volume 11 issue 37 pages 34526-34531

Polymorph-Dependent Luminescence Response to Acid Vapors and Its Application in Safety Protection of File Information

Publication typeJournal Article
Publication date2019-08-28
scimago Q1
wos Q1
SJR1.921
CiteScore14.5
Impact factor8.2
ISSN19448244, 19448252
General Materials Science
Abstract
A Schiff base, (E)-1-(phenylimino)methyl-2-hydroxylnaphthalene (PIHN), was found to form both nonluminescent and luminescent polymorphs. A unique luminescence "turn on" behavior was observed when the nonluminescent polymorph was fumed with the vapor of aliphatic acids with two or three carbons in the main chain, while the luminescent polymorphs almost did not change the emission color under the same condition. As we know, this is the first report on polymorph-dependent acid response which discloses the influence of crystalline phase on acid-responsive behavior. The formation of hydrogen bonds between PIHN and aliphatic acid is proposed to be the reason for the responsive behavior of the nonemissive polymorph, and such a mechanism is different from the common protonation mechanism. A novel safety protection method of file information has been developed based on the polymorph-dependent luminescence response of PIHN. In addition, we disclose that a crystalline form could show multiple responsive behaviors toward different acids, which benefits the further design of novel acid sensors, such as the sensors that can qualitatively analyze the species of the acid source in an acidic environment.
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GOST |
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GOST Copy
Liu H. et al. Polymorph-Dependent Luminescence Response to Acid Vapors and Its Application in Safety Protection of File Information // ACS applied materials & interfaces. 2019. Vol. 11. No. 37. pp. 34526-34531.
GOST all authors (up to 50) Copy
Liu H., Lu Z., Ye K., Zhang Z., Zhang H. Polymorph-Dependent Luminescence Response to Acid Vapors and Its Application in Safety Protection of File Information // ACS applied materials & interfaces. 2019. Vol. 11. No. 37. pp. 34526-34531.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1021/acsami.9b14474
UR - https://doi.org/10.1021/acsami.9b14474
TI - Polymorph-Dependent Luminescence Response to Acid Vapors and Its Application in Safety Protection of File Information
T2 - ACS applied materials & interfaces
AU - Liu, Huapeng
AU - Lu, Zhuoqun
AU - Ye, Kaiqi
AU - Zhang, Zuo-Lun
AU - Zhang, Hongyu
PY - 2019
DA - 2019/08/28
PB - American Chemical Society (ACS)
SP - 34526-34531
IS - 37
VL - 11
PMID - 31455079
SN - 1944-8244
SN - 1944-8252
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2019_Liu,
author = {Huapeng Liu and Zhuoqun Lu and Kaiqi Ye and Zuo-Lun Zhang and Hongyu Zhang},
title = {Polymorph-Dependent Luminescence Response to Acid Vapors and Its Application in Safety Protection of File Information},
journal = {ACS applied materials & interfaces},
year = {2019},
volume = {11},
publisher = {American Chemical Society (ACS)},
month = {aug},
url = {https://doi.org/10.1021/acsami.9b14474},
number = {37},
pages = {34526--34531},
doi = {10.1021/acsami.9b14474}
}
MLA
Cite this
MLA Copy
Liu, Huapeng, et al. “Polymorph-Dependent Luminescence Response to Acid Vapors and Its Application in Safety Protection of File Information.” ACS applied materials & interfaces, vol. 11, no. 37, Aug. 2019, pp. 34526-34531. https://doi.org/10.1021/acsami.9b14474.