ACS applied materials & interfaces, volume 14, issue 38, pages 43116-43126
Garnet Li7La3Zr2O12-Based Solid-State Lithium Batteries Achieved by In Situ Thermally Polymerized Gel Polymer Electrolyte
Meng Liu
1, 2
,
Wenhao Xie
2, 3
,
Bin Li
1
,
Yibo Wang
2
,
Guangqi Li
1
,
Songtong Zhang
2
,
Yuehua Wen
2
,
Jingyi Qiu
2
,
Junhong Chen
1
,
Pengcheng Zhao
2
2
Research Institute of Chemical Defense, Beijing Key Laboratory of Advanced Chemical Energy Storage Technology and Materials, Beijing 100191, China
|
Publication type: Journal Article
Publication date: 2022-09-19
Journal:
ACS applied materials & interfaces
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 9.5
ISSN: 19448244, 19448252
General Materials Science
Abstract
Garnet Li7La3Zr2O12 (LLZO) is a potential solid electrolyte for solid-state batteries (SSBs) because of its high ionic conductivity, electrochemical stability, and mechanical strength. However, large interface resistances arising from deserted cathodes and rigid garnet/electrode interfaces block its application. In order to deal with this issue, a gel polymer electrolyte (GPE) was introduced into the cathode and both sides of LLZO to achieve a solid-state battery. Especially, the provided GPE could be thermally polymerized and solidified in situ, which would integrate LLZO with both anode and cathode and dramatically simplify the battery manufacturing process. Since the interface from rigid LLZO is improved by the flexible GPE buffer, the inability of flexible GPE to inhibit lithium dendrites is compensated by the rigid LLZO in return. As a result, the interface resistances are reduced from 6880 to 473 Ω, the Li symmetric cell exhibits a flat galvanostatic charge/discharge for 400 h without lithium dendrites, and the solid-state Li|GPE@LLZO|LiCoO2 battery exerts a capacity retention of 82.6% after 100 cycles at 0.5 C at room temperature. Such an interfacial engineering approach represents a promising strategy to address solid-solid interface issues and provides a new design for SSBs with high performance.
Top-30
Citations by journals
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1
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Journal of Materiomics
1 publication, 7.69%
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Batteries & Supercaps
1 publication, 7.69%
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Materials
1 publication, 7.69%
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Batteries
1 publication, 7.69%
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Gels
1 publication, 7.69%
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Next Energy
1 publication, 7.69%
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Rare Metals
1 publication, 7.69%
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Journal of Power Sources
1 publication, 7.69%
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Journal of Energy Chemistry
1 publication, 7.69%
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Materials Chemistry Frontiers
1 publication, 7.69%
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Energy Storage Materials
1 publication, 7.69%
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Green Energy and Environment
1 publication, 7.69%
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Russian Chemical Reviews
1 publication, 7.69%
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1
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Citations by publishers
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1
2
3
4
5
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Elsevier
5 publications, 38.46%
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Multidisciplinary Digital Publishing Institute (MDPI)
3 publications, 23.08%
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Chinese Ceramic Society
1 publication, 7.69%
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Wiley
1 publication, 7.69%
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Nonferrous Metals Society of China
1 publication, 7.69%
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Royal Society of Chemistry (RSC)
1 publication, 7.69%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 7.69%
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1
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3
4
5
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Liu M. et al. Garnet Li7La3Zr2O12-Based Solid-State Lithium Batteries Achieved by In Situ Thermally Polymerized Gel Polymer Electrolyte // ACS applied materials & interfaces. 2022. Vol. 14. No. 38. pp. 43116-43126.
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Liu M., Xie W., Li B., Wang Y., Li G., Zhang S., Wen Y., Qiu J., Chen J., Zhao P. Garnet Li7La3Zr2O12-Based Solid-State Lithium Batteries Achieved by In Situ Thermally Polymerized Gel Polymer Electrolyte // ACS applied materials & interfaces. 2022. Vol. 14. No. 38. pp. 43116-43126.
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TY - JOUR
DO - 10.1021/acsami.2c09028
UR - https://doi.org/10.1021/acsami.2c09028
TI - Garnet Li7La3Zr2O12-Based Solid-State Lithium Batteries Achieved by In Situ Thermally Polymerized Gel Polymer Electrolyte
T2 - ACS applied materials & interfaces
AU - Liu, Meng
AU - Xie, Wenhao
AU - Li, Bin
AU - Wang, Yibo
AU - Li, Guangqi
AU - Zhang, Songtong
AU - Wen, Yuehua
AU - Qiu, Jingyi
AU - Chen, Junhong
AU - Zhao, Pengcheng
PY - 2022
DA - 2022/09/19 00:00:00
PB - American Chemical Society (ACS)
SP - 43116-43126
IS - 38
VL - 14
SN - 1944-8244
SN - 1944-8252
ER -
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@article{2022_Liu,
author = {Meng Liu and Wenhao Xie and Bin Li and Yibo Wang and Guangqi Li and Songtong Zhang and Yuehua Wen and Jingyi Qiu and Junhong Chen and Pengcheng Zhao},
title = {Garnet Li7La3Zr2O12-Based Solid-State Lithium Batteries Achieved by In Situ Thermally Polymerized Gel Polymer Electrolyte},
journal = {ACS applied materials & interfaces},
year = {2022},
volume = {14},
publisher = {American Chemical Society (ACS)},
month = {sep},
url = {https://doi.org/10.1021/acsami.2c09028},
number = {38},
pages = {43116--43126},
doi = {10.1021/acsami.2c09028}
}
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Liu, Meng, et al. “Garnet Li7La3Zr2O12-Based Solid-State Lithium Batteries Achieved by In Situ Thermally Polymerized Gel Polymer Electrolyte.” ACS applied materials & interfaces, vol. 14, no. 38, Sep. 2022, pp. 43116-43126. https://doi.org/10.1021/acsami.2c09028.