Layered MgxV2O5·nH2O as Cathode Material for High-Performance Aqueous Zinc Ion Batteries
Тип публикации: Journal Article
Дата публикации: 2018-09-28
scimago Q1
wos Q1
БС1
SJR: 6.799
CiteScore: 29.6
Impact factor: 18.2
ISSN: 23808195
Materials Chemistry
Chemistry (miscellaneous)
Energy Engineering and Power Technology
Fuel Technology
Renewable Energy, Sustainability and the Environment
Краткое описание
The performance of chemically intercalated V2O5 was found to strongly depend on the interlayer spacing, which is related to the radius of hydrated metal ion, which can be readily tuned by using different intercalated metals. We report a layered Mg2+-intercalated V2O5 as the cathode material for aqueous ZIBs. The large radius of hydrated Mg2+ (∼4.3 A, compared with 3.8 A of commonly used Li+) results in an interlayer spacing as large as 13.4 A (against 11.07 A for Li+-intercalated V2O5), which allows efficient Zn2+ (de)insertion. As a result, the obtained porous Mg0.34V2O5·0.84H2O cathodes work in a wide potential window of 0.1 to 1.8 V versus Zn2+/Zn, and can deliver high capacities of 353 and 264 mA h g–1 at current densities of 100 and 1000 mA g–1, respectively, along with long-term durability. Furthermore, the reversible Zn2+ (de)intercalation reaction mechanism is confirmed by multiple characterizations methods.
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725
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ГОСТ
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Ming F. et al. Layered MgxV2O5·nH2O as Cathode Material for High-Performance Aqueous Zinc Ion Batteries // ACS Energy Letters. 2018. Vol. 3. No. 10. pp. 2602-2609.
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Ming F., Liang H., Lei Y., Kandambeth S., Eddaoudi M., Alshareef H. N. Layered MgxV2O5·nH2O as Cathode Material for High-Performance Aqueous Zinc Ion Batteries // ACS Energy Letters. 2018. Vol. 3. No. 10. pp. 2602-2609.
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TY - JOUR
DO - 10.1021/acsenergylett.8b01423
UR - https://doi.org/10.1021/acsenergylett.8b01423
TI - Layered MgxV2O5·nH2O as Cathode Material for High-Performance Aqueous Zinc Ion Batteries
T2 - ACS Energy Letters
AU - Ming, Fangwang
AU - Liang, Hanfeng
AU - Lei, Yongjiu
AU - Kandambeth, Sharath
AU - Eddaoudi, Mohamed
AU - Alshareef, Husam N.
PY - 2018
DA - 2018/09/28
PB - American Chemical Society (ACS)
SP - 2602-2609
IS - 10
VL - 3
SN - 2380-8195
ER -
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@article{2018_Ming,
author = {Fangwang Ming and Hanfeng Liang and Yongjiu Lei and Sharath Kandambeth and Mohamed Eddaoudi and Husam N. Alshareef},
title = {Layered MgxV2O5·nH2O as Cathode Material for High-Performance Aqueous Zinc Ion Batteries},
journal = {ACS Energy Letters},
year = {2018},
volume = {3},
publisher = {American Chemical Society (ACS)},
month = {sep},
url = {https://doi.org/10.1021/acsenergylett.8b01423},
number = {10},
pages = {2602--2609},
doi = {10.1021/acsenergylett.8b01423}
}
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MLA
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Ming, Fangwang, et al. “Layered MgxV2O5·nH2O as Cathode Material for High-Performance Aqueous Zinc Ion Batteries.” ACS Energy Letters, vol. 3, no. 10, Sep. 2018, pp. 2602-2609. https://doi.org/10.1021/acsenergylett.8b01423.