volume 10 issue 50 pages 43311-43315

Toward Higher Capacities of Hydrocarbon Cathodes in Dual-Ion Batteries

Ismael A. Rodríguez-Pérez 1
Clement Bommier 1
Duncan D Fuller 1
Daniel P Leonard 1
Andrew G Williams 1
Publication typeJournal Article
Publication date2018-11-29
scimago Q1
wos Q1
SJR1.921
CiteScore14.5
Impact factor8.2
ISSN19448244, 19448252
General Materials Science
Abstract
We report the electrochemical anion storage properties of a group of molecular solids of polycyclic aromatic hydrocarbons (PAHs): coronene, perylene, and triphenylene. We discover an interesting trend of progressively lower potentials for these three molecular solids. Our DFT calculations reveal that the inserted PF6- anions preferably bind with the edge sites of the coronene molecules as opposed to being sandwiched between two coronene molecular planes. For smaller PAHs, the more edge sites in the solids may facilitate higher capacity values. However, small PAHs do face a greater challenge of dissolution in the nonaqueous electrolyte, which affects the cycling stability.
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GOST Copy
Rodríguez-Pérez I. A. et al. Toward Higher Capacities of Hydrocarbon Cathodes in Dual-Ion Batteries // ACS applied materials & interfaces. 2018. Vol. 10. No. 50. pp. 43311-43315.
GOST all authors (up to 50) Copy
Rodríguez-Pérez I. A., Bommier C., Fuller D. D., Leonard D. P., Williams A. G., Ji X. Toward Higher Capacities of Hydrocarbon Cathodes in Dual-Ion Batteries // ACS applied materials & interfaces. 2018. Vol. 10. No. 50. pp. 43311-43315.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1021/acsami.8b17105
UR - https://doi.org/10.1021/acsami.8b17105
TI - Toward Higher Capacities of Hydrocarbon Cathodes in Dual-Ion Batteries
T2 - ACS applied materials & interfaces
AU - Rodríguez-Pérez, Ismael A.
AU - Bommier, Clement
AU - Fuller, Duncan D
AU - Leonard, Daniel P
AU - Williams, Andrew G
AU - Ji, Xiulei
PY - 2018
DA - 2018/11/29
PB - American Chemical Society (ACS)
SP - 43311-43315
IS - 50
VL - 10
PMID - 30496687
SN - 1944-8244
SN - 1944-8252
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2018_Rodríguez-Pérez,
author = {Ismael A. Rodríguez-Pérez and Clement Bommier and Duncan D Fuller and Daniel P Leonard and Andrew G Williams and Xiulei Ji},
title = {Toward Higher Capacities of Hydrocarbon Cathodes in Dual-Ion Batteries},
journal = {ACS applied materials & interfaces},
year = {2018},
volume = {10},
publisher = {American Chemical Society (ACS)},
month = {nov},
url = {https://doi.org/10.1021/acsami.8b17105},
number = {50},
pages = {43311--43315},
doi = {10.1021/acsami.8b17105}
}
MLA
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MLA Copy
Rodríguez-Pérez, Ismael A., et al. “Toward Higher Capacities of Hydrocarbon Cathodes in Dual-Ion Batteries.” ACS applied materials & interfaces, vol. 10, no. 50, Nov. 2018, pp. 43311-43315. https://doi.org/10.1021/acsami.8b17105.