ACS applied materials & interfaces, volume 10, issue 18, pages 16033-16040

Hybrid Black Phosphorus/Zero-Dimensional Quantum Dot Phototransistors: Tunable Photodoping and Enhanced Photoresponsivity

A-Young Lee ¹

Hyun Soo Ra ¹

Do Hyun Kwak ¹

Min Hye Jeong ¹

JEONG HYUN PARK ¹

Yeon Su Kang ¹

Weon-Sik Chae ²

Joohyoung Lee ¹

Hide authors affiliations Show authors affiliations: 2 affiliations

Department of Energy Science and Engineering, DGIST, Daegu 42988, Republic of Korea |

Analysis Research Division, Daegu Center, Korea Basic Science Institute, Daegu 41566, Republic of Korea |

Publication type: Journal Article

Publication date: 2018-04-13

American Chemical Society (ACS)

Journal: ACS applied materials & interfaces

Quartile SCImago

Quartile WOS

Impact factor: 9.5

ISSN: 19448244, 19448252

DOI: 10.1021/acsami.8b03285

Copy DOI

General Materials Science

Abstract

Recently, black phosphorus (BP) with direct band gap exhibited excellent potential for optoelectronic applications because of its high charge carrier mobility and low dark current as well as the variable band gap of 0.3-1.5 eV depending on the number of layers. However, few-layer BP-based phototransistors (photo-FETs) have been limited in sensitivity and wavelength selectivity. To overcome the drawback of these photo-FETs, we studied hybrid photo-FETs combined with the novel properties of the two materials between the channel and sensitizer layers. By combining a strong absorbance of a quantum dot (QD) layer and a two-dimensional layer material with high carrier mobility, the hybrid photo-FETs are expected to produce high-performance photodetectors that can effectively control the responsivity, detectivity, and response time. In this study, we demonstrate that the photogenerated carriers formed from QD sensitizer layers migrate to the BP transport layer with high charge mobility and not only improve the photodetector performance but also enhance the photodoping effect of the BP transport layer with an ambipolar characteristic by electrons transferred from n-type CdSe QDs or holes injected from p-type PbS QDs. The responsivity and detectivity of hybrid BP/0D photo-FETs exhibit 1.16 × 109 A W-1 and 7.53 × 1016 Jones for the BP/CdSe QD photo-FET and 5.36 × 108 A W-1 and 1.89 × 1016 Jones for the BP/PbS QD photo-FET, respectively. The photocurrent rise (τrise) and decay (τdecay) times were τrise = 0.406 s and τdecay = 0.815 s for BP/CdSe QD photo-FET and τrise = 0.576 s and τdecay = 0.773 s for BP/PbS QD photo-FET, respectively.

By date By citations

Top-30

Citations by journals

	1 2 3 4
ACS applied materials & interfaces	ACS applied materials & interfaces, 4, 13.33% ACS applied materials & interfaces 4 publications, 13.33%
Applied Physics Letters	Applied Physics Letters, 2, 6.67% Applied Physics Letters 2 publications, 6.67%
Micromachines	Micromachines, 2, 6.67% Micromachines 2 publications, 6.67%
Journal of Communications Technology and Electronics	Journal of Communications Technology and Electronics, 2, 6.67% Journal of Communications Technology and Electronics 2 publications, 6.67%
Physical Review B	Physical Review B, 1, 3.33% Physical Review B 1 publication, 3.33%
Materials	Materials, 1, 3.33% Materials 1 publication, 3.33%
Nanomaterials	Nanomaterials, 1, 3.33% Nanomaterials 1 publication, 3.33%
npj 2D Materials and Applications	npj 2D Materials and Applications, 1, 3.33% npj 2D Materials and Applications 1 publication, 3.33%
Advanced Energy Materials	Advanced Energy Materials, 1, 3.33% Advanced Energy Materials 1 publication, 3.33%
Applied Surface Science	Applied Surface Science, 1, 3.33% Applied Surface Science 1 publication, 3.33%
Journal of Alloys and Compounds	Journal of Alloys and Compounds, 1, 3.33% Journal of Alloys and Compounds 1 publication, 3.33%
Journal of Molecular Liquids	Journal of Molecular Liquids, 1, 3.33% Journal of Molecular Liquids 1 publication, 3.33%
Advanced Functional Materials	Advanced Functional Materials, 1, 3.33% Advanced Functional Materials 1 publication, 3.33%
Advanced Science	Advanced Science, 1, 3.33% Advanced Science 1 publication, 3.33%
Advanced Materials	Advanced Materials, 1, 3.33% Advanced Materials 1 publication, 3.33%
ACS Photonics	ACS Photonics, 1, 3.33% ACS Photonics 1 publication, 3.33%
Journal of Physical Chemistry C	Journal of Physical Chemistry C, 1, 3.33% Journal of Physical Chemistry C 1 publication, 3.33%
Physical Review Applied	Physical Review Applied, 1, 3.33% Physical Review Applied 1 publication, 3.33%
Journal of Materials Chemistry C	Journal of Materials Chemistry C, 1, 3.33% Journal of Materials Chemistry C 1 publication, 3.33%
Small Methods	Small Methods, 1, 3.33% Small Methods 1 publication, 3.33%
Current Applied Physics	Current Applied Physics, 1, 3.33% Current Applied Physics 1 publication, 3.33%
2D Materials	2D Materials, 1, 3.33% 2D Materials 1 publication, 3.33%
Electron	Electron, 1, 3.33% Electron 1 publication, 3.33%
Russian Chemical Reviews	Russian Chemical Reviews, 1, 3.33% Russian Chemical Reviews 1 publication, 3.33%
	1 2 3 4

Citations by publishers

	1 2 3 4 5 6
Wiley	Wiley, 6, 20% Wiley 6 publications, 20%
American Chemical Society (ACS)	American Chemical Society (ACS), 6, 20% American Chemical Society (ACS) 6 publications, 20%
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 4, 13.33% Multidisciplinary Digital Publishing Institute (MDPI) 4 publications, 13.33%
Elsevier	Elsevier, 4, 13.33% Elsevier 4 publications, 13.33%
American Institute of Physics (AIP)	American Institute of Physics (AIP), 2, 6.67% American Institute of Physics (AIP) 2 publications, 6.67%
American Physical Society (APS)	American Physical Society (APS), 2, 6.67% American Physical Society (APS) 2 publications, 6.67%
Pleiades Publishing	Pleiades Publishing, 2, 6.67% Pleiades Publishing 2 publications, 6.67%
Springer Nature	Springer Nature, 1, 3.33% Springer Nature 1 publication, 3.33%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 1, 3.33% Royal Society of Chemistry (RSC) 1 publication, 3.33%
IOP Publishing	IOP Publishing, 1, 3.33% IOP Publishing 1 publication, 3.33%
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii	Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii, 1, 3.33% Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii 1 publication, 3.33%
	1 2 3 4 5 6

We do not take into account publications without a DOI.
Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
Statistics recalculated weekly.

{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2019,2020,2021,2022,2023,2024],"ids":[0,0,0,0,0,0],"codes":[0,0,0,0,0,0],"imageUrls":["","","","","",""],"datasets":[{"label":"Citations number","data":[8,4,6,3,6,3],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":["26.67","13.33","20","10","20","10"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["ACS applied materials & interfaces","Applied Physics Letters","Micromachines","Journal of Communications Technology and Electronics","Physical Review B","Materials","Nanomaterials","npj 2D Materials and Applications","Advanced Energy Materials","Applied Surface Science","Journal of Alloys and Compounds","Journal of Molecular Liquids","Advanced Functional Materials","Advanced Science","Advanced Materials","ACS Photonics","Journal of Physical Chemistry C","Physical Review Applied","Journal of Materials Chemistry C","Small Methods","Current Applied Physics","2D Materials","Electron","Russian Chemical Reviews"],"ids":[1458,4202,1083,3665,25280,25198,10051,3271,22475,12539,4015,13597,7715,4130,25159,12730,8859,15438,3848,4145,18948,22357,42222,23802],"codes":[0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/ARM4e6URKRsbRZvIF0vFis9DjxGloBjnBYJXbHmZ_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/oZgeErrVFhuDksyqFURLvYS1wtVSBWczh001igGo_medium.webp","\/storage\/images\/resized\/nrK64iXHTzj43wMrfN1ZoUQ0vanswGzWPN45K3jA_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/nrK64iXHTzj43wMrfN1ZoUQ0vanswGzWPN45K3jA_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/LsKy6OnmmmRGcAU6CZgWQvNiP1polbaSLNrN7zqj_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/9Mus3KG1Tkd7Bwaurt8H3RwWh0CxRlGoO6ng9UK1_medium.webp"],"datasets":[{"label":"","data":[4,2,2,2,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[13.33,6.67,6.67,6.67,3.33,3.33,3.33,3.33,3.33,3.33,3.33,3.33,3.33,3.33,3.33,3.33,3.33,3.33,3.33,3.33,3.33,3.33,3.33,3.33],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["Wiley","American Chemical Society (ACS)","Multidisciplinary Digital Publishing Institute (MDPI)","Elsevier","American Institute of Physics (AIP)","American Physical Society (APS)","Pleiades Publishing","Springer Nature","Royal Society of Chemistry (RSC)","IOP Publishing","Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii"],"ids":[11,40,202,17,250,1539,101,8,123,2075,9422],"codes":[0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/ARM4e6URKRsbRZvIF0vFis9DjxGloBjnBYJXbHmZ_medium.webp","\/storage\/images\/resized\/nrK64iXHTzj43wMrfN1ZoUQ0vanswGzWPN45K3jA_medium.webp","\/storage\/images\/resized\/oZgeErrVFhuDksyqFURLvYS1wtVSBWczh001igGo_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/LsKy6OnmmmRGcAU6CZgWQvNiP1polbaSLNrN7zqj_medium.webp","\/storage\/images\/resized\/9Mus3KG1Tkd7Bwaurt8H3RwWh0CxRlGoO6ng9UK1_medium.webp"],"datasets":[{"label":"","data":[6,6,4,4,2,2,2,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[20,20,13.33,13.33,6.67,6.67,6.67,3.33,3.33,3.33,3.33],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"yearsCitationsQuartiles":{"type":"bar","data":{"show":true,"labels":[2019,2020,2021,2022,2023,2024],"ids":[],"codes":[],"imageUrls":[],"datasets":[{"label":"Q4","backgroundColor":"rgb(221,90,78)","data":[0,0,0,0,0,0],"percentage":["0","0","0","0","0","0"]},{"label":"Q3","backgroundColor":"rgb(251, 163,83)","data":[0,0,0,2,0,0],"percentage":["0","0","0","6.67","0","0"]},{"label":"Q2","backgroundColor":"rgb(232, 213, 89)","data":[2,0,1,0,1,0],"percentage":["6.67","0","3.33","0","3.33","0"]},{"label":"Q1","backgroundColor":"rgb(164, 207, 99)","data":[6,4,5,1,5,2],"percentage":["20","13.33","16.67","3.33","16.67","6.67"]},{"label":"Quartile not defined","backgroundColor":"#E5E7EB","data":[0,0,0,0,0,1],"percentage":["0","0","0","0","0","3.33"]}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations quartiles by SCImago per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"yearsCitationsQuartilesWs":{"type":"bar","data":{"show":true,"labels":[2019,2020,2021,2022,2023,2024],"ids":[],"codes":[],"imageUrls":[],"datasets":[{"label":"Q4","backgroundColor":"rgb(221,90,78)","data":[0,0,0,2,0,0],"percentage":["0","0","0","6.67","0","0"]},{"label":"Q3","backgroundColor":"rgb(251, 163,83)","data":[0,0,0,0,1,0],"percentage":["0","0","0","0","3.33","0"]},{"label":"Q2","backgroundColor":"rgb(232, 213, 89)","data":[4,0,2,0,2,1],"percentage":["13.33","0","6.67","0","6.67","3.33"]},{"label":"Q1","backgroundColor":"rgb(164, 207, 99)","data":[4,4,4,1,3,1],"percentage":["13.33","13.33","13.33","3.33","10","3.33"]},{"label":"Quartile not defined","backgroundColor":"#E5E7EB","data":[0,0,0,0,0,1],"percentage":["0","0","0","0","0","3.33"]}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations quartiles by WoS per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}

Are you a researcher?

Create a profile to get free access to personal recommendations for colleagues and new articles.

Metrics

Cite this

GOST |

Cite this

GOST Copy

Lee A. et al. Hybrid Black Phosphorus/Zero-Dimensional Quantum Dot Phototransistors: Tunable Photodoping and Enhanced Photoresponsivity // ACS applied materials & interfaces. 2018. Vol. 10. No. 18. pp. 16033-16040.

GOST all authors (up to 50) Copy

Lee A., Ra H. S., Kwak D. H., Jeong M. H., PARK J. H., Kang Y. S., Chae W., Lee J. Hybrid Black Phosphorus/Zero-Dimensional Quantum Dot Phototransistors: Tunable Photodoping and Enhanced Photoresponsivity // ACS applied materials & interfaces. 2018. Vol. 10. No. 18. pp. 16033-16040.

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.1021/acsami.8b03285

UR - https://doi.org/10.1021/acsami.8b03285

TI - Hybrid Black Phosphorus/Zero-Dimensional Quantum Dot Phototransistors: Tunable Photodoping and Enhanced Photoresponsivity

T2 - ACS applied materials & interfaces

AU - Lee, A-Young

AU - Ra, Hyun Soo

AU - Kwak, Do Hyun

AU - Jeong, Min Hye

AU - PARK, JEONG HYUN

AU - Kang, Yeon Su

AU - Chae, Weon-Sik

AU - Lee, Joohyoung

PY - 2018

DA - 2018/04/13 00:00:00

PB - American Chemical Society (ACS)

SP - 16033-16040

IS - 18

VL - 10

SN - 1944-8244

SN - 1944-8252

ER -

BibTex |

Cite this

BibTex Copy

@article{2018_Lee,

author = {A-Young Lee and Hyun Soo Ra and Do Hyun Kwak and Min Hye Jeong and JEONG HYUN PARK and Yeon Su Kang and Weon-Sik Chae and Joohyoung Lee},

title = {Hybrid Black Phosphorus/Zero-Dimensional Quantum Dot Phototransistors: Tunable Photodoping and Enhanced Photoresponsivity},

journal = {ACS applied materials & interfaces},

year = {2018},

volume = {10},

publisher = {American Chemical Society (ACS)},

month = {apr},

url = {https://doi.org/10.1021/acsami.8b03285},

number = {18},

pages = {16033--16040},

doi = {10.1021/acsami.8b03285}

}

MLA

Cite this

MLA Copy

Lee, A-Young, et al. “Hybrid Black Phosphorus/Zero-Dimensional Quantum Dot Phototransistors: Tunable Photodoping and Enhanced Photoresponsivity.” ACS applied materials & interfaces, vol. 10, no. 18, Apr. 2018, pp. 16033-16040. https://doi.org/10.1021/acsami.8b03285.

Found error?

Publisher

American Chemical Society (ACS)

Journal

ACS applied materials & interfaces

Quartile SCImago

Quartile WOS

Impact factor

9.5

ISSN

19448244 (Print)
19448252 (Electronic)