volume 7 issue 5 pages 3344-3348

Selective Copper–N-Heterocyclic Carbene (Copper-NHC)-Catalyzed Aerobic Cleavage of β-1 Lignin Models to Aldehydes

Publication typeJournal Article
Publication date2017-04-10
scimago Q1
wos Q1
SJR3.782
CiteScore19.5
Impact factor13.1
ISSN21555435
General Chemistry
Catalysis
Abstract
As fossil resources are undergoing fast depletion, the harvesting of sustainable aromatic compounds from biorenewable lignin has become highly appealing nowadays. However, the development of efficient catalysts for lignin depolymerization to high value-added chemicals is challenging. In this paper, a selective copper–N-heterocyclic carbene (copper-NHC)-catalyzed aerobic cleavage is reported for β-1 lignin model compound, which represents an important family of natural wood lignin. Using this catalyst system, the cleavage of β-1 model compounds gave >99% conversions and satisfactory yields of the corresponding aldehydes, which can serve as versatile starting materials for the chemical industry.
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GOST Copy
Zhou Z. Z. et al. Selective Copper–N-Heterocyclic Carbene (Copper-NHC)-Catalyzed Aerobic Cleavage of β-1 Lignin Models to Aldehydes // ACS Catalysis. 2017. Vol. 7. No. 5. pp. 3344-3348.
GOST all authors (up to 50) Copy
Zhou Z. Z., Liu M., Li C. Selective Copper–N-Heterocyclic Carbene (Copper-NHC)-Catalyzed Aerobic Cleavage of β-1 Lignin Models to Aldehydes // ACS Catalysis. 2017. Vol. 7. No. 5. pp. 3344-3348.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1021/acscatal.7b00565
UR - https://doi.org/10.1021/acscatal.7b00565
TI - Selective Copper–N-Heterocyclic Carbene (Copper-NHC)-Catalyzed Aerobic Cleavage of β-1 Lignin Models to Aldehydes
T2 - ACS Catalysis
AU - Zhou, Zhong Zhen
AU - Liu, Mingxin
AU - Li, Chao-Jun
PY - 2017
DA - 2017/04/10
PB - American Chemical Society (ACS)
SP - 3344-3348
IS - 5
VL - 7
SN - 2155-5435
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2017_Zhou,
author = {Zhong Zhen Zhou and Mingxin Liu and Chao-Jun Li},
title = {Selective Copper–N-Heterocyclic Carbene (Copper-NHC)-Catalyzed Aerobic Cleavage of β-1 Lignin Models to Aldehydes},
journal = {ACS Catalysis},
year = {2017},
volume = {7},
publisher = {American Chemical Society (ACS)},
month = {apr},
url = {https://doi.org/10.1021/acscatal.7b00565},
number = {5},
pages = {3344--3348},
doi = {10.1021/acscatal.7b00565}
}
MLA
Cite this
MLA Copy
Zhou, Zhong Zhen, et al. “Selective Copper–N-Heterocyclic Carbene (Copper-NHC)-Catalyzed Aerobic Cleavage of β-1 Lignin Models to Aldehydes.” ACS Catalysis, vol. 7, no. 5, Apr. 2017, pp. 3344-3348. https://doi.org/10.1021/acscatal.7b00565.