ACS Catalysis, volume 6, issue 2, pages 1093-1096
C–H Difluoroalkylation of Aldehyde Hydrazones with Functionalized Difluoromethyl Bromides under Copper Catalysis
1
Université Claude Bernard Lyon 1, CNRS UMR 5246, Institut
de Chimie et Biochimie Moléculaires et Supramoléculaires,
CPE Lyon, 43 Boulevard
du 11 Novembre 1918, 69622 Villeurbanne, France
|
Publication type: Journal Article
Publication date: 2016-01-13
General Chemistry
Catalysis
Abstract
The Cu-catalyzed direct difluoroalkylation of aldehyde hydrazones with functionalized difluoromethyl bromides is described. The reaction yields stereodefined α,α–difluoro-β-keto hydrazones under mild conditions and can be carried out at a scale that opens up the possibility of practical applications.
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Prieto A. et al. C–H Difluoroalkylation of Aldehyde Hydrazones with Functionalized Difluoromethyl Bromides under Copper Catalysis // ACS Catalysis. 2016. Vol. 6. No. 2. pp. 1093-1096.
GOST all authors (up to 50)
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Prieto A., Melot R., Bouyssi D., Monteiro N. C–H Difluoroalkylation of Aldehyde Hydrazones with Functionalized Difluoromethyl Bromides under Copper Catalysis // ACS Catalysis. 2016. Vol. 6. No. 2. pp. 1093-1096.
Cite this
RIS
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TY - JOUR
DO - 10.1021/acscatal.5b02755
UR - https://doi.org/10.1021/acscatal.5b02755
TI - C–H Difluoroalkylation of Aldehyde Hydrazones with Functionalized Difluoromethyl Bromides under Copper Catalysis
T2 - ACS Catalysis
AU - Prieto, Alexis
AU - Melot, Romain
AU - Bouyssi, Didier
AU - Monteiro, Nuno
PY - 2016
DA - 2016/01/13
PB - American Chemical Society (ACS)
SP - 1093-1096
IS - 2
VL - 6
SN - 2155-5435
ER -
Cite this
BibTex (up to 50 authors)
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@article{2016_Prieto,
author = {Alexis Prieto and Romain Melot and Didier Bouyssi and Nuno Monteiro},
title = {C–H Difluoroalkylation of Aldehyde Hydrazones with Functionalized Difluoromethyl Bromides under Copper Catalysis},
journal = {ACS Catalysis},
year = {2016},
volume = {6},
publisher = {American Chemical Society (ACS)},
month = {jan},
url = {https://doi.org/10.1021/acscatal.5b02755},
number = {2},
pages = {1093--1096},
doi = {10.1021/acscatal.5b02755}
}
Cite this
MLA
Copy
Prieto, Alexis, et al. “C–H Difluoroalkylation of Aldehyde Hydrazones with Functionalized Difluoromethyl Bromides under Copper Catalysis.” ACS Catalysis, vol. 6, no. 2, Jan. 2016, pp. 1093-1096. https://doi.org/10.1021/acscatal.5b02755.