Iron- or Copper-Catalyzed Trifluoromethylation of Acrylamide-Tethered Alkylidenecyclopropanes: Facile Synthesis of CF3-Containing Polycyclic Benzazepine Derivatives
Publication type: Journal Article
Publication date: 2015-12-21
scimago Q1
wos Q1
SJR: 3.782
CiteScore: 19.5
Impact factor: 13.1
ISSN: 21555435
General Chemistry
Catalysis
Abstract
A novel iron- or copper-catalyzed trifluoromethylation of acrylamide-tethered alkylidenecyclopropanes with Togni reagent II to construct CF3-containing tetracyclic benzazepine derivatives under mild and convenient conditions has been disclosed. The chemoselective addition of in situ generated trifluoromethyl radical onto the activated alkenes triggers the reaction followed by a ring-opening process of alkylidenecyclopropanes, leading to the formation of two types of CF3-containing tetracyclic benzazepine derivatives in moderate to good yields, respectively, with excellent functional group tolerance.
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Metrics
106
Total citations:
106
Citations from 2024:
16
(15%)
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MLA
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GOST
Copy
Yu L. Z. et al. Iron- or Copper-Catalyzed Trifluoromethylation of Acrylamide-Tethered Alkylidenecyclopropanes: Facile Synthesis of CF3-Containing Polycyclic Benzazepine Derivatives // ACS Catalysis. 2015. Vol. 6. No. 2. pp. 526-531.
GOST all authors (up to 50)
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Yu L. Z., Xu Q., Tang X. Y., Shi M. Iron- or Copper-Catalyzed Trifluoromethylation of Acrylamide-Tethered Alkylidenecyclopropanes: Facile Synthesis of CF3-Containing Polycyclic Benzazepine Derivatives // ACS Catalysis. 2015. Vol. 6. No. 2. pp. 526-531.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acscatal.5b02400
UR - https://doi.org/10.1021/acscatal.5b02400
TI - Iron- or Copper-Catalyzed Trifluoromethylation of Acrylamide-Tethered Alkylidenecyclopropanes: Facile Synthesis of CF3-Containing Polycyclic Benzazepine Derivatives
T2 - ACS Catalysis
AU - Yu, Liu Zhu
AU - Xu, Qin
AU - Tang, Xiang Yiang
AU - Shi, Min
PY - 2015
DA - 2015/12/21
PB - American Chemical Society (ACS)
SP - 526-531
IS - 2
VL - 6
SN - 2155-5435
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2015_Yu,
author = {Liu Zhu Yu and Qin Xu and Xiang Yiang Tang and Min Shi},
title = {Iron- or Copper-Catalyzed Trifluoromethylation of Acrylamide-Tethered Alkylidenecyclopropanes: Facile Synthesis of CF3-Containing Polycyclic Benzazepine Derivatives},
journal = {ACS Catalysis},
year = {2015},
volume = {6},
publisher = {American Chemical Society (ACS)},
month = {dec},
url = {https://doi.org/10.1021/acscatal.5b02400},
number = {2},
pages = {526--531},
doi = {10.1021/acscatal.5b02400}
}
Cite this
MLA
Copy
Yu., Liu Zhu, et al. “Iron- or Copper-Catalyzed Trifluoromethylation of Acrylamide-Tethered Alkylidenecyclopropanes: Facile Synthesis of CF3-Containing Polycyclic Benzazepine Derivatives.” ACS Catalysis, vol. 6, no. 2, Dec. 2015, pp. 526-531. https://doi.org/10.1021/acscatal.5b02400.