ACS Catalysis, volume 9, issue 1, pages 632-639
Carbon Dioxide Reduction to Methanol Catalyzed by Mn(I) PNP Pincer Complexes under Mild Reaction Conditions
Federica Bertini
1
,
Mathias Glatz
2
,
Berthold Stöger
3
,
Maurizio Peruzzini
1, 4
,
L. F. Veiros
5
,
Karl Kirchner
2
,
Luca Gonsalvi
1
4
Consiglio Nazionale delle Ricerche, Dipartimento di Scienze Chimiche e Tecnologia dei Materiali (CNR-DSCTM), Via dei Taurini 19, 00185 Rome, Italy
|
Publication type: Journal Article
Publication date: 2018-12-10
General Chemistry
Catalysis
Abstract
Well-defined Mn(I) hydrido carbonyl PNP pincer-type complexes were tested as efficient and selective nonprecious transition metal catalysts for the reduction of CO2 to MeOH in the presence of hydrosilanes. The choice of reaction temperature and type of silanes proved to be pivotal to achieve fast reactions and high selectivity to the methoxysilyl- vs silylformate derivatives in DMSO. The catalytic data are complemented by DFT calculations, highlighting a stepwise CO2 reduction mechanism centered on the Mn catalyst without metal-to-ligand cooperation.
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Bertini F. et al. Carbon Dioxide Reduction to Methanol Catalyzed by Mn(I) PNP Pincer Complexes under Mild Reaction Conditions // ACS Catalysis. 2018. Vol. 9. No. 1. pp. 632-639.
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Bertini F., Glatz M., Stöger B., Peruzzini M., Veiros L. F., Kirchner K., Gonsalvi L. Carbon Dioxide Reduction to Methanol Catalyzed by Mn(I) PNP Pincer Complexes under Mild Reaction Conditions // ACS Catalysis. 2018. Vol. 9. No. 1. pp. 632-639.
Cite this
RIS
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TY - JOUR
DO - 10.1021/acscatal.8b04106
UR - https://doi.org/10.1021/acscatal.8b04106
TI - Carbon Dioxide Reduction to Methanol Catalyzed by Mn(I) PNP Pincer Complexes under Mild Reaction Conditions
T2 - ACS Catalysis
AU - Veiros, L. F.
AU - Gonsalvi, Luca
AU - Bertini, Federica
AU - Glatz, Mathias
AU - Stöger, Berthold
AU - Peruzzini, Maurizio
AU - Kirchner, Karl
PY - 2018
DA - 2018/12/10
PB - American Chemical Society (ACS)
SP - 632-639
IS - 1
VL - 9
SN - 2155-5435
ER -
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BibTex
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@article{2018_Bertini,
author = {L. F. Veiros and Luca Gonsalvi and Federica Bertini and Mathias Glatz and Berthold Stöger and Maurizio Peruzzini and Karl Kirchner},
title = {Carbon Dioxide Reduction to Methanol Catalyzed by Mn(I) PNP Pincer Complexes under Mild Reaction Conditions},
journal = {ACS Catalysis},
year = {2018},
volume = {9},
publisher = {American Chemical Society (ACS)},
month = {dec},
url = {https://doi.org/10.1021/acscatal.8b04106},
number = {1},
pages = {632--639},
doi = {10.1021/acscatal.8b04106}
}
Cite this
MLA
Copy
Bertini, Federica, et al. “Carbon Dioxide Reduction to Methanol Catalyzed by Mn(I) PNP Pincer Complexes under Mild Reaction Conditions.” ACS Catalysis, vol. 9, no. 1, Dec. 2018, pp. 632-639. https://doi.org/10.1021/acscatal.8b04106.