ACS applied materials & interfaces, volume 9, issue 4, pages 3723-3732
Ultraconcentrated Sodium Bis(fluorosulfonyl)imide-Based Electrolytes for High-Performance Sodium Metal Batteries
Jaegi Lee
1
,
Yongwon Lee
1
,
Jeongmin Lee
1
,
Sang-Min Lee
2
,
Jeong-Hee Choi
2
,
H.S. Kim
3
,
Mi-Sook Kwon
4
,
Kisuk Kang
3
,
Kyu Tae Lee
4
,
2
Publication type: Journal Article
Publication date: 2017-01-19
Journal:
ACS applied materials & interfaces
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 9.5
ISSN: 19448244, 19448252
General Materials Science
Abstract
We present an ultraconcentrated electrolyte composed of 5 M sodium bis(fluorosulfonyl)imide in 1,2-dimethoxyethane for Na metal anodes coupled with high-voltage cathodes. Using this electrolyte, a very high Coulombic efficiency of 99.3% at the 120th cycle for Na plating/stripping is obtained in Na/stainless steel (SS) cells with highly reduced corrosivity toward Na metal and high oxidation durability (over 4.9 V versus Na/Na+) without corrosion of the aluminum cathode current collector. Importantly, the use of this ultraconcentrated electrolyte results in substantially improved rate capability in Na/SS cells and excellent cycling performance in Na/Na symmetric cells without the increase of polarization. Moreover, this ultraconcentrated electrolyte exhibits good compatibility with high-voltage Na4Fe3(PO4)2(P2O7) and Na0.7(Fe0.5Mn0.5)O2 cathodes charged to high voltages (>4.2 V versus Na/Na+), resulting in outstanding cycling stability (high reversible capacity of 109 mAh g-1 over 300 cycles for the Na/Na4Fe3(PO4)2(P2O7) cell) compared with the conventional dilute electrolyte, 1 M NaPF6 in ethylene carbonate/propylene carbonate (5/5, v/v).
Top-30
Citations by journals
|
5
10
15
20
|
|
|
Energy Storage Materials
20 publications, 10.31%
|
|
|
ACS applied materials & interfaces
16 publications, 8.25%
|
|
|
Advanced Energy Materials
11 publications, 5.67%
|
|
|
Advanced Functional Materials
9 publications, 4.64%
|
|
|
Journal of Materials Chemistry A
9 publications, 4.64%
|
|
|
Energy and Environmental Science
8 publications, 4.12%
|
|
|
Advanced Materials
7 publications, 3.61%
|
|
|
ACS Applied Energy Materials
5 publications, 2.58%
|
|
|
Nano Energy
5 publications, 2.58%
|
|
|
Journal of Physical Chemistry C
5 publications, 2.58%
|
|
|
Journal of Energy Chemistry
4 publications, 2.06%
|
|
|
Angewandte Chemie - International Edition
4 publications, 2.06%
|
|
|
Angewandte Chemie
4 publications, 2.06%
|
|
|
Small
4 publications, 2.06%
|
|
|
Chemical Communications
4 publications, 2.06%
|
|
|
Chemical Engineering Journal
3 publications, 1.55%
|
|
|
ACS Sustainable Chemistry and Engineering
3 publications, 1.55%
|
|
|
Journal of the Electrochemical Society
2 publications, 1.03%
|
|
|
Trends in Chemistry
2 publications, 1.03%
|
|
|
Journal of Power Sources
2 publications, 1.03%
|
|
|
Chem
2 publications, 1.03%
|
|
|
Journal of Molecular Liquids
2 publications, 1.03%
|
|
|
Chinese Chemical Letters
2 publications, 1.03%
|
|
|
Journal of Physical Chemistry B
2 publications, 1.03%
|
|
|
Chemical Reviews
2 publications, 1.03%
|
|
|
Sustainable Energy and Fuels
2 publications, 1.03%
|
|
|
Energy & Fuels
2 publications, 1.03%
|
|
|
Chemical Society Reviews
2 publications, 1.03%
|
|
|
Physical Chemistry Chemical Physics
2 publications, 1.03%
|
|
|
5
10
15
20
|
Citations by publishers
|
10
20
30
40
50
60
|
|
|
Wiley
53 publications, 27.32%
|
|
|
Elsevier
51 publications, 26.29%
|
|
|
American Chemical Society (ACS)
39 publications, 20.1%
|
|
|
Royal Society of Chemistry (RSC)
32 publications, 16.49%
|
|
|
Springer Nature
5 publications, 2.58%
|
|
|
The Electrochemical Society
2 publications, 1.03%
|
|
|
Multidisciplinary Digital Publishing Institute (MDPI)
2 publications, 1.03%
|
|
|
The Chemical Society of Japan
1 publication, 0.52%
|
|
|
The Electrochemical Society of Japan
1 publication, 0.52%
|
|
|
Frontiers Media S.A.
1 publication, 0.52%
|
|
|
Nonferrous Metals Society of China
1 publication, 0.52%
|
|
|
KeAi Communications Co.
1 publication, 0.52%
|
|
|
IOP Publishing
1 publication, 0.52%
|
|
|
Taylor & Francis
1 publication, 0.52%
|
|
|
OAE Publishing Inc.
1 publication, 0.52%
|
|
|
Proceedings of the National Academy of Sciences (PNAS)
1 publication, 0.52%
|
|
|
10
20
30
40
50
60
|
- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2017,2018,2019,2020,2021,2022,2023,2024],"ids":[0,0,0,0,0,0,0,0],"codes":[0,0,0,0,0,0,0,0],"imageUrls":["","","","","","","",""],"datasets":[{"label":"Citations number","data":[8,22,25,34,23,29,28,25],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":["4.12","11.34","12.89","17.53","11.86","14.95","14.43","12.89"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["Energy Storage Materials","ACS applied materials & interfaces","Advanced Energy Materials","Advanced Functional Materials","Journal of Materials Chemistry A","Energy and Environmental Science","Advanced Materials","ACS Applied Energy Materials","Nano Energy","Journal of Physical Chemistry C","Journal of Energy Chemistry","Angewandte Chemie - International Edition","Angewandte Chemie","Small","Chemical Communications","Chemical Engineering Journal","ACS Sustainable Chemistry and Engineering","Journal of the Electrochemical Society","Trends in Chemistry","Journal of Power Sources","Chem","Journal of Molecular Liquids","Chinese Chemical Letters","Journal of Physical Chemistry B","Chemical Reviews","Sustainable Energy and Fuels","Energy & Fuels","Chemical Society Reviews","Physical Chemistry Chemical Physics"],"ids":[3858,1458,22475,7715,14919,10138,25159,6419,23236,8859,20653,19215,25450,9872,9073,16275,18886,5297,4660,14844,12363,13597,20341,14990,13718,14712,10347,20586,1773],"codes":[0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/s6nfxitVCZUsdJiJZESaAXqdmMJxom8q4Ps6ayL2_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp"],"datasets":[{"label":"","data":[20,16,11,9,9,8,7,5,5,5,4,4,4,4,4,3,3,2,2,2,2,2,2,2,2,2,2,2,2],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[10.31,8.25,5.67,4.64,4.64,4.12,3.61,2.58,2.58,2.58,2.06,2.06,2.06,2.06,2.06,1.55,1.55,1.03,1.03,1.03,1.03,1.03,1.03,1.03,1.03,1.03,1.03,1.03,1.03],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["Wiley","Elsevier","American Chemical Society (ACS)","Royal Society of Chemistry (RSC)","Springer Nature","The Electrochemical Society","Multidisciplinary Digital Publishing Institute (MDPI)","The Chemical Society of Japan","The Electrochemical Society of Japan","Frontiers Media S.A.","Nonferrous Metals Society of China","KeAi Communications Co.","IOP Publishing","Taylor & Francis","OAE Publishing Inc.","Proceedings of the National Academy of Sciences (PNAS)"],"ids":[11,17,40,123,8,6916,202,6950,7035,208,1585,326,2075,18,7181,162],"codes":[0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/s6nfxitVCZUsdJiJZESaAXqdmMJxom8q4Ps6ayL2_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/ktSZPrGjOMvauY6mn7jk8bqo3Af0S6abv653w90B_medium.webp","\/storage\/images\/resized\/JWkRrt4U4oPa4E6W7adkLpyIMTatGmlu51Ge50zC_medium.webp","\/storage\/images\/resized\/4QWA67eqfcfyOiA8Wk7YnqroHFqQbTsmDJUYTCTg_medium.webp","","\/storage\/images\/resized\/jeWDR7NTA9Ab5MVz8Uqjl2RPCndzFjSyl0FaRAHg_medium.webp","\/storage\/images\/resized\/LsKy6OnmmmRGcAU6CZgWQvNiP1polbaSLNrN7zqj_medium.webp","\/storage\/images\/resized\/5YZtvLvkPZuc2JHOaZsjCvGSHFCuC3drUwN3YAc5_medium.webp","\/storage\/images\/resized\/0oGA3odz6rRHYyWD8vQnHiPJ8KIaP1PtNoJm7RE1_medium.webp","\/storage\/images\/resized\/mxFdPe9qujsfvfYfcN0QOclAiYORFb0xrRlwV8gs_medium.webp"],"datasets":[{"label":"","data":[53,51,39,32,5,2,2,1,1,1,1,1,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[27.32,26.29,20.1,16.49,2.58,1.03,1.03,0.52,0.52,0.52,0.52,0.52,0.52,0.52,0.52,0.52],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"yearsCitationsQuartiles":{"type":"bar","data":{"show":true,"labels":[2017,2018,2019,2020,2021,2022,2023,2024],"ids":[],"codes":[],"imageUrls":[],"datasets":[{"label":"Q4","backgroundColor":"rgb(221,90,78)","data":[0,0,0,1,0,0,0,0],"percentage":["0","0","0","0.52","0","0","0","0"]},{"label":"Q3","backgroundColor":"rgb(251, 163,83)","data":[0,0,0,0,0,0,0,0],"percentage":["0","0","0","0","0","0","0","0"]},{"label":"Q2","backgroundColor":"rgb(232, 213, 89)","data":[1,0,0,0,1,1,1,0],"percentage":["0.52","0","0","0","0.52","0.52","0.52","0"]},{"label":"Q1","backgroundColor":"rgb(164, 207, 99)","data":[7,22,24,33,22,25,26,23],"percentage":["3.61","11.34","12.37","17.01","11.34","12.89","13.4","11.86"]},{"label":"Quartile not defined","backgroundColor":"#E5E7EB","data":[0,0,1,0,0,3,1,2],"percentage":["0","0","0.52","0","0","1.55","0.52","1.03"]}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations quartiles by SCImago per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"yearsCitationsQuartilesWs":{"type":"bar","data":{"show":true,"labels":[2017,2018,2019,2020,2021,2022,2023,2024],"ids":[],"codes":[],"imageUrls":[],"datasets":[{"label":"Q4","backgroundColor":"rgb(221,90,78)","data":[1,0,0,1,0,0,0,0],"percentage":["0.52","0","0","0.52","0","0","0","0"]},{"label":"Q3","backgroundColor":"rgb(251, 163,83)","data":[1,1,0,0,1,1,0,0],"percentage":["0.52","0.52","0","0","0.52","0.52","0","0"]},{"label":"Q2","backgroundColor":"rgb(232, 213, 89)","data":[1,4,4,6,0,5,4,1],"percentage":["0.52","2.06","2.06","3.09","0","2.58","2.06","0.52"]},{"label":"Q1","backgroundColor":"rgb(164, 207, 99)","data":[5,15,19,25,22,19,23,22],"percentage":["2.58","7.73","9.79","12.89","11.34","9.79","11.86","11.34"]},{"label":"Quartile not defined","backgroundColor":"#E5E7EB","data":[0,2,2,2,0,4,1,2],"percentage":["0","1.03","1.03","1.03","0","2.06","0.52","1.03"]}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations quartiles by WoS per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Lee J. et al. Ultraconcentrated Sodium Bis(fluorosulfonyl)imide-Based Electrolytes for High-Performance Sodium Metal Batteries // ACS applied materials & interfaces. 2017. Vol. 9. No. 4. pp. 3723-3732.
GOST all authors (up to 50)
Copy
Lee J., Lee Y., Lee J., Lee S., Choi J., Kim H., Kwon M., Kang K., Lee K. T., Choi N. Ultraconcentrated Sodium Bis(fluorosulfonyl)imide-Based Electrolytes for High-Performance Sodium Metal Batteries // ACS applied materials & interfaces. 2017. Vol. 9. No. 4. pp. 3723-3732.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acsami.6b14878
UR - https://doi.org/10.1021/acsami.6b14878
TI - Ultraconcentrated Sodium Bis(fluorosulfonyl)imide-Based Electrolytes for High-Performance Sodium Metal Batteries
T2 - ACS applied materials & interfaces
AU - Lee, Jaegi
AU - Lee, Yongwon
AU - Lee, Jeongmin
AU - Kang, Kisuk
AU - Lee, Kyu Tae
AU - Choi, Nam-Soon
AU - Lee, Sang-Min
AU - Choi, Jeong-Hee
AU - Kim, H.S.
AU - Kwon, Mi-Sook
PY - 2017
DA - 2017/01/19 00:00:00
PB - American Chemical Society (ACS)
SP - 3723-3732
IS - 4
VL - 9
SN - 1944-8244
SN - 1944-8252
ER -
Cite this
BibTex
Copy
@article{2017_Lee,
author = {Jaegi Lee and Yongwon Lee and Jeongmin Lee and Kisuk Kang and Kyu Tae Lee and Nam-Soon Choi and Sang-Min Lee and Jeong-Hee Choi and H.S. Kim and Mi-Sook Kwon},
title = {Ultraconcentrated Sodium Bis(fluorosulfonyl)imide-Based Electrolytes for High-Performance Sodium Metal Batteries},
journal = {ACS applied materials & interfaces},
year = {2017},
volume = {9},
publisher = {American Chemical Society (ACS)},
month = {jan},
url = {https://doi.org/10.1021/acsami.6b14878},
number = {4},
pages = {3723--3732},
doi = {10.1021/acsami.6b14878}
}
Cite this
MLA
Copy
Lee, Jaegi, et al. “Ultraconcentrated Sodium Bis(fluorosulfonyl)imide-Based Electrolytes for High-Performance Sodium Metal Batteries.” ACS applied materials & interfaces, vol. 9, no. 4, Jan. 2017, pp. 3723-3732. https://doi.org/10.1021/acsami.6b14878.
Profiles