Ir(III)-PC(sp3)P Bifunctional Catalysts for Production of H2 by Dehydrogenation of Formic Acid: Experimental and Theoretical Study
Publication type: Journal Article
Publication date: 2017-10-31
scimago Q1
wos Q1
SJR: 3.782
CiteScore: 19.5
Impact factor: 13.1
ISSN: 21555435
General Chemistry
Catalysis
Abstract
Reversible storage of hydrogen in the form of stable and relatively harmless chemical substances such as formic acid (FA) is one of the cornerstones of a fossil-fuel-free economy. Recently, Ru(III)-PC(sp3)P (where PC(sp3)P = modular dibenzobarrelene-based pincer ligand possessing a pendant functional group) complex 1 has been reported as a mild and E-selective catalyst in semihydrogenation of alkynes with stoichiometric neat formic acid. Discovery of the additive-free protocol for dehydrogenation of FA launched further studies aiming at the rational design of highly efficient catalysts for this reaction operating under neutral conditions. We now report the results of our investigation on a series of bifunctionl PC(sp3)P complexes equipped with different outer-sphere auxiliaries, that allowed us to identify an amine-functionalized Ir(III)-PC(sp3)P complex 3, as a clean and efficient catalyst for the FA dehydrogenation. The catalyst is suitable for fuel-cell applications demonstrating a TON up to 5 × 105 an...
Found
Nothing found, try to update filter.
Found
Nothing found, try to update filter.
Top-30
Journals
|
1
2
3
4
5
6
7
|
|
|
ACS Catalysis
7 publications, 12.28%
|
|
|
Dalton Transactions
6 publications, 10.53%
|
|
|
Inorganic Chemistry
5 publications, 8.77%
|
|
|
European Journal of Inorganic Chemistry
3 publications, 5.26%
|
|
|
Organometallics
3 publications, 5.26%
|
|
|
ChemSusChem
3 publications, 5.26%
|
|
|
Chemistry - A European Journal
3 publications, 5.26%
|
|
|
Chemical Communications
3 publications, 5.26%
|
|
|
Catalysts
2 publications, 3.51%
|
|
|
New Journal of Chemistry
2 publications, 3.51%
|
|
|
Catalysis Science and Technology
2 publications, 3.51%
|
|
|
Inorganic Chemistry Frontiers
2 publications, 3.51%
|
|
|
Topics in Organometallic Chemistry
2 publications, 3.51%
|
|
|
Journal of Catalysis
2 publications, 3.51%
|
|
|
Molecules
1 publication, 1.75%
|
|
|
Nature Catalysis
1 publication, 1.75%
|
|
|
Chemistry - An Asian Journal
1 publication, 1.75%
|
|
|
Advanced Energy Materials
1 publication, 1.75%
|
|
|
Journal of Physical Chemistry A
1 publication, 1.75%
|
|
|
Green Chemistry
1 publication, 1.75%
|
|
|
Advances in Organometallic Chemistry
1 publication, 1.75%
|
|
|
Angewandte Chemie
1 publication, 1.75%
|
|
|
Angewandte Chemie - International Edition
1 publication, 1.75%
|
|
|
Organophosphorus Chemistry
1 publication, 1.75%
|
|
|
1
2
3
4
5
6
7
|
Publishers
|
2
4
6
8
10
12
14
16
18
|
|
|
Royal Society of Chemistry (RSC)
17 publications, 29.82%
|
|
|
American Chemical Society (ACS)
16 publications, 28.07%
|
|
|
Wiley
13 publications, 22.81%
|
|
|
Elsevier
5 publications, 8.77%
|
|
|
MDPI
3 publications, 5.26%
|
|
|
Springer Nature
3 publications, 5.26%
|
|
|
2
4
6
8
10
12
14
16
18
|
- We do not take into account publications without a DOI.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
57
Total citations:
57
Citations from 2024:
10
(17%)
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Cohen S. et al. Ir(III)-PC(sp3)P Bifunctional Catalysts for Production of H2 by Dehydrogenation of Formic Acid: Experimental and Theoretical Study // ACS Catalysis. 2017. Vol. 7. No. 12. pp. 8139-8146.
GOST all authors (up to 50)
Copy
Cohen S., Borin V. A., Schapiro I., Musa S., De Botton S., Belkova N. V., Gelman D. Ir(III)-PC(sp3)P Bifunctional Catalysts for Production of H2 by Dehydrogenation of Formic Acid: Experimental and Theoretical Study // ACS Catalysis. 2017. Vol. 7. No. 12. pp. 8139-8146.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acscatal.7b02482
UR - https://doi.org/10.1021/acscatal.7b02482
TI - Ir(III)-PC(sp3)P Bifunctional Catalysts for Production of H2 by Dehydrogenation of Formic Acid: Experimental and Theoretical Study
T2 - ACS Catalysis
AU - Cohen, Shirel
AU - Borin, Veniamin A.
AU - Schapiro, Igor
AU - Musa, Sanaa
AU - De Botton, Sophie
AU - Belkova, Natalia V
AU - Gelman, Dmitri
PY - 2017
DA - 2017/10/31
PB - American Chemical Society (ACS)
SP - 8139-8146
IS - 12
VL - 7
SN - 2155-5435
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2017_Cohen,
author = {Shirel Cohen and Veniamin A. Borin and Igor Schapiro and Sanaa Musa and Sophie De Botton and Natalia V Belkova and Dmitri Gelman},
title = {Ir(III)-PC(sp3)P Bifunctional Catalysts for Production of H2 by Dehydrogenation of Formic Acid: Experimental and Theoretical Study},
journal = {ACS Catalysis},
year = {2017},
volume = {7},
publisher = {American Chemical Society (ACS)},
month = {oct},
url = {https://doi.org/10.1021/acscatal.7b02482},
number = {12},
pages = {8139--8146},
doi = {10.1021/acscatal.7b02482}
}
Cite this
MLA
Copy
Cohen, Shirel, et al. “Ir(III)-PC(sp3)P Bifunctional Catalysts for Production of H2 by Dehydrogenation of Formic Acid: Experimental and Theoretical Study.” ACS Catalysis, vol. 7, no. 12, Oct. 2017, pp. 8139-8146. https://doi.org/10.1021/acscatal.7b02482.