volume 15 issue 25 pages 30272-30280

NaNbV(PO4)3: Multielectron NASICON-Type Anode Material for Na-Ion Batteries with Excellent Rate Capability

Publication typeJournal Article
Publication date2023-06-17
scimago Q1
wos Q1
SJR1.921
CiteScore14.5
Impact factor8.2
ISSN19448244, 19448252
General Materials Science
Abstract
NASICON-type NaNbV(PO4)3 electrode material synthesized by the Pechini sol-gel technique undergoes a reversible three-electron reaction in a Na-ion cell which corresponds to the Nb5+/Nb4+, Nb4+/Nb3+, and V3+/V2+ redox processes and provides a reversible capacity of 180 mAh·g-1. The sodium insertion/extraction takes place in a narrow potential range at an average potential of 1.55 V versus Na+/Na. Structural characterization by operando and ex situ X-ray diffraction disclosed the reversible evolution of the NaNbV(PO4)3 polyhedron framework during cycling, while XANES measurements in the operando regime confirmed the multielectron transfer upon sodium intercalation/extraction into NaNbV(PO4)3. This electrode material demonstrates extended cycling stability and excellent rate capability maintaining the capacity value of 144 mAh·g-1 at 10 C current rates. It can be regarded as a superior anode material suitable for application in high-power and long-life sodium-ion batteries.
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Khasanova N. R. et al. NaNbV(PO4)3: Multielectron NASICON-Type Anode Material for Na-Ion Batteries with Excellent Rate Capability // ACS applied materials & interfaces. 2023. Vol. 15. No. 25. pp. 30272-30280.
GOST all authors (up to 50) Copy
Khasanova N. R., Panin R. V., Cherkashchenko I. R., Zakharkin M. V., Novichkov D. A., Antipov E. V. NaNbV(PO4)3: Multielectron NASICON-Type Anode Material for Na-Ion Batteries with Excellent Rate Capability // ACS applied materials & interfaces. 2023. Vol. 15. No. 25. pp. 30272-30280.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1021/acsami.3c04576
UR - https://pubs.acs.org/doi/10.1021/acsami.3c04576
TI - NaNbV(PO4)3: Multielectron NASICON-Type Anode Material for Na-Ion Batteries with Excellent Rate Capability
T2 - ACS applied materials & interfaces
AU - Khasanova, Nellie R.
AU - Panin, Rodion V.
AU - Cherkashchenko, Ilia R.
AU - Zakharkin, Maxim V.
AU - Novichkov, Daniil A.
AU - Antipov, Evgeny V.
PY - 2023
DA - 2023/06/17
PB - American Chemical Society (ACS)
SP - 30272-30280
IS - 25
VL - 15
PMID - 37329310
SN - 1944-8244
SN - 1944-8252
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2023_Khasanova,
author = {Nellie R. Khasanova and Rodion V. Panin and Ilia R. Cherkashchenko and Maxim V. Zakharkin and Daniil A. Novichkov and Evgeny V. Antipov},
title = {NaNbV(PO4)3: Multielectron NASICON-Type Anode Material for Na-Ion Batteries with Excellent Rate Capability},
journal = {ACS applied materials & interfaces},
year = {2023},
volume = {15},
publisher = {American Chemical Society (ACS)},
month = {jun},
url = {https://pubs.acs.org/doi/10.1021/acsami.3c04576},
number = {25},
pages = {30272--30280},
doi = {10.1021/acsami.3c04576}
}
MLA
Cite this
MLA Copy
Khasanova, Nellie R., et al. “NaNbV(PO4)3: Multielectron NASICON-Type Anode Material for Na-Ion Batteries with Excellent Rate Capability.” ACS applied materials & interfaces, vol. 15, no. 25, Jun. 2023, pp. 30272-30280. https://pubs.acs.org/doi/10.1021/acsami.3c04576.