ACS applied materials & interfaces, volume 11, issue 40, pages 36774-36781
High Capacity and Superior Cyclic Performances of All-Solid-State Lithium–Sulfur Batteries Enabled by a High-Conductivity Li10SnP2S12 Solid Electrolyte
Publication type: Journal Article
Publication date: 2019-09-11
Journal:
ACS applied materials & interfaces
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 9.5
ISSN: 19448244, 19448252
General Materials Science
Abstract
All-solid-state lithium-sulfur batteries (ASSLSBs) employing sulfide-based solid electrolytes have gained widespread attention for their high energy density and intrinsic safety. Li10SnP2S12 is identified as one of the most rivaling candidates in sulfide electrolytes. Herein, a highly Li-ion-conductive Li10SnP2S12 solid-state electrolyte (SSE) is synthesized via a combination of high-energy ball-milling and heat treatment processes, which is more facile and efficient compared with other previously reported methods. The obtained Li10SnP2S12 SSE exhibits high ionic conductivity (3.2 × 10-3 S cm-1) at room temperature (RT). The effects of the annealing temperature on the Li-ion conductivity and activation energy of Li10SnP2S12 are also thoroughly studied. Moreover, the ASSLSBs based on the Li10SnP2S12 electrolyte are constructed, and they deliver a high initial capacity of 1601.7 mAh g-1 at 40 mA g-1. A favorable capacity retention upon cycling and a good rate performance are also achieved at RT. Concomitantly, the Coulombic efficiency approaches 100% during the prolonged cycling. This work tremendously accelerates the practical applications of the Li10SnP2S12 SSE among the emerging high-energy ASSLSBs.
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Yi J. et al. High Capacity and Superior Cyclic Performances of All-Solid-State Lithium–Sulfur Batteries Enabled by a High-Conductivity Li10SnP2S12 Solid Electrolyte // ACS applied materials & interfaces. 2019. Vol. 11. No. 40. pp. 36774-36781.
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Yi J., Chen L., Liu Y., Geng H., Fan L. High Capacity and Superior Cyclic Performances of All-Solid-State Lithium–Sulfur Batteries Enabled by a High-Conductivity Li10SnP2S12 Solid Electrolyte // ACS applied materials & interfaces. 2019. Vol. 11. No. 40. pp. 36774-36781.
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TY - JOUR
DO - 10.1021/acsami.9b12846
UR - https://doi.org/10.1021/acsami.9b12846
TI - High Capacity and Superior Cyclic Performances of All-Solid-State Lithium–Sulfur Batteries Enabled by a High-Conductivity Li10SnP2S12 Solid Electrolyte
T2 - ACS applied materials & interfaces
AU - Yi, Jingguang
AU - Geng, Hongxia
AU - Liu, Yongchang
AU - Fan, Li‐Zhen
AU - Chen, Long
PY - 2019
DA - 2019/09/11 00:00:00
PB - American Chemical Society (ACS)
SP - 36774-36781
IS - 40
VL - 11
SN - 1944-8244
SN - 1944-8252
ER -
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@article{2019_Yi,
author = {Jingguang Yi and Hongxia Geng and Yongchang Liu and Li‐Zhen Fan and Long Chen},
title = {High Capacity and Superior Cyclic Performances of All-Solid-State Lithium–Sulfur Batteries Enabled by a High-Conductivity Li10SnP2S12 Solid Electrolyte},
journal = {ACS applied materials & interfaces},
year = {2019},
volume = {11},
publisher = {American Chemical Society (ACS)},
month = {sep},
url = {https://doi.org/10.1021/acsami.9b12846},
number = {40},
pages = {36774--36781},
doi = {10.1021/acsami.9b12846}
}
Cite this
MLA
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Yi, Jingguang, et al. “High Capacity and Superior Cyclic Performances of All-Solid-State Lithium–Sulfur Batteries Enabled by a High-Conductivity Li10SnP2S12 Solid Electrolyte.” ACS applied materials & interfaces, vol. 11, no. 40, Sep. 2019, pp. 36774-36781. https://doi.org/10.1021/acsami.9b12846.