Exploring Highly Reversible 1.5-Electron Reactions (V3+/V4+/V5+) in Na3VCr(PO4)3 Cathode for Sodium-Ion Batteries
Publication type: Journal Article
Publication date: 2017-12-06
scimago Q1
wos Q1
SJR: 1.921
CiteScore: 14.5
Impact factor: 8.2
ISSN: 19448244, 19448252
PubMed ID:
29164850
General Materials Science
Abstract
The development of highly reversible multielectron reaction per redox center in sodium super ionic conductor-structured cathode materials is desired to improve the energy density of sodium-ion batteries. Here, we investigated more than one-electron storage of Na in Na3VCr(PO4)3. Combining a series of advanced characterization techniques such as ex situ 51V solid-state nuclear magnetic resonance, X-ray absorption near-edge structure, and in situ X-ray diffraction, we reveal that V3+/V4+ and V4+/V5+ redox couples in the materials can be accessed, leading to a 1.5-electron reaction. It is also found that a light change on the local electronic and structural states or phase change could be observed after the first cycle, resulting in the fast capacity fade at room temperature. We also showed that the irreversibility of the phase changes could be largely suppressed at low temperature, thus leading to a much improved electrochemical performance.
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Total citations:
189
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Liu R. et al. Exploring Highly Reversible 1.5-Electron Reactions (V3+/V4+/V5+) in Na3VCr(PO4)3 Cathode for Sodium-Ion Batteries // ACS applied materials & interfaces. 2017. Vol. 9. No. 50. pp. 43632-43639.
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Xu G., Fu R., Chen Z., Amine K. Exploring Highly Reversible 1.5-Electron Reactions (V3+/V4+/V5+) in Na3VCr(PO4)3 Cathode for Sodium-Ion Batteries // ACS applied materials & interfaces. 2017. Vol. 9. No. 50. pp. 43632-43639.
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TY - JOUR
DO - 10.1021/acsami.7b13018
UR - https://doi.org/10.1021/acsami.7b13018
TI - Exploring Highly Reversible 1.5-Electron Reactions (V3+/V4+/V5+) in Na3VCr(PO4)3 Cathode for Sodium-Ion Batteries
T2 - ACS applied materials & interfaces
AU - Xu, Guiliang
AU - Fu, Riqiang
AU - Chen, Zonghai
AU - Amine, Khalil
PY - 2017
DA - 2017/12/06
PB - American Chemical Society (ACS)
SP - 43632-43639
IS - 50
VL - 9
PMID - 29164850
SN - 1944-8244
SN - 1944-8252
ER -
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BibTex (up to 50 authors)
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@article{2017_Liu,
author = {Guiliang Xu and Riqiang Fu and Zonghai Chen and Khalil Amine},
title = {Exploring Highly Reversible 1.5-Electron Reactions (V3+/V4+/V5+) in Na3VCr(PO4)3 Cathode for Sodium-Ion Batteries},
journal = {ACS applied materials & interfaces},
year = {2017},
volume = {9},
publisher = {American Chemical Society (ACS)},
month = {dec},
url = {https://doi.org/10.1021/acsami.7b13018},
number = {50},
pages = {43632--43639},
doi = {10.1021/acsami.7b13018}
}
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MLA
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Liu, Rui, et al. “Exploring Highly Reversible 1.5-Electron Reactions (V3+/V4+/V5+) in Na3VCr(PO4)3 Cathode for Sodium-Ion Batteries.” ACS applied materials & interfaces, vol. 9, no. 50, Dec. 2017, pp. 43632-43639. https://doi.org/10.1021/acsami.7b13018.