Thermal and Dielectric Stability of Functional Photo-cross-linkable Carbazole-Modified Polypropylene
Publication type: Journal Article
Publication date: 2023-09-25
scimago Q1
wos Q1
SJR: 0.981
CiteScore: 6.9
Impact factor: 4.7
ISSN: 26376105
Organic Chemistry
Process Chemistry and Technology
Polymers and Plastics
Abstract
The present work deals with the synthesis and characterization of fluorescent polypropylene materials as well as the study of some properties, with the purpose of exploring their potential as specialty materials in high-thermal stability dielectrics. Direct copolymerization of propylene with 9-(undec-10-en-1-yl)-9H-carbazole, via metallocene catalysis, has allowed the preparation of materials containing up to 4 mol % of carbazole units. Characterization of obtained materials has shown that, besides fluorescence emission, improvements in both dielectric response and stability are important enough for potential use in PP-based film capacitors. In addition, an exploratory study on a UV-irradiated copolymer reveals that cross-linking between carbazole units is the mechanism that enables further improvements in thermal and thermo-oxidative stabilities, with respect to polypropylene.
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7
Total citations:
7
Citations from 2024:
7
(100%)
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Plaza-González D. et al. Thermal and Dielectric Stability of Functional Photo-cross-linkable Carbazole-Modified Polypropylene // ACS Applied Polymer Materials. 2023. Vol. 5. No. 10. pp. 7958-7967.
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Plaza-González D., Blázquez Blázquez E., Gómez-Elvira J., Hoyos M. Thermal and Dielectric Stability of Functional Photo-cross-linkable Carbazole-Modified Polypropylene // ACS Applied Polymer Materials. 2023. Vol. 5. No. 10. pp. 7958-7967.
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RIS
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TY - JOUR
DO - 10.1021/acsapm.3c01208
UR - https://pubs.acs.org/doi/10.1021/acsapm.3c01208
TI - Thermal and Dielectric Stability of Functional Photo-cross-linkable Carbazole-Modified Polypropylene
T2 - ACS Applied Polymer Materials
AU - Plaza-González, Daniel
AU - Blázquez Blázquez, Enrique
AU - Gómez-Elvira, J.M.
AU - Hoyos, Mario
PY - 2023
DA - 2023/09/25
PB - American Chemical Society (ACS)
SP - 7958-7967
IS - 10
VL - 5
SN - 2637-6105
ER -
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BibTex (up to 50 authors)
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@article{2023_Plaza-González,
author = {Daniel Plaza-González and Enrique Blázquez Blázquez and J.M. Gómez-Elvira and Mario Hoyos},
title = {Thermal and Dielectric Stability of Functional Photo-cross-linkable Carbazole-Modified Polypropylene},
journal = {ACS Applied Polymer Materials},
year = {2023},
volume = {5},
publisher = {American Chemical Society (ACS)},
month = {sep},
url = {https://pubs.acs.org/doi/10.1021/acsapm.3c01208},
number = {10},
pages = {7958--7967},
doi = {10.1021/acsapm.3c01208}
}
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MLA
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Plaza-González, Daniel, et al. “Thermal and Dielectric Stability of Functional Photo-cross-linkable Carbazole-Modified Polypropylene.” ACS Applied Polymer Materials, vol. 5, no. 10, Sep. 2023, pp. 7958-7967. https://pubs.acs.org/doi/10.1021/acsapm.3c01208.
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