ACS Catalysis, volume 6, issue 2, pages 526-531
Iron- or Copper-Catalyzed Trifluoromethylation of Acrylamide-Tethered Alkylidenecyclopropanes: Facile Synthesis of CF3-Containing Polycyclic Benzazepine Derivatives
Publication type: Journal Article
Publication date: 2015-12-21
Journal:
ACS Catalysis
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 12.9
ISSN: 21555435, 21555435
General Chemistry
Catalysis
Abstract
A novel iron- or copper-catalyzed trifluoromethylation of acrylamide-tethered alkylidenecyclopropanes with Togni reagent II to construct CF3-containing tetracyclic benzazepine derivatives under mild and convenient conditions has been disclosed. The chemoselective addition of in situ generated trifluoromethyl radical onto the activated alkenes triggers the reaction followed by a ring-opening process of alkylidenecyclopropanes, leading to the formation of two types of CF3-containing tetracyclic benzazepine derivatives in moderate to good yields, respectively, with excellent functional group tolerance.
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2
4
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Citations by publishers
5
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35
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36 publications, 37.5%
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27 publications, 28.13%
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2 publications, 2.08%
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Elsevier
2 publications, 2.08%
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The Chemical Society of Japan
1 publication, 1.04%
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1 publication, 1.04%
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1 publication, 1.04%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 1.04%
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5
10
15
20
25
30
35
40
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Yu L. Z. et al. Iron- or Copper-Catalyzed Trifluoromethylation of Acrylamide-Tethered Alkylidenecyclopropanes: Facile Synthesis of CF3-Containing Polycyclic Benzazepine Derivatives // ACS Catalysis. 2015. Vol. 6. No. 2. pp. 526-531.
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Yu L. Z., Xu Q., Tang X. Y., Shi M. Iron- or Copper-Catalyzed Trifluoromethylation of Acrylamide-Tethered Alkylidenecyclopropanes: Facile Synthesis of CF3-Containing Polycyclic Benzazepine Derivatives // ACS Catalysis. 2015. Vol. 6. No. 2. pp. 526-531.
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TY - JOUR
DO - 10.1021/acscatal.5b02400
UR - https://doi.org/10.1021/acscatal.5b02400
TI - Iron- or Copper-Catalyzed Trifluoromethylation of Acrylamide-Tethered Alkylidenecyclopropanes: Facile Synthesis of CF3-Containing Polycyclic Benzazepine Derivatives
T2 - ACS Catalysis
AU - Yu, Liu Zhu
AU - Xu, Qin
AU - Tang, Xiang Yiang
AU - Shi, Min
PY - 2015
DA - 2015/12/21 00:00:00
PB - American Chemical Society (ACS)
SP - 526-531
IS - 2
VL - 6
SN - 2155-5435
SN - 2155-5435
ER -
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@article{2015_Yu,
author = {Liu Zhu Yu and Qin Xu and Xiang Yiang Tang and Min Shi},
title = {Iron- or Copper-Catalyzed Trifluoromethylation of Acrylamide-Tethered Alkylidenecyclopropanes: Facile Synthesis of CF3-Containing Polycyclic Benzazepine Derivatives},
journal = {ACS Catalysis},
year = {2015},
volume = {6},
publisher = {American Chemical Society (ACS)},
month = {dec},
url = {https://doi.org/10.1021/acscatal.5b02400},
number = {2},
pages = {526--531},
doi = {10.1021/acscatal.5b02400}
}
Cite this
MLA
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Yu., Liu Zhu, et al. “Iron- or Copper-Catalyzed Trifluoromethylation of Acrylamide-Tethered Alkylidenecyclopropanes: Facile Synthesis of CF3-Containing Polycyclic Benzazepine Derivatives.” ACS Catalysis, vol. 6, no. 2, Dec. 2015, pp. 526-531. https://doi.org/10.1021/acscatal.5b02400.