volume 11 issue 38 pages 34889-34894

Li–Nb–O Coating/Substitution Enhances the Electrochemical Performance of the LiNi0.8Mn0.1Co0.1O2 (NMC 811) Cathode

Publication typeJournal Article
Publication date2019-08-30
scimago Q1
wos Q1
SJR1.921
CiteScore14.5
Impact factor8.2
ISSN19448244, 19448252
General Materials Science
Abstract
High-nickel layered oxides, such as NMC 811, are very attractive high energy density cathode materials. However, the high nickel content creates a number of challenges, including high surface reactivity and structural instability. Through a wet chemistry method, a Li-Nb-O coated and substituted NMC 811 was obtained in a single step treatment. This Li-Nb-O treatment not only supplied a protective surface coating but also optimized the electrochemical behavior by Nb5+ incorporation into the bulk structure. As a result, the 1st capacity loss was significantly reduced (13.7 vs. 25.1 mAh/g), contributing at least a 5% increase to the energy density of the full cell. In addition, both the rate (158 vs. 135 mAh/g at 2C) and capacity retention (89.6 vs. 81.6% after 60 cycles) performance were enhanced.
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Xin F. et al. Li–Nb–O Coating/Substitution Enhances the Electrochemical Performance of the LiNi0.8Mn0.1Co0.1O2 (NMC 811) Cathode // ACS applied materials & interfaces. 2019. Vol. 11. No. 38. pp. 34889-34894.
GOST all authors (up to 50) Copy
Xin F., Zhou H., Chen X., Zuba M., Chernova N. A., Zhou G., Whittingham M. S. Li–Nb–O Coating/Substitution Enhances the Electrochemical Performance of the LiNi0.8Mn0.1Co0.1O2 (NMC 811) Cathode // ACS applied materials & interfaces. 2019. Vol. 11. No. 38. pp. 34889-34894.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1021/acsami.9b09696
UR - https://doi.org/10.1021/acsami.9b09696
TI - Li–Nb–O Coating/Substitution Enhances the Electrochemical Performance of the LiNi0.8Mn0.1Co0.1O2 (NMC 811) Cathode
T2 - ACS applied materials & interfaces
AU - Xin, Feng-Xia
AU - Zhou, Hui
AU - Chen, Xiaobo
AU - Zuba, Mateusz
AU - Chernova, Natasha A.
AU - Zhou, Guangwen
AU - Whittingham, M. Stanley
PY - 2019
DA - 2019/08/30
PB - American Chemical Society (ACS)
SP - 34889-34894
IS - 38
VL - 11
PMID - 31466439
SN - 1944-8244
SN - 1944-8252
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2019_Xin,
author = {Feng-Xia Xin and Hui Zhou and Xiaobo Chen and Mateusz Zuba and Natasha A. Chernova and Guangwen Zhou and M. Stanley Whittingham},
title = {Li–Nb–O Coating/Substitution Enhances the Electrochemical Performance of the LiNi0.8Mn0.1Co0.1O2 (NMC 811) Cathode},
journal = {ACS applied materials & interfaces},
year = {2019},
volume = {11},
publisher = {American Chemical Society (ACS)},
month = {aug},
url = {https://doi.org/10.1021/acsami.9b09696},
number = {38},
pages = {34889--34894},
doi = {10.1021/acsami.9b09696}
}
MLA
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MLA Copy
Xin, Feng-Xia, et al. “Li–Nb–O Coating/Substitution Enhances the Electrochemical Performance of the LiNi0.8Mn0.1Co0.1O2 (NMC 811) Cathode.” ACS applied materials & interfaces, vol. 11, no. 38, Aug. 2019, pp. 34889-34894. https://doi.org/10.1021/acsami.9b09696.