ACS applied materials & interfaces, volume 9, issue 10, pages 8737-8741

Facile and Reliable in Situ Polymerization of Poly(Ethyl Cyanoacrylate)-Based Polymer Electrolytes toward Flexible Lithium Batteries

Yanyan Cui ^{1, 2}

Jingchao Chai ^{2, 3}

Huiping Du ^{2, 3}

Yulong Duan ^{2, 3}

Guang-wen Xie ¹

Zhihong Liu ^{2, 3}

Guanglei Cui ^{2, 3}

Hide authors affiliations Show authors affiliations: 3 affiliations

Key Laboratory of Nanomaterials, Qingdao University of Science and Technology, No. 53 Zhengzhou Road, Qingdao 266042, People’s Republic of China |

Qingdao Industrial Energy Storage Research Institute, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao 266101, People’s Republic of China |

University of Chinese Academy of Sciences, No. 19A Yuquan Road, 100049, Beijing, China |

Publication type: Journal Article

Publication date: 2017-03-03

American Chemical Society (ACS)

Journal: ACS applied materials & interfaces

Quartile SCImago

Quartile WOS

Impact factor: 9.5

ISSN: 19448244, 19448252

DOI: 10.1021/acsami.6b16218

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General Materials Science

Abstract

Polycyanoacrylate is a very promising matrix for polymer electrolyte, which possesses advantages of strong binding and high electrochemical stability owing to the functional nitrile groups. Herein, a facile and reliable in situ polymerization strategy of poly(ethyl cyanoacrylate) (PECA) based gel polymer electrolytes (GPE) via a high efficient anionic polymerization was introduced consisting of PECA and 4 M LiClO4 in carbonate solvents. The in situ polymerized PECA gel polymer electrolyte achieved an excellent ionic conductivity (2.7 × 10-3 S cm-1) at room temperature, and exhibited a considerable electrochemical stability window up to 4.8 V vs Li/Li+. The LiFePO4/PECA-GPE/Li and LiNi1.5Mn0.5O4/PECA-GPE/Li batteries using this in-situ-polymerized GPE delivered stable charge/discharge profiles, considerable rate capability, and excellent cycling performance. These results demonstrated this reliable in situ polymerization process is a very promising strategy to prepare high performance polymer electrolytes for flexible thin-film batteries, micropower lithium batteries, and deformable lithium batteries for special purpose.

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Citations by journals

	1 2 3 4 5 6 7 8
Electrochimica Acta	Electrochimica Acta, 8, 6.25% Electrochimica Acta 8 publications, 6.25%
Chemical Engineering Journal	Chemical Engineering Journal, 7, 5.47% Chemical Engineering Journal 7 publications, 5.47%
ACS applied materials & interfaces	ACS applied materials & interfaces, 7, 5.47% ACS applied materials & interfaces 7 publications, 5.47%
Energy Storage Materials	Energy Storage Materials, 5, 3.91% Energy Storage Materials 5 publications, 3.91%
Journal of Power Sources	Journal of Power Sources, 5, 3.91% Journal of Power Sources 5 publications, 3.91%
Advanced Functional Materials	Advanced Functional Materials, 4, 3.13% Advanced Functional Materials 4 publications, 3.13%
Journal of the Electrochemical Society	Journal of the Electrochemical Society, 3, 2.34% Journal of the Electrochemical Society 3 publications, 2.34%
Polymers	Polymers, 3, 2.34% Polymers 3 publications, 2.34%
Advanced Energy Materials	Advanced Energy Materials, 3, 2.34% Advanced Energy Materials 3 publications, 2.34%
Chinese Chemical Letters	Chinese Chemical Letters, 3, 2.34% Chinese Chemical Letters 3 publications, 2.34%
ACS Applied Energy Materials	ACS Applied Energy Materials, 3, 2.34% ACS Applied Energy Materials 3 publications, 2.34%
Journal of Solid State Electrochemistry	Journal of Solid State Electrochemistry, 2, 1.56% Journal of Solid State Electrochemistry 2 publications, 1.56%
Ionics	Ionics, 2, 1.56% Ionics 2 publications, 1.56%
Journal of Colloid and Interface Science	Journal of Colloid and Interface Science, 2, 1.56% Journal of Colloid and Interface Science 2 publications, 1.56%
Polymer	Polymer, 2, 1.56% Polymer 2 publications, 1.56%
Journal of Energy Chemistry	Journal of Energy Chemistry, 2, 1.56% Journal of Energy Chemistry 2 publications, 1.56%
Solid State Ionics	Solid State Ionics, 2, 1.56% Solid State Ionics 2 publications, 1.56%
Nano Energy	Nano Energy, 2, 1.56% Nano Energy 2 publications, 1.56%
Advanced Science	Advanced Science, 2, 1.56% Advanced Science 2 publications, 1.56%
Journal of Physical Chemistry C	Journal of Physical Chemistry C, 2, 1.56% Journal of Physical Chemistry C 2 publications, 1.56%
Chemistry of Materials	Chemistry of Materials, 2, 1.56% Chemistry of Materials 2 publications, 1.56%
Clean Energy	Clean Energy, 2, 1.56% Clean Energy 2 publications, 1.56%
Small	Small, 2, 1.56% Small 2 publications, 1.56%
Applied Physics Letters	Applied Physics Letters, 1, 0.78% Applied Physics Letters 1 publication, 0.78%
Functional Materials Letters	Functional Materials Letters, 1, 0.78% Functional Materials Letters 1 publication, 0.78%
Molecules	Molecules, 1, 0.78% Molecules 1 publication, 0.78%
Membranes	Membranes, 1, 0.78% Membranes 1 publication, 0.78%
Nature Communications	Nature Communications, 1, 0.78% Nature Communications 1 publication, 0.78%
Science China Materials	Science China Materials, 1, 0.78% Science China Materials 1 publication, 0.78%
	1 2 3 4 5 6 7 8

Citations by publishers

	5 10 15 20 25 30 35 40 45 50
Elsevier	Elsevier, 47, 36.72% Elsevier 47 publications, 36.72%
Wiley	Wiley, 27, 21.09% Wiley 27 publications, 21.09%
American Chemical Society (ACS)	American Chemical Society (ACS), 17, 13.28% American Chemical Society (ACS) 17 publications, 13.28%
Springer Nature	Springer Nature, 12, 9.38% Springer Nature 12 publications, 9.38%
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 5, 3.91% Multidisciplinary Digital Publishing Institute (MDPI) 5 publications, 3.91%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 4, 3.13% Royal Society of Chemistry (RSC) 4 publications, 3.13%
The Electrochemical Society	The Electrochemical Society, 3, 2.34% The Electrochemical Society 3 publications, 2.34%
Oxford University Press	Oxford University Press, 2, 1.56% Oxford University Press 2 publications, 1.56%
American Institute of Physics (AIP)	American Institute of Physics (AIP), 1, 0.78% American Institute of Physics (AIP) 1 publication, 0.78%
World Scientific	World Scientific, 1, 0.78% World Scientific 1 publication, 0.78%
Chinese Ceramic Society	Chinese Ceramic Society, 1, 0.78% Chinese Ceramic Society 1 publication, 0.78%
IOP Publishing	IOP Publishing, 1, 0.78% IOP Publishing 1 publication, 0.78%
Pleiades Publishing	Pleiades Publishing, 1, 0.78% Pleiades Publishing 1 publication, 0.78%
OAE Publishing Inc.	OAE Publishing Inc., 1, 0.78% OAE Publishing Inc. 1 publication, 0.78%
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii	Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii, 1, 0.78% Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii 1 publication, 0.78%
	5 10 15 20 25 30 35 40 45 50

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Cui Y. et al. Facile and Reliable in Situ Polymerization of Poly(Ethyl Cyanoacrylate)-Based Polymer Electrolytes toward Flexible Lithium Batteries // ACS applied materials & interfaces. 2017. Vol. 9. No. 10. pp. 8737-8741.

GOST all authors (up to 50) Copy

Cui Y., Chai J., Du H., Duan Y., Xie G., Liu Z., Cui G. Facile and Reliable in Situ Polymerization of Poly(Ethyl Cyanoacrylate)-Based Polymer Electrolytes toward Flexible Lithium Batteries // ACS applied materials & interfaces. 2017. Vol. 9. No. 10. pp. 8737-8741.

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.1021/acsami.6b16218

UR - https://doi.org/10.1021/acsami.6b16218

TI - Facile and Reliable in Situ Polymerization of Poly(Ethyl Cyanoacrylate)-Based Polymer Electrolytes toward Flexible Lithium Batteries

T2 - ACS applied materials & interfaces

AU - Cui, Yanyan

AU - Chai, Jingchao

AU - Du, Huiping

AU - Duan, Yulong

AU - Liu, Zhihong

AU - Cui, Guanglei

AU - Xie, Guang-wen

PY - 2017

DA - 2017/03/03 00:00:00

PB - American Chemical Society (ACS)

SP - 8737-8741

IS - 10

VL - 9

SN - 1944-8244

SN - 1944-8252

ER -

BibTex |

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BibTex Copy

@article{2017_Cui,

author = {Yanyan Cui and Jingchao Chai and Huiping Du and Yulong Duan and Zhihong Liu and Guanglei Cui and Guang-wen Xie},

title = {Facile and Reliable in Situ Polymerization of Poly(Ethyl Cyanoacrylate)-Based Polymer Electrolytes toward Flexible Lithium Batteries},

journal = {ACS applied materials & interfaces},

year = {2017},

volume = {9},

publisher = {American Chemical Society (ACS)},

month = {mar},

url = {https://doi.org/10.1021/acsami.6b16218},

number = {10},

pages = {8737--8741},

doi = {10.1021/acsami.6b16218}

}

MLA

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MLA Copy

Cui, Yanyan, et al. “Facile and Reliable in Situ Polymerization of Poly(Ethyl Cyanoacrylate)-Based Polymer Electrolytes toward Flexible Lithium Batteries.” ACS applied materials & interfaces, vol. 9, no. 10, Mar. 2017, pp. 8737-8741. https://doi.org/10.1021/acsami.6b16218.

Found error?

Publisher

American Chemical Society (ACS)

Journal

ACS applied materials & interfaces

Quartile SCImago

Quartile WOS

Impact factor

9.5

ISSN

19448244 (Print)
19448252 (Electronic)