Polynitro-Functionalized Azopyrazole with High Performance and Low Sensitivity as Novel Energetic Materials
2
Institute of Chemical Materials, China Academy of Engineering Physics (CAEP), Mianyang 621900, P. R. China
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Publication type: Journal Article
Publication date: 2022-02-22
scimago Q1
wos Q1
SJR: 1.921
CiteScore: 14.5
Impact factor: 8.2
ISSN: 19448244, 19448252
PubMed ID:
35189684
General Materials Science
Abstract
The development of energetic materials is still facing a huge challenge because the relationship between energy and sensitivity is usually contradictory: high energy is always accompanied with low sensitivity. Here, a high-energy, low-sensitivity energetic polynitro-functionalized azopyrazole (TNAP) and its energetic salts have been synthesized. The structural characterization of these compounds was analyzed by elemental analysis, 1H and 13C NMR spectroscopies, and infrared spectroscopy. The single-crystal structure of compounds K2TNAP, TNAP, 5, and 6 was obtained by X-ray diffraction, and K2TNAP is a novel energetic metal-organic framework. The calculated detonation properties of TNAP (9040 m s-1 and 36.0 GPa) are superior to that of RDX (8796 m s-1 and 33.6 GPa). In addition, TNAP also has lower mechanical sensitivity (IS > 40 J, FS = 244 N) and higher decomposition temperature (Td = 221 °C) than RDX (IS = 7.4 J, FS = 120 N, and Td = 204 °C). These experimental results suggest that TNAP may become a new candidate for secondary explosives.
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47
Total citations:
47
Citations from 2025:
10
(21.28%)
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GOST
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Zhang G. et al. Polynitro-Functionalized Azopyrazole with High Performance and Low Sensitivity as Novel Energetic Materials // ACS applied materials & interfaces. 2022. Vol. 14. No. 8. pp. 10594-10604.
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Zhang G., Yi Z., Cheng G., Yang W., Yang H. Polynitro-Functionalized Azopyrazole with High Performance and Low Sensitivity as Novel Energetic Materials // ACS applied materials & interfaces. 2022. Vol. 14. No. 8. pp. 10594-10604.
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RIS
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TY - JOUR
DO - 10.1021/acsami.2c00154
UR - https://doi.org/10.1021/acsami.2c00154
TI - Polynitro-Functionalized Azopyrazole with High Performance and Low Sensitivity as Novel Energetic Materials
T2 - ACS applied materials & interfaces
AU - Zhang, Guojie
AU - Yi, Zhenxin
AU - Cheng, Guangbin
AU - Yang, Wei
AU - Yang, Hongwei
PY - 2022
DA - 2022/02/22
PB - American Chemical Society (ACS)
SP - 10594-10604
IS - 8
VL - 14
PMID - 35189684
SN - 1944-8244
SN - 1944-8252
ER -
Cite this
BibTex (up to 50 authors)
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@article{2022_Zhang,
author = {Guojie Zhang and Zhenxin Yi and Guangbin Cheng and Wei Yang and Hongwei Yang},
title = {Polynitro-Functionalized Azopyrazole with High Performance and Low Sensitivity as Novel Energetic Materials},
journal = {ACS applied materials & interfaces},
year = {2022},
volume = {14},
publisher = {American Chemical Society (ACS)},
month = {feb},
url = {https://doi.org/10.1021/acsami.2c00154},
number = {8},
pages = {10594--10604},
doi = {10.1021/acsami.2c00154}
}
Cite this
MLA
Copy
Zhang, Guojie, et al. “Polynitro-Functionalized Azopyrazole with High Performance and Low Sensitivity as Novel Energetic Materials.” ACS applied materials & interfaces, vol. 14, no. 8, Feb. 2022, pp. 10594-10604. https://doi.org/10.1021/acsami.2c00154.