ACS applied materials & interfaces, volume 14, issue 13, pages 15461-15467
Advanced Nonvolatile Organic Optical Memory Using Self-Assembled Monolayers of Porphyrin–Fullerene Dyads
Frolova Lyubov A
1
,
Furmansky Yulia
2
,
Shestakov Alexander F.
1
,
Liddell Paul A.
3
,
Gust Devens
3
,
Visoly-Fisher I
2
,
Troshin Pavel A.
1, 4
3
School of Molecular Sciences, College of Liberal Arts and Sciences, Arizona State University, Tempe, Arizona 85287-1604, United States
|
4
Silesian University of Technology, Akademicka 2A, 44-100 Gliwice, Poland
|
Publication type: Journal Article
Publication date: 2022-03-28
Journal:
ACS applied materials & interfaces
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 9.5
ISSN: 19448244, 19448252
PubMed ID:
35343673
General Materials Science
Abstract
Photo-switchable organic field-effect transistors (OFETs) represent an important platform for designing memory devices for a diverse array of products including security (brand-protection, copy-protection, keyless entry, etc.), credit cards, tickets, and multiple wearable organic electronics applications. Herein, we present a new concept by introducing self-assembled monolayers of donor–acceptor porphyrin–fullerene dyads as light-responsive triggers modulating the electrical characteristics of OFETs and thus pave the way to the development of advanced nonvolatile optical memory. The devices demonstrated wide memory windows, high programming speeds, and long retention times. Furthermore, we show a remarkable effect of the orientation of the fullerene–polymer dyads at the dielectric/semiconductor interface on the device behavior. In particular, the dyads anchored to the dielectric by the porphyrin part induced a reversible photoelectrical switching of OFETs, which is characteristic of flash memory elements. On the contrary, the devices utilizing the dyad anchored by the fullerene moiety demonstrated irreversible switching, thus operating as read-only memory (ROM). A mechanism explaining this behavior is proposed using theoretical DFT calculations. The results suggest the possibility of revisiting hundreds of known donor–acceptor dyads designed previously for artificial photosynthesis or other purposes as versatile optical triggers in advanced OFET-based multibit memory devices for emerging electronic applications.
Citations by journals
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1
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Journal of Materials Chemistry C
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Journal of Materials Chemistry C
1 publication, 6.67%
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Advanced Electronic Materials
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Advanced Electronic Materials
1 publication, 6.67%
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Advanced Functional Materials
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Advanced Functional Materials
1 publication, 6.67%
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Small Structures
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Small Structures
1 publication, 6.67%
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Advanced Materials
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Advanced Materials
1 publication, 6.67%
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Macromolecules
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Macromolecules
1 publication, 6.67%
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International Journal of Biological Macromolecules
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International Journal of Biological Macromolecules
1 publication, 6.67%
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Journal of Molecular Structure
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Journal of Molecular Structure
1 publication, 6.67%
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Advanced Optical Materials
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Advanced Optical Materials
1 publication, 6.67%
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DeCarbon
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DeCarbon
1 publication, 6.67%
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ACS Applied Electronic Materials
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ACS Applied Electronic Materials
1 publication, 6.67%
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Chemical Reviews
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Chemical Reviews
1 publication, 6.67%
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Journal of Photochemistry and Photobiology A: Chemistry
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Journal of Photochemistry and Photobiology A: Chemistry
1 publication, 6.67%
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1
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Citations by publishers
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1
2
3
4
5
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Wiley
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Wiley
5 publications, 33.33%
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Elsevier
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Elsevier
4 publications, 26.67%
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American Chemical Society (ACS)
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American Chemical Society (ACS)
3 publications, 20%
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Royal Society of Chemistry (RSC)
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Royal Society of Chemistry (RSC)
1 publication, 6.67%
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1
2
3
4
5
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Frolova L. A. et al. Advanced Nonvolatile Organic Optical Memory Using Self-Assembled Monolayers of Porphyrin–Fullerene Dyads // ACS applied materials & interfaces. 2022. Vol. 14. No. 13. pp. 15461-15467.
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Frolova L. A., Furmansky Y., Shestakov A. F., Emelianov N. A., Liddell P. A., Gust D., Visoly-Fisher I., Troshin P. A. Advanced Nonvolatile Organic Optical Memory Using Self-Assembled Monolayers of Porphyrin–Fullerene Dyads // ACS applied materials & interfaces. 2022. Vol. 14. No. 13. pp. 15461-15467.
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TY - JOUR
DO - 10.1021/acsami.1c24979
UR - https://doi.org/10.1021%2Facsami.1c24979
TI - Advanced Nonvolatile Organic Optical Memory Using Self-Assembled Monolayers of Porphyrin–Fullerene Dyads
T2 - ACS applied materials & interfaces
AU - Frolova, Lyubov A
AU - Furmansky, Yulia
AU - Liddell, Paul A.
AU - Shestakov, Alexander F.
AU - Emelianov, Nikita A.
AU - Gust, Devens
AU - Visoly-Fisher, I
AU - Troshin, Pavel A.
PY - 2022
DA - 2022/03/28 00:00:00
PB - American Chemical Society (ACS)
SP - 15461-15467
IS - 13
VL - 14
PMID - 35343673
SN - 1944-8244
SN - 1944-8252
ER -
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@article{2022_Frolova,
author = {Lyubov A Frolova and Yulia Furmansky and Paul A. Liddell and Alexander F. Shestakov and Nikita A. Emelianov and Devens Gust and I Visoly-Fisher and Pavel A. Troshin},
title = {Advanced Nonvolatile Organic Optical Memory Using Self-Assembled Monolayers of Porphyrin–Fullerene Dyads},
journal = {ACS applied materials & interfaces},
year = {2022},
volume = {14},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021%2Facsami.1c24979},
number = {13},
pages = {15461--15467},
doi = {10.1021/acsami.1c24979}
}
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Frolova, Lyubov A., et al. “Advanced Nonvolatile Organic Optical Memory Using Self-Assembled Monolayers of Porphyrin–Fullerene Dyads.” ACS applied materials & interfaces, vol. 14, no. 13, Mar. 2022, pp. 15461-15467. https://doi.org/10.1021%2Facsami.1c24979.