ACS applied materials & interfaces, volume 8, issue 23, pages 14552-14557

Li-Ion Conduction and Stability of Perovskite Li3/8Sr7/16Hf1/4Ta3/4O3

Bing Huang 1, 2
Biyi Xu 3
Yutao Li 4
Weidong Zhou 4
Ya You 4
Shengwen Zhong 2, 4
Changan Wang 1
Publication typeJournal Article
Publication date2016-06-01
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor9.5
ISSN19448244, 19448252
General Materials Science
Abstract
A solid Li-ion conductor with a high room temperature Li-ion conductivity and small interfacial resistance is required for its application in next-generation Li-ion batteries. Here, we prepared a cubic perovskite-related oxide with the general formula Li3/8Sr7/16Hf1/4Ta3/4O3 (LSHT) by a conventional solid-state reaction method, which was studied by X-ray diffraction, electrochemical impedance spectroscopy, and (7)Li MAS NMR. Li3/8Sr7/16Hf1/4Ta3/4O3 has a high Li-ion conductivity of 3.8 × 10(-4) S cm(-1) at 25 °C and a low activation energy of 0.36 eV in the temperature range 298-430 K. It exhibits both high stability and small interfacial resistance with commercial organic liquid electrolytes, which makes it promising as a separator in Li-ion batteries.

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GOST Copy
Huang B. et al. Li-Ion Conduction and Stability of Perovskite Li3/8Sr7/16Hf1/4Ta3/4O3 // ACS applied materials & interfaces. 2016. Vol. 8. No. 23. pp. 14552-14557.
GOST all authors (up to 50) Copy
Huang B., Xu B., Li Y., Zhou W., You Ya., Zhong S., Wang C., Goodenough J. Li-Ion Conduction and Stability of Perovskite Li3/8Sr7/16Hf1/4Ta3/4O3 // ACS applied materials & interfaces. 2016. Vol. 8. No. 23. pp. 14552-14557.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1021/acsami.6b03070
UR - https://doi.org/10.1021/acsami.6b03070
TI - Li-Ion Conduction and Stability of Perovskite Li3/8Sr7/16Hf1/4Ta3/4O3
T2 - ACS applied materials & interfaces
AU - Huang, Bing
AU - Xu, Biyi
AU - Zhong, Shengwen
AU - Li, Yutao
AU - Zhou, Weidong
AU - You, Ya
AU - Wang, Changan
AU - Goodenough, John
PY - 2016
DA - 2016/06/01 00:00:00
PB - American Chemical Society (ACS)
SP - 14552-14557
IS - 23
VL - 8
SN - 1944-8244
SN - 1944-8252
ER -
BibTex |
Cite this
BibTex Copy
@article{2016_Huang,
author = {Bing Huang and Biyi Xu and Shengwen Zhong and Yutao Li and Weidong Zhou and Ya You and Changan Wang and John Goodenough},
title = {Li-Ion Conduction and Stability of Perovskite Li3/8Sr7/16Hf1/4Ta3/4O3},
journal = {ACS applied materials & interfaces},
year = {2016},
volume = {8},
publisher = {American Chemical Society (ACS)},
month = {jun},
url = {https://doi.org/10.1021/acsami.6b03070},
number = {23},
pages = {14552--14557},
doi = {10.1021/acsami.6b03070}
}
MLA
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MLA Copy
Huang, Bing, et al. “Li-Ion Conduction and Stability of Perovskite Li3/8Sr7/16Hf1/4Ta3/4O3.” ACS applied materials & interfaces, vol. 8, no. 23, Jun. 2016, pp. 14552-14557. https://doi.org/10.1021/acsami.6b03070.
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