ACS applied materials & interfaces, volume 9, issue 50, pages 43838-43845
Ultrathin Polydiacetylene-Based Synergetic Composites with Plasmon-Enhanced Photoelectric Properties
Dubas Anastasiia L
1
,
Tameev Alexey
1
,
Ежов А. А.
2, 3
,
Ivanov Vladimir K.
4, 5
,
König Burkhard
6
,
Arslanov Vladimir V.
1
,
Gribkova Oxana
1
,
6
Institut für Organische
Chemie, Universität Regensburg, D-93040 Regensburg, Germany
|
Publication type: Journal Article
Publication date: 2017-12-05
Journal:
ACS applied materials & interfaces
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 9.5
ISSN: 19448244, 19448252
General Materials Science
Abstract
Fabricating plasmon-enhanced organic nanomaterials with technologically relevant supporting architectures on planar solids remains a challenging task in the chemistry of thin films and interfaces. In this work, we report a bottom-up assembly of ultrathin layered composites of conductive polymers with photophysical properties enhanced by gold nanoparticles. The polydiacetylene component was formed by photopolymerization of a catanionic mixture of pentacosadiynoic surfactants on a surface of citrate-stabilized gold hydrosol monitored by a fiber optic spectrometer. Microscopic examination of the 3 nm thick solid-immobilized film showed that gold nanoparticles (AuNPs) do not aggregate within the monolayer upon polymerization. This polydiacetylene/AuNPs monolayer was coupled with 60 nm thick polyaniline-based layer deposited atop. The resulting polymer composite with an integrated 4-stripe electric cell showed nonadditive electric behavior due to the formation of electron-hole pairs with increased charge carrier mobility at the interface between the polymer layers. Under visible light irradiation of the composite film, a plasmonic effect of the gold nanoparticles was observed at the onset of photoconductivity, although neither polydiacetylene nor the polyaniline component alone are photoconductive polymers. The results indicate that our bottom-up strategy can be expanded to design other plasmon-enhanced ultrathin polymer composites with potential applications in optoelectronics and photovoltaics.
Citations by journals
1
|
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Colloids and Interface Science Communications
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Colloids and Interface Science Communications
1 publication, 16.67%
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Organic Electronics
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Organic Electronics
1 publication, 16.67%
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Biosensors and Bioelectronics
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Biosensors and Bioelectronics
1 publication, 16.67%
|
Journal of Physical Chemistry Letters
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Journal of Physical Chemistry Letters
1 publication, 16.67%
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Langmuir
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Langmuir
1 publication, 16.67%
|
1
|
Citations by publishers
1
2
3
|
|
Elsevier
|
Elsevier
3 publications, 50%
|
American Chemical Society (ACS)
|
American Chemical Society (ACS)
2 publications, 33.33%
|
1
2
3
|
- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Dubas A. L. et al. Ultrathin Polydiacetylene-Based Synergetic Composites with Plasmon-Enhanced Photoelectric Properties // ACS applied materials & interfaces. 2017. Vol. 9. No. 50. pp. 43838-43845.
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Dubas A. L., Tameev A., Zvyagina A. I., Ежов А. А., Ivanov V. K., König B., Arslanov V. V., Gribkova O., Kalinina M. A. Ultrathin Polydiacetylene-Based Synergetic Composites with Plasmon-Enhanced Photoelectric Properties // ACS applied materials & interfaces. 2017. Vol. 9. No. 50. pp. 43838-43845.
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TY - JOUR
DO - 10.1021/acsami.7b12156
UR - https://doi.org/10.1021%2Facsami.7b12156
TI - Ultrathin Polydiacetylene-Based Synergetic Composites with Plasmon-Enhanced Photoelectric Properties
T2 - ACS applied materials & interfaces
AU - Dubas, Anastasiia L
AU - Arslanov, Vladimir V.
AU - Zvyagina, Alexandra I
AU - Ivanov, Vladimir K.
AU - König, Burkhard
AU - Kalinina, Maria A
AU - Tameev, Alexey
AU - Ежов, А. А.
AU - Gribkova, Oxana
PY - 2017
DA - 2017/12/05 00:00:00
PB - American Chemical Society (ACS)
SP - 43838-43845
IS - 50
VL - 9
SN - 1944-8244
SN - 1944-8252
ER -
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@article{2017_Dubas,
author = {Anastasiia L Dubas and Vladimir V. Arslanov and Alexandra I Zvyagina and Vladimir K. Ivanov and Burkhard König and Maria A Kalinina and Alexey Tameev and А. А. Ежов and Oxana Gribkova},
title = {Ultrathin Polydiacetylene-Based Synergetic Composites with Plasmon-Enhanced Photoelectric Properties},
journal = {ACS applied materials & interfaces},
year = {2017},
volume = {9},
publisher = {American Chemical Society (ACS)},
month = {dec},
url = {https://doi.org/10.1021%2Facsami.7b12156},
number = {50},
pages = {43838--43845},
doi = {10.1021/acsami.7b12156}
}
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MLA
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Dubas, Anastasiia L., et al. “Ultrathin Polydiacetylene-Based Synergetic Composites with Plasmon-Enhanced Photoelectric Properties.” ACS applied materials & interfaces, vol. 9, no. 50, Dec. 2017, pp. 43838-43845. https://doi.org/10.1021%2Facsami.7b12156.