influence of Porosity of Sulfide-Based Artificial Solid Electrolyte Interphases on Their Performance with Liquid and Solid Electrolytes in Li and Na Metal Batteries // ACS applied materials & interfaces. 2022. Vol. 14. No. 14. pp. 16147-16156.
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TY - JOUR
DO - 10.1021/acsami.1c23923
UR - https://doi.org/10.1021/acsami.1c23923
TI - Influence of Porosity of Sulfide-Based Artificial Solid Electrolyte Interphases on Their Performance with Liquid and Solid Electrolytes in Li and Na Metal Batteries
T2 - ACS applied materials & interfaces
AU - Lim, Kyungmi
AU - Fenk, Bernhard
AU - Küster, Kathrin
AU - Acartürk, Tolga
AU - Weiss, Jürgen
AU - Maier, Joachim
AU - Starke, Ulrich
AU - Liu, Hai-Wen
PY - 2022
DA - 2022/03/31 00:00:00
PB - American Chemical Society (ACS)
SP - 16147-16156
IS - 14
VL - 14
SN - 1944-8244
SN - 1944-8252
ER -
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@article{2022_Lim,
author = {Kyungmi Lim and Bernhard Fenk and Kathrin Küster and Tolga Acartürk and Jürgen Weiss and Joachim Maier and Ulrich Starke and Hai-Wen Liu},
title = {Influence of Porosity of Sulfide-Based Artificial Solid Electrolyte Interphases on Their Performance with Liquid and Solid Electrolytes in Li and Na Metal Batteries},
journal = {ACS applied materials & interfaces},
year = {2022},
volume = {14},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021/acsami.1c23923},
number = {14},
pages = {16147--16156},
doi = {10.1021/acsami.1c23923}
}
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Lim, Kyungmi, et al. “Influence of Porosity of Sulfide-Based Artificial Solid Electrolyte Interphases on Their Performance with Liquid and Solid Electrolytes in Li and Na Metal Batteries.” ACS applied materials & interfaces, vol. 14, no. 14, Mar. 2022, pp. 16147-16156. https://doi.org/10.1021/acsami.1c23923.