ACS applied materials & interfaces, volume 9, issue 50, pages 43838-43845

Ultrathin Polydiacetylene-Based Synergetic Composites with Plasmon-Enhanced Photoelectric Properties

Dubas Anastasiia L 1
Ежов А. А. 2, 3
Arslanov Vladimir V. 1
Gribkova Oxana 1
Publication typeJournal Article
Publication date2017-12-05
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor9.5
ISSN19448244, 19448252
General Materials Science
Abstract
Fabricating plasmon-enhanced organic nanomaterials with technologically relevant supporting architectures on planar solids remains a challenging task in the chemistry of thin films and interfaces. In this work, we report a bottom-up assembly of ultrathin layered composites of conductive polymers with photophysical properties enhanced by gold nanoparticles. The polydiacetylene component was formed by photopolymerization of a catanionic mixture of pentacosadiynoic surfactants on a surface of citrate-stabilized gold hydrosol monitored by a fiber optic spectrometer. Microscopic examination of the 3 nm thick solid-immobilized film showed that gold nanoparticles (AuNPs) do not aggregate within the monolayer upon polymerization. This polydiacetylene/AuNPs monolayer was coupled with 60 nm thick polyaniline-based layer deposited atop. The resulting polymer composite with an integrated 4-stripe electric cell showed nonadditive electric behavior due to the formation of electron-hole pairs with increased charge carrier mobility at the interface between the polymer layers. Under visible light irradiation of the composite film, a plasmonic effect of the gold nanoparticles was observed at the onset of photoconductivity, although neither polydiacetylene nor the polyaniline component alone are photoconductive polymers. The results indicate that our bottom-up strategy can be expanded to design other plasmon-enhanced ultrathin polymer composites with potential applications in optoelectronics and photovoltaics.

Citations by journals

1
Colloids and Interface Science Communications
Colloids and Interface Science Communications, 1, 16.67%
Colloids and Interface Science Communications
1 publication, 16.67%
Organic Electronics
Organic Electronics, 1, 16.67%
Organic Electronics
1 publication, 16.67%
Biosensors and Bioelectronics
Biosensors and Bioelectronics, 1, 16.67%
Biosensors and Bioelectronics
1 publication, 16.67%
Journal of Physical Chemistry Letters
Journal of Physical Chemistry Letters, 1, 16.67%
Journal of Physical Chemistry Letters
1 publication, 16.67%
Langmuir
Langmuir, 1, 16.67%
Langmuir
1 publication, 16.67%
1

Citations by publishers

1
2
3
Elsevier
Elsevier, 3, 50%
Elsevier
3 publications, 50%
American Chemical Society (ACS)
American Chemical Society (ACS), 2, 33.33%
American Chemical Society (ACS)
2 publications, 33.33%
1
2
3
  • We do not take into account publications that without a DOI.
  • Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
  • Statistics recalculated weekly.
Metrics
Share
Cite this
GOST |
Cite this
GOST Copy
Dubas A. L. et al. Ultrathin Polydiacetylene-Based Synergetic Composites with Plasmon-Enhanced Photoelectric Properties // ACS applied materials & interfaces. 2017. Vol. 9. No. 50. pp. 43838-43845.
GOST all authors (up to 50) Copy
Dubas A. L., Tameev A., Zvyagina A. I., Ежов А. А., Ivanov V. K., König B., Arslanov V. V., Gribkova O., Kalinina M. A. Ultrathin Polydiacetylene-Based Synergetic Composites with Plasmon-Enhanced Photoelectric Properties // ACS applied materials & interfaces. 2017. Vol. 9. No. 50. pp. 43838-43845.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1021/acsami.7b12156
UR - https://doi.org/10.1021%2Facsami.7b12156
TI - Ultrathin Polydiacetylene-Based Synergetic Composites with Plasmon-Enhanced Photoelectric Properties
T2 - ACS applied materials & interfaces
AU - Dubas, Anastasiia L
AU - Arslanov, Vladimir V.
AU - Zvyagina, Alexandra I
AU - Ivanov, Vladimir K.
AU - König, Burkhard
AU - Kalinina, Maria A
AU - Tameev, Alexey
AU - Ежов, А. А.
AU - Gribkova, Oxana
PY - 2017
DA - 2017/12/05 00:00:00
PB - American Chemical Society (ACS)
SP - 43838-43845
IS - 50
VL - 9
SN - 1944-8244
SN - 1944-8252
ER -
BibTex |
Cite this
BibTex Copy
@article{2017_Dubas,
author = {Anastasiia L Dubas and Vladimir V. Arslanov and Alexandra I Zvyagina and Vladimir K. Ivanov and Burkhard König and Maria A Kalinina and Alexey Tameev and А. А. Ежов and Oxana Gribkova},
title = {Ultrathin Polydiacetylene-Based Synergetic Composites with Plasmon-Enhanced Photoelectric Properties},
journal = {ACS applied materials & interfaces},
year = {2017},
volume = {9},
publisher = {American Chemical Society (ACS)},
month = {dec},
url = {https://doi.org/10.1021%2Facsami.7b12156},
number = {50},
pages = {43838--43845},
doi = {10.1021/acsami.7b12156}
}
MLA
Cite this
MLA Copy
Dubas, Anastasiia L., et al. “Ultrathin Polydiacetylene-Based Synergetic Composites with Plasmon-Enhanced Photoelectric Properties.” ACS applied materials & interfaces, vol. 9, no. 50, Dec. 2017, pp. 43838-43845. https://doi.org/10.1021%2Facsami.7b12156.
Found error?