ACS applied materials & interfaces, volume 11, issue 6, pages 6015-6021
Rapid and Economic Synthesis of a Li7PS6 Solid Electrolyte from a Liquid Approach
Publication type: Journal Article
Publication date: 2019-01-17
Journal:
ACS applied materials & interfaces
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 9.5
ISSN: 19448244, 19448252
General Materials Science
Abstract
Solid electrolytes are the key to realize future solid-state batteries that show the advantages of high energy density and intrinsic safety. However, most solid electrolytes require long time and energy-consuming synthesis conditions of either extended ball milling or high-temperature solid-state reactions, impeding practical applications of solid electrolytes for large-scale systems. Here, we report a new and rapid liquid-based synthetic method for preparing a high-purity Li7PS6 solid electrolyte through the stoichemical reaction of Li3PS4 and Li2S. This method relies on facile and low-cost solution-based soft chemistry to complete chemical reaction in extensively short time (2 h). The prepared Li7PS6 solid electrolyte shows a high phase purity, an impressive ionic conductivity (0.11 mS cm-1), and a reasonable electrochemical stability with a metallic lithium anode. Our results highlight the use of an economic and nontoxic solvent to quickly synthesize a Li7PS6 solid electrolyte, which would promote the development of solid-state batteries for next-generation energy storage systems.
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Citations by publishers
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25
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Elsevier
24 publications, 31.17%
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21 publications, 27.27%
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Wiley
10 publications, 12.99%
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8 publications, 10.39%
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Springer Nature
3 publications, 3.9%
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Walter de Gruyter
2 publications, 2.6%
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World Scientific
1 publication, 1.3%
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Social Science Electronic Publishing
1 publication, 1.3%
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Multidisciplinary Digital Publishing Institute (MDPI)
1 publication, 1.3%
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Proceedings of the National Academy of Sciences (PNAS)
1 publication, 1.3%
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American Association for the Advancement of Science (AAAS)
1 publication, 1.3%
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Taylor & Francis
1 publication, 1.3%
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The Electrochemical Society
1 publication, 1.3%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 1.3%
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5
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25
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Ziolkowska D. A. et al. Rapid and Economic Synthesis of a Li7PS6 Solid Electrolyte from a Liquid Approach // ACS applied materials & interfaces. 2019. Vol. 11. No. 6. pp. 6015-6021.
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Ziolkowska D. A., Arnold W., Druffel T., Sunkara M., Wang H. Rapid and Economic Synthesis of a Li7PS6 Solid Electrolyte from a Liquid Approach // ACS applied materials & interfaces. 2019. Vol. 11. No. 6. pp. 6015-6021.
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TY - JOUR
DO - 10.1021/acsami.8b19181
UR - https://doi.org/10.1021/acsami.8b19181
TI - Rapid and Economic Synthesis of a Li7PS6 Solid Electrolyte from a Liquid Approach
T2 - ACS applied materials & interfaces
AU - Druffel, Thad
AU - Sunkara, Mahendra
AU - Wang, Hui
AU - Ziolkowska, Dominika A
AU - Arnold, William
PY - 2019
DA - 2019/01/17 00:00:00
PB - American Chemical Society (ACS)
SP - 6015-6021
IS - 6
VL - 11
SN - 1944-8244
SN - 1944-8252
ER -
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@article{2019_Ziolkowska,
author = {Thad Druffel and Mahendra Sunkara and Hui Wang and Dominika A Ziolkowska and William Arnold},
title = {Rapid and Economic Synthesis of a Li7PS6 Solid Electrolyte from a Liquid Approach},
journal = {ACS applied materials & interfaces},
year = {2019},
volume = {11},
publisher = {American Chemical Society (ACS)},
month = {jan},
url = {https://doi.org/10.1021/acsami.8b19181},
number = {6},
pages = {6015--6021},
doi = {10.1021/acsami.8b19181}
}
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MLA
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Ziolkowska, Dominika A., et al. “Rapid and Economic Synthesis of a Li7PS6 Solid Electrolyte from a Liquid Approach.” ACS applied materials & interfaces, vol. 11, no. 6, Jan. 2019, pp. 6015-6021. https://doi.org/10.1021/acsami.8b19181.